Lanthanum Barium Copper Oxide
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Lanthanum Barium Copper Oxide
Lanthanum barium copper oxide, or LBCO, is an inorganic compound with the formula CuBa0.15La1.85O4. It is a black solid produced by heating an intimate mixture of barium oxide, copper(II) oxide, and lanthanum oxide in the presence of oxygen. The material was discovered in 1986 and was the first high temperature superconductor. Johannes Georg Bednorz and K. Alex Müller shared the 1987 Nobel Prize in physics for the discovery that this material exhibits superconductivity at the then unusually high temperature. This finding led to intense and fruitful efforts to generate other cuprate superconductor Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductor ...s. Lanthanum barium copper oxide is related to the far simpler compound lanthanum cuprate, which has a similar structure. In lan ...
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Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ...
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Barium Oxide
Barium oxide, also known as baria, is a white hygroscopic non-flammable compound with the formula BaO. It has a cubic structure and is used in cathode ray tubes, crown glass, and catalysts. It is harmful to human skin and if swallowed in large quantity causes irritation. Excessive quantities of barium oxide may lead to death. It is prepared by heating barium carbonate with coke, carbon black or tar or by thermal decomposition of barium nitrate. Uses Barium oxide is used as a coating for hot cathodes, for example, those in cathode ray tubes. It replaced lead(II) oxide in the production of certain kinds of glass such as optical crown glass. While lead oxide raised the refractive index, it also raised the dispersive power, which barium oxide does not alter. Barium oxide also has use as an ethoxylation catalyst in the reaction of ethylene oxide and alcohols, which takes place between 150 and 200 °C. It is also a source of pure oxygen through heat fluctuation. It readily o ...
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Copper(II) Oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds. Production It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to give copper(I) and copper(II) ammine complexes, which are extracted from the solids. These complexes are decomposed with steam to give CuO. It can be formed by heating copper in air at around 300–800°C: : 2 Cu + O2 → 2 CuO For laboratory uses, pure copper(II) oxide is better prepared by heating copper(II) nitrate, copper(II) hydroxide, or basic copper(II) carbonate: : 2 Cu(NO3)2(s) → 2 CuO(s) + 4 NO2(g) + O2(g) (180° ...
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Lanthanum Oxide
Lanthanum(III) oxide, also known as lanthana, chemical formula , is an inorganic compound containing the rare earth element lanthanum and oxygen. It is used in some ferroelectric materials, as a component of optical materials, and is a feedstock for certain catalysts, among other uses. Properties Lanthanum oxide is a white solid that is insoluble in water, but dissolves in acidic solutions. absorbs moisture from air, converts to lanthanum hydroxide. Lanthanum oxide has p-type semiconducting properties and a band gap of approximately 5.8 eV. Its average room temperature resistivity is 10 kΩ·cm, which decreases with an increase in temperature. has the lowest lattice energy of the rare earth oxides, with very high dielectric constant, ε = 27. Structure At low temperatures, has an A- hexagonal crystal structure. The metal atoms are surrounded by a 7 coordinate group of atoms, the oxygen ions are in an octahedral shape around the metal atom and there is one oxygen ion above ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as ...
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High-temperature Superconductivity
High-temperature superconductors (abbreviated high-c or HTS) are defined as materials that behave as superconductors at temperatures above , the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previously known superconductors, which function at even colder temperatures close to absolute zero. In absolute terms, these "high temperatures" are still far below ambient, and therefore require cooling. The first high-temperature superconductor was discovered in 1986, by IBM researchers Bednorz and Müller, who were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-c materials are type-II superconductors. The major advantage of high-temperature superconductors is that they can be cooled by using liquid nitrogen, as opposed to the previously known superconductors which require expensive and hard-to-handle coolants, primarily liquid helium. ...
