Laser-induced Incandescence
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Laser-induced Incandescence
Laser-induced incandescence (LII) is an ''in situ'' method of measuring aerosol particle volume fraction, primary particle sizes, and other thermophysical properties in flames, during gas-phase nanoparticle synthesis, and in aerosol streams more broadly. The technique is prominently used to characterize soot. The technique can broadly be separated into applications involving continuous or pulsed laser sources, with the former implemented in the Single Particle Soot Photometer (SP2) and the latter used in time-resolved laser-induced incandescence (TiRe-LII) analyses. References See also * Laser-induced fluorescence * Planar laser-induced fluorescence Planar laser-induced fluorescence (PLIF) is an optical diagnostic technique widely used for flow visualization and quantitative measurements. PLIF has been shown to be used for velocity, concentration, temperature and pressure measurements. Wo ... Spectroscopy {{Spectroscopy-stub ...
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Aerosol
An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be natural or Human impact on the environment, anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at Hydroelectric dam, hydroelectric dams, Irrigation, irrigation mist, Perfume, perfume from atomizers, smoke, steam from a kettle, Pesticide, sprayed pesticides, and medical treatments for respiratory illnesses. When a person inhales the contents of a vape pen or e-cigarette, they are inhaling an Human impact on the environment, anthropogenic aerosol. The liquid or solid particles in an aerosol have diameters typically less than micrometre, 1 μm (larger particles with a significant settling speed make the mixture a Suspension (chemistry), suspension, but the distinction is not clear-cut) ...
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Volume Fraction
In chemistry and fluid mechanics, the volume fraction φ''i'' is defined as the volume of a constituent ''V''''i'' divided by the volume of all constituents of the mixture ''V'' prior to mixing: :\phi_i = \frac Being dimensionless, its unit is 1; it is expressed as a number, e.g., 0.18. It is the same concept as volume percent (vol%) except that the latter is expressed with a denominator of 100, e.g., 18%. The volume fraction coincides with the volume concentration in ideal solutions where the volumes of the constituents are additive (the volume of the solution is equal to the sum of the volumes of its ingredients). The sum of all volume fractions of a mixture is equal to 1: :\sum_^ V_i = V ; \qquad \sum_^ \phi_i = 1 The volume fraction (percentage by volume, vol%) is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction (percentage by weight, wt%) and mole fraction (percentage by moles, mol%) are others. Volume concentration and ...
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Flame
A flame (from Latin ''flamma'') is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density they are then considered plasma. Mechanism Color and temperature of a flame are dependent on the type of fuel involved in the combustion, as, for example, when a lighter is held to a candle. The applied heat causes the fuel molecules in the candle wax to vaporize (if this process happens in inert atmosphere without oxidizer, it is called pyrolysis). In this state they can then readily react with oxygen in the air, which gives off enough heat in the subsequent exothermic reaction to vaporize yet more fuel, thus sustaining a consistent flame. The high temperature of the flame causes the vaporized fuel molecules to decompose, forming various incomplete combustion products and free radicals, and these products then react with each other and with ...
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Soot
Soot ( ) is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons. It is more properly restricted to the product of the gas-phase combustion process but is commonly extended to include the residual pyrolysed fuel particles such as coal, cenospheres, charred wood, and petroleum coke that may become airborne during pyrolysis and that are more properly identified as cokes or char. Soot causes various types of cancer and lung disease. Sources Soot as an airborne contaminant in the environment has many different sources, all of which are results of some form of pyrolysis. They include soot from coal burning, internal-combustion engines, power-plant boilers, hog-fuel boilers, ship boilers, central steam-heat boilers, waste incineration, local field burning, house fires, forest fires, fireplaces, and furnaces. These exterior sources also contribute to the indoor environment sources such as smoking of plant matter, cooking, oil lamps, candles, qu ...
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Laser-induced Fluorescence
Laser-induced fluorescence (LIF) or laser-stimulated fluorescence (LSF) is a spectroscopic method in which an atom or molecule is excited to a higher energy level by the absorption of laser light followed by spontaneous emission of light. It was first reported by Zare and coworkers in 1968. LIF is used for studying structure of molecules, detection of selective species and flow visualization and measurements. The wavelength is often selected to be the one at which the species has its largest cross section. The excited species will after some time, usually in the order of few nanoseconds to microseconds, de-excite and emit light at a wavelength longer than the excitation wavelength. This fluorescent light is typically recorded with a photomultiplier tube (PMT) or filtered photodiodes. Types Two different kinds of spectra exist, disperse spectra and excitation spectra. The disperse spectra are performed with a fixed lasing wavelength, as above and the fluorescence spectrum is anal ...
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Planar Laser-induced Fluorescence
Planar laser-induced fluorescence (PLIF) is an optical diagnostic technique widely used for flow visualization and quantitative measurements. PLIF has been shown to be used for velocity, concentration, temperature and pressure measurements. Working A PLIF setup consists of a source of light (usually a laser), an arrangement of lenses to form a sheet, fluorescent medium, collection optics and a detector. The light from the source, illuminates the medium, which then fluoresces. This signal is captured by the detector and can be related to the various properties of the medium. The typical lasers used as light sources are pulsed, which provide a higher peak power than the continuous-wave lasers. Also the short pulse time is useful for good temporal resolution. Some of the widely used laser sources are Nd:YAG laser, dye lasers, excimer lasers, and ion lasers. The light from the laser (usually a beam) is passed through a set of lenses and/or mirrors to form a sheet, which is then ...
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