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Lithium Triborate
Lithium triborate (LiB3O5) or LBO is a non-linear optics crystal. It has a wide transparency range, moderately high nonlinear coupling, high damage threshold and desirable chemical and mechanical properties. This crystal is often used for second harmonic generation (SHG, also known as ''frequency doubling''), for example of Nd:YAG lasers (1064 nm → 532 nm). LBO can be both critically and non-critically phase-matched. In the latter case the crystal has to be heated or cooled depending on the wavelength. Lithium triborate was discovered and developed by Chen Chuangtian and others of the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. It has been patented. Chemical properties *Point group: mm2 *Lattice parameters: ''a''=8.4473 Å, ''b''=7.3788 Å, ''c''=5.1395 Å *Mohs hardness: 6 *Transmission range: 0.16 – 2.6 μm * Damage threshold: 25 J/cm2 (1064 nm, 10 ns pulses) *Thermal expansion coefficients: ''x'': 10.8×10−5 ...
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Lithium
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. When cut, it exhibits a metallic luster, but moist air corrodes it quickly to a dull silvery gray, then black tarnish. It never occurs freely in nature, but only in (usually ionic) compounds, such as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride. The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes foun ...
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Fujian Institute Of Research On The Structure Of Matter
Fujian (; alternately romanized as Fukien or Hokkien) is a province on the southeastern coast of China. Fujian is bordered by Zhejiang to the north, Jiangxi to the west, Guangdong to the south, and the Taiwan Strait to the east. Its capital is Fuzhou, while its largest city by population is Quanzhou, both located near the coast of the Taiwan Strait in the east of the province. While its population is predominantly of Chinese ethnicity, it is one of the most culturally and linguistically diverse provinces in China. The dialects of the language group Min Chinese were most commonly spoken within the province, including the Fuzhou dialect of northeastern Fujian and various Hokkien dialects of southeastern Fujian. Hakka Chinese is also spoken, by the Hakka people in Fujian. Min dialects, Hakka and Mandarin Chinese are mutually unintelligible. Due to emigration, a sizable amount of the ethnic Chinese populations of Taiwan, Singapore, Malaysia, Indonesia, and the Philippines spe ...
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Nonlinear Optical Materials
In mathematics and science, a nonlinear system is a system in which the change of the output is not proportional to the change of the input. Nonlinear problems are of interest to engineers, biologists, physicists, mathematicians, and many other scientists because most systems are inherently nonlinear in nature. Nonlinear dynamical systems, describing changes in variables over time, may appear chaotic, unpredictable, or counterintuitive, contrasting with much simpler linear systems. Typically, the behavior of a nonlinear system is described in mathematics by a nonlinear system of equations, which is a set of simultaneous equations in which the unknowns (or the unknown functions in the case of differential equations) appear as variables of a polynomial of degree higher than one or in the argument of a function which is not a polynomial of degree one. In other words, in a nonlinear system of equations, the equation(s) to be solved cannot be written as a linear combination of the un ...
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Borates
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found in sodium metaborate * diborate , f ...
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Optical Parametric Oscillator
An optical parametric oscillator (OPO) is a parametric oscillator that oscillates at optical frequencies. It converts an input laser wave (called "pump") with frequency \omega_p into two output waves of lower frequency (\omega_s, \omega_i) by means of second- order nonlinear optical interaction. The sum of the output waves' frequencies is equal to the input wave frequency: \omega_s + \omega_i=\omega_p. For historical reasons, the two output waves are called "signal" and "idler", where the output wave with higher frequency is the "signal". A special case is the degenerate OPO, when the output frequency is one-half the pump frequency, \omega_s=\omega_i=\omega_p/2, which can result in half-harmonic generation when signal and idler have the same polarization. The first optical parametric oscillator was demonstrated by Joseph A. Giordmaine and Robert C. Miller in 1965, five years after the invention of the laser, at Bell Labs. Optical parametric oscillators are used as coherent light s ...