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Johannes Georg Bednorz
Johannes Georg Bednorz (; born 16 May 1950) is a German physicist who, together with K. Alex Müller, discovered high-temperature superconductivity in ceramics, for which they shared the 1987 Nobel Prize in Physics. Life and work Bednorz was born in Neuenkirchen, North Rhine-Westphalia, Germany to elementary-school teacher Anton and piano teacher Elisabeth Bednorz, as the youngest of four children. His parents were both from Silesia in Central Europe, but were forced to move westwards in turbulences of World War II. including the Nobel Lecture, December 8, 1987 ''Perovskite-Type Oxides – The New Approach to High-Tc Superconductivity'' As a child, his parents tried to get him interested in classical music, but he was more practically inclined, preferring to work on motorcycles and cars. (Although as a teenager he did eventually learn to play the violin and trumpet.) In high school he developed an interest in the natural sciences, focusing on chemistry, which he could learn in ...
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Karl Alexander Müller
Karl may refer to: People * Karl (given name), including a list of people and characters with the name * Karl der Große, commonly known in English as Charlemagne * Karl Marx, German philosopher and political writer * Karl of Austria, last Austrian Emperor * Karl (footballer) (born 1993), Karl Cachoeira Della Vedova Júnior, Brazilian footballer In myth * Karl (mythology), in Norse mythology, a son of Rig and considered the progenitor of peasants (churl) * ''Karl'', giant in Icelandic myth, associated with Drangey island Vehicles * Opel Karl, a car * ST ''Karl'', Swedish tugboat requisitioned during the Second World War as ST ''Empire Henchman'' Other uses * Karl, Germany, municipality in Rhineland-Palatinate, Germany * ''Karl-Gerät'', AKA Mörser Karl, 600mm German mortar used in the Second World War * KARL project, an open source knowledge management system * Korean Amateur Radio League, a national non-profit organization for amateur radio enthusiasts in South Korea * K ...
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Nobel Prize
The Nobel Prizes ( ; sv, Nobelpriset ; no, Nobelprisen ) are five separate prizes that, according to Alfred Nobel's will of 1895, are awarded to "those who, during the preceding year, have conferred the greatest benefit to humankind." Alfred Nobel was a Swedish chemist, engineer, and industrialist most famously known for the invention of dynamite. He died in 1896. In his will, he bequeathed all of his "remaining realisable assets" to be used to establish five prizes which became known as "Nobel Prizes." Nobel Prizes were first awarded in 1901. Nobel Prizes are awarded in the fields of Physics, Chemistry, Physiology or Medicine, Literature, and Peace (Nobel characterized the Peace Prize as "to the person who has done the most or best to advance fellowship among nations, the abolition or reduction of standing armies, and the establishment and promotion of peace congresses"). In 1968, Sveriges Riksbank (Sweden's central bank) funded the establishment of the Prize in Economi ...
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Physics
Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." Physics is one of the most fundamental scientific disciplines, with its main goal being to understand how the universe behaves. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physic ...
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Cuprate Superconductor
Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductors are the highest temperature superconductors known. However, the mechanism by which superconductivity occurs is still not understood. History The first cuprate superconductor was found in 1986 in the non-stoichiometric cuprate lanthanum barium copper oxide by IBM researchers Georg Bednorz and Karl Alex Müller. The critical temperature for this material was 35K, well above the previous record of 23 K. The discovery led to a sharp increase in research on the cuprates, resulting in thousands of publications between 1986 and 2001. Bednorz and Müller were awarded the Nobel Prize in Physics in 1987, only a year after their discovery.
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Lanthanum Cuprate
Lanthanum cuprate usually refers to the inorganic compound with the formula CuLa2O4. The name implies that the compound consists of a cuprate (CuOn]2n-) salt of lanthanum (La3+). In fact it is a highly covalent solid. It is prepared by high temperature reaction of lanthanum oxide and copper(II) oxide follow by annealing under oxygen. The material adopts a tetragonal structure related to potassium tetrafluoronickelate (K2NiF4), which is orthorhombic. Replacement of some lanthanum by barium gives the quaternary phase CuLa1.85Ba0.15O4, called lanthanum barium copper oxide. That doped material displays superconductivity at −243 K, which at the time of its discovery was a high temperature. This discovery initiated research on cuprate superconductors and was the basis of a Nobel Prize in Physics to Georg Bednorz Johannes Georg Bednorz (; born 16 May 1950) is a German physicist who, together with K. Alex Müller, discovered high-temperature superconductivity in ceramics, for w ...
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