Lanthanum Cuprate
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Lanthanum cuprate usually refers to the inorganic compound with the formula CuLa2O4. The name implies that the compound consists of a
cuprate Cuprate loosely refers to a material that can be viewed as containing anionic copper complexes. Examples include tetrachloridocuprate ( uCl4sup>2−), the superconductor YBa2Cu3O7, and the organocuprates (e.g., dimethylcuprate u(CH3)2sup>∠...
(CuOn]2n-) salt of lanthanum (La3+). In fact it is a highly covalent solid. It is prepared by high temperature reaction of
lanthanum oxide Lanthanum(III) oxide, also known as lanthana, chemical formula , is an inorganic compound containing the rare earth element lanthanum and oxygen. It is used in some ferroelectric materials, as a component of optical materials, and is a feedstock ...
and
copper(II) oxide Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is ...
follow by annealing under oxygen. The material adopts a tetragonal structure related to
potassium tetrafluoronickelate Potassium tetrafluoronickelate is the inorganic compound with the formula K2NiF4. It features octahedral (high spin) Ni centers with Ni-F bond lengths of 2.006 Ã…. This green solid is a salt of tetrafluoronickelate. It is prepared by melting a mixt ...
(K2NiF4), which is orthorhombic. Replacement of some lanthanum by barium gives the quaternary phase CuLa1.85Ba0.15O4, called
lanthanum barium copper oxide Lanthanum barium copper oxide, or LBCO, is an inorganic compound with the formula CuBa0.15La1.85O4. It is a black solid produced by heating an intimate mixture of barium oxide, copper(II) oxide, and lanthanum oxide in the presence of oxygen. ...
. That doped material displays superconductivity at −243 K, which at the time of its discovery was a high temperature. This discovery initiated research on
cuprate superconductor Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductor ...
s and was the basis of a
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
to
Georg Bednorz Johannes Georg Bednorz (; born 16 May 1950) is a German physicist who, together with K. Alex Müller, discovered high-temperature superconductivity in ceramics, for which they shared the 1987 Nobel Prize in Physics. Life and work Bednorz was bor ...
and K. Alex Müller.{{cite journal , doi=10.1007/BF01303701, title=Possible High Tc Superconductivity in the Ba-La-Cu-O System, year=1986, last1=Bednorz, first1=J. G., last2=Müller, first2=K. A., journal=Zeitschrift für Physik B: Condensed Matter, volume=64, issue=2, pages=189–193, bibcode=1986ZPhyB..64..189B, s2cid=118314311


References

Inorganic compounds Chemical substances