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Dye Laser
A dye laser is a laser that uses an organic dye as the lasing medium, usually as a liquid solution. Compared to gases and most solid state lasing media, a dye can usually be used for a much wider range of wavelengths, often spanning 50 to 100 nanometers or more. The wide bandwidth makes them particularly suitable for tunable lasers and pulsed lasers. The dye rhodamine 6G, for example, can be tuned from 635 nm (orangish-red) to 560 nm (greenish-yellow), and produce pulses as short as 16 femtoseconds. Moreover, the dye can be replaced by another type in order to generate an even broader range of wavelengths with the same laser, from the near-infrared to the near-ultraviolet, although this usually requires replacing other optical components in the laser as well, such as dielectric mirrors or pump lasers. Dye lasers were independently discovered by P. P. Sorokin and F. P. Schäfer (and colleagues) in 1966. In addition to the usual liquid state, dye lasers are also availa ...
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Sapphire Lasers
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphirus" from the Greek "sappheiros", which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires 9 on the Mohs scale (the third hardest mineral, after diamond at 10 and moissanite at 9.5) sapphires are also u ...
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Second-harmonic Generation
Second-harmonic generation (SHG, also called frequency doubling) is a nonlinear optical process in which two photons with the same frequency interact with a nonlinear material, are "combined", and generate a new photon with twice the energy of the initial photons (equivalently, twice the frequency and half the wavelength), that conserves the coherence of the excitation. It is a special case of sum-frequency generation (2 photons), and more generally of harmonic generation. The second-order nonlinear susceptibility of a medium characterizes its tendency to cause SHG. Second-harmonic generation, like other even-order nonlinear optical phenomena, is not allowed in media with inversion symmetry (in the leading electric dipole contribution). However, effects such as the Bloch–Siegert shift (oscillation), found when two-level systems are driven at Rabi frequencies comparable to their transition frequencies, will give rise to second harmonic generation in centro-symmetric systems. ...
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Thermal Expansion Coefficient
Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions. Temperature is a monotonic function of the average molecular kinetic energy of a substance. When a substance is heated, molecules begin to vibrate and move more, usually creating more distance between themselves. Substances which contract with increasing temperature are unusual, and only occur within limited temperature ranges (see examples below). The relative expansion (also called strain) divided by the change in temperature is called the material's coefficient of linear thermal expansion and generally varies with temperature. As energy in particles increases, they start moving faster and faster weakening the intermolecular forces between them, therefore expanding the substance. Overview Predicting expansion If an equation of state is available, it can be used to predict the values of the thermal expan ...
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Laser Damage Threshold
The laser damage threshold (LDT) or laser induced damage threshold (LIDT) is the limit at which an optic or material will be damaged by a laser given the fluence (energy per area), intensity (power per area), and wavelength. LDT values are relevant to both transmissive and reflective optical elements and in applications where the laser induced modification or destruction of a material is the intended outcome. Mechanisms Thermal For long pulses or continuous wave lasers the primary damage mechanism tends to be thermal. Since both transmitting and reflecting optics both have non-zero absorption, the laser can deposit thermal energy into the optic. At a certain point, there can be sufficient localized heating to either affect the material properties or induce thermal shock. Dielectric breakdown Dielectric breakdown occurs in insulating materials whenever the electric field is sufficient to induce electrical conductivity. Although this concept is more common in the context of D ...
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Mohs Hardness
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by the German geologist and mineralogist Friedrich Mohs, in his book ''"Versuch einer Elementar-Methode zur naturhistorischen Bestimmung und Erkennung der Fossilien"''; it is one of several definitions of hardness in materials science, some of which are more quantitative. The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned by Theophrastus in his treatise ''On Stones'', , followed by Pliny the Elder in his ''Naturalis Historia'', . The Mohs scale is useful for identification of minerals in the field, but is not an accurate predictor of how well materials endure in an industrial setting – ''toughness''. Minerals The Mohs scale of mineral hardness is based on the ability ...
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Lattice Parameter
A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal. A simple cubic crystal has only one lattice constant, the distance between atoms, but in general lattices in three dimensions have six lattice constants: the lengths ''a'', ''b'', and ''c'' of the three cell edges meeting at a vertex, and the angles ''α'', ''β'', and ''γ'' between those edges. The crystal lattice parameters ''a'', ''b'', and ''c'' have the dimension of length. The three numbers represent the size of the unit cell, that is, the distance from a given atom to an identical atom in the same position and orientation in a neighboring cell (except for very simple crystal structures, this will not necessarily be disance to the nearest neighbor). Their SI unit is the meter, and they are traditionally specified in angstroms (Å); an angstrom being 0.1 nanome ...
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