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Liquation Cracking
Liquation is a metallurgical method for separating metals from an ore or alloy. A mixture of metals is melted together with a third, after which the mixture is separated by liquid extraction. This method was largely used to separate silver from copper using lead, but it can also be used to remove antimony minerals from ore, and refine tin. Separating copper and silver The first known use of liquation on a large scale was in Germany in the mid-15th century. Metal workers had long known that Central European copper ore was rich in silver, so it was only a matter of time until a method was discovered that could separate the two metals.Lynch, M., 2004. ''Mining in World History''. London: Reaktion Books. Process The 16th-century process of separating copper and silver using liquation, described by Georg Agricola in his 1556 treatise '' De re metallica'',Hoover, H.C. and Hoover L.H., 1950. ''De re metallica / Georgius Agricola''. New York: Dover. remained almost unchanged until th ...
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Metallurgical
Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals; that is, the way in which science is applied to the production of metals, and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist. The science of metallurgy is further subdivided into two broad categories: chemical metallurgy and physical metallurgy. Chemical metallurgy is chiefly concerned with the reduction and oxidation of metals, and the chemical performance of metals. Subjects of study in chemical metallurgy include mi ...
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Ratio
In mathematics, a ratio shows how many times one number contains another. For example, if there are eight oranges and six lemons in a bowl of fruit, then the ratio of oranges to lemons is eight to six (that is, 8:6, which is equivalent to the ratio 4:3). Similarly, the ratio of lemons to oranges is 6:8 (or 3:4) and the ratio of oranges to the total amount of fruit is 8:14 (or 4:7). The numbers in a ratio may be quantities of any kind, such as counts of people or objects, or such as measurements of lengths, weights, time, etc. In most contexts, both numbers are restricted to be Positive integer, positive. A ratio may be specified either by giving both constituting numbers, written as "''a'' to ''b''" or "''a'':''b''", or by giving just the value of their quotient Equal quotients correspond to equal ratios. Consequently, a ratio may be considered as an ordered pair of numbers, a Fraction (mathematics), fraction with the first number in the numerator and the second in the denom ...
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Smelting
Smelting is a process of applying heat to ore, to extract a base metal. It is a form of extractive metallurgy. It is used to extract many metals from their ores, including silver, iron, copper, and other base metals. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal base behind. The reducing agent is commonly a fossil fuel source of carbon, such as coke—or, in earlier times, charcoal. The oxygen in the ore binds to carbon at high temperatures due to the lower potential energy of the bonds in carbon dioxide (). Smelting most prominently takes place in a blast furnace to produce pig iron, which is converted into steel. The carbon source acts as a chemical reactant to remove oxygen from the ore, yielding the purified metal element as a product. The carbon source is oxidized in two stages. First, the carbon (C) combusts with oxygen (O2) in the air to produce carbon monoxide (CO). Second, the ...
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Sankt Andreasberg
Sankt Andreasberg is a former town in the Goslar (district), district of Goslar, in Lower Saxony, Germany. Since 1 November 2011, it is part of the town Braunlage. It is situated in the Harz, approximately 7 km west of Braunlage proper, and 20 km east of Osterode am Harz. History Sankt Andreasberg was founded in the 1480s. It was first mentioned in a letter from the Count Heinrich zu Stolberg to Dietrich von Witzlebenon on 3 November 1487. The establishment of the village took place around the market. The first silver mines are assumed to be the St. Andrews Cross Mine (german: Grube St. Andreaskreuz) at the foot of the ''Beerberg'' and the St. Andrews Mine (''Grube St. Andreas'') by the market. In 1521, St. Andreasberg received the right to mine from Counts Heinrich and Ernst von Hohenstein. It was proclaimed in Mansfelder Land (district), Mansfelder Land and in the mining areas of Saxony and miners were invited to dig for silver and other metals. Natural monuments ...
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Altenau, Lower Saxony
Altenau () is a town and a former municipality in the district of Goslar, in Lower Saxony, Germany. Since 1 January 2015 it is part of the town Clausthal-Zellerfeld. It is situated in the middle of the Harz mountains, between Clausthal-Zellerfeld and the Brocken. It was part of the former ''Samtgemeinde'' ("collective municipality") Oberharz. Geography The place is centrally located in the Upper Harz. Clausthal-Zellerfeld in the west is about ten kilometers, Goslar in the north about 15 km and Osterode am Harz in the southwest about 25 km away. To the east of the mountain town, twelve kilometers away, is the summit of the Brocken, which can be seen from many places in Altenau. The Oker flows through Altenau from south to north . Other streams flow into the Oker in the urban area and give Altenau a townscape with numerous valleys and hilltops. The area is heavily forested. Districts The Torfhaus settlement about ten kilometers away belongs to Altenau . This is at ...
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Slag
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-products of recovering non-ferrous materials like copper, nickel, zinc and phosphorus). Within these general categories, slags can be further categorized by their precursor and processing conditions (e.g., Blast furnace (BF) slags, air-cooled blast furnace (ACBF) slag, basic oxygen furnace (BOF) slag, and electric arc furnace (EAF) slag) . Due to the large demand for these materials, slag production has also significantly increased throughout the years despite recycling (most notably in the iron and steelmaking industries) and upcycling efforts. The World Steel Association (WSA) estimates that 600 kg of by-products (~90 wt% is slags) are generated per tonne of steel produced. Composition Slag is usually a mixture of metal oxides and sili ...
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Metallurgical Assay
A metallurgical assay is a compositional analysis of an ore, metal, or alloy, usually performed in order to test for purity or quality. Some assay methods are suitable for raw materials; others are more appropriate for finished goods. Raw precious metals (bullion) are assayed by an assay office. Silver is assayed by titration, gold by cupellation and platinum by inductively coupled plasma optical emission spectrometry (ICP OES). Precious metal items of art or jewelry are frequently hallmarked (depending upon the requirements of the laws of either the place of manufacture or the place of import). Where required to be hallmarked, semi-finished precious metal items of art or jewelry pass through the official testing channels where they are analyzed or assayed for precious metal content. While different nations permit a variety of legally acceptable finenesses, the assayer is actually testing to determine that the fineness of the product conforms with the statement or claim of fin ...
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Cupellation
Cupellation is a refining process in metallurgy where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals, like lead, copper, zinc, arsenic, antimony, or bismuth, present in the ore. The process is based on the principle that precious metals do not oxidise or react chemically, unlike base metals. When they are heated at high temperatures, the precious metals remain apart, and the others react, forming slags or other compounds.Bayley, J. 2008 Since the Early Bronze Age, the process was used to obtain silver from smelted lead ores.Rehren, Th., Eckstein, K. 2002 By the Middle Ages and the Renaissance, cupellation was one of the most common processes for refining precious metals. By then, fire assays were used for assaying minerals: testing fresh metals such as lead and recycled metals to know their purity for jewellery and coin making. Cupellation is still in use today.Hoover, ...
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Charcoal
Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, called charcoal burning, often by forming a charcoal kiln, the heat is supplied by burning part of the starting material itself, with a limited supply of oxygen. The material can also be heated in a closed retort. Modern "charcoal" briquettes used for outdoor cooking may contain many other additives, e.g. coal. This process happens naturally when combustion is incomplete, and is sometimes used in radiocarbon dating. It also happens inadvertently while burning wood, as in a fireplace or wood stove. The visible flame in these is due to combustion of the volatile gases exuded as the wood turns into charcoal. The soot and smoke commonly given off by wood fires result from incomplete combustion of those volatiles. Charcoal burns at a higher temper ...
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Oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as ...
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Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ...
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