Linalool Enantiomers Structural Formulae
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Linalool Enantiomers Structural Formulae
Linalool () refers to two Enantiomer, enantiomers of a naturally occurring terpene Alcohol (chemistry), alcohol found in many flowers and spice plants. Linalool has multiple commercial applications, the majority of which are based on its pleasant scent (floral, with a touch of spiciness). A colorless oil, linalool is classified as an acyclic monoterpenoid. In plants, it is a metabolite, a Essential oil, volatile oil component, an antimicrobial agent, and an aroma compound. Linalool has uses in manufacturing of soaps, fragrances, food additives as flavors, household products, and insecticides. Esters of linalool are referred to as linalyl, e.g. linalyl pyrophosphate, an isomer of geranyl pyrophosphate. The word ''linalool'' is based on ''linaloe'' (a type of wood) and the suffix '. In food manufacturing, it may be called ''coriandrol''. Occurrence Both enantiomeric forms are found in nature: (''S'')-linalool is found, for example, as a major constituent of the essential oils of ...
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Enantiomer
In chemistry, an enantiomer ( /ɪˈnænti.əmər, ɛ-, -oʊ-/ ''ih-NAN-tee-ə-mər''; from Ancient Greek ἐνάντιος ''(enántios)'' 'opposite', and μέρος ''(méros)'' 'part') – also called optical isomer, antipode, or optical antipode – is one of two stereoisomers that are non-superposable onto their own mirror image. Enantiomers are much like one's right and left hands, when looking at the same face, they cannot be superposed onto each other. No amount of reorientation will allow the four unique groups on the chiral carbon (see Chirality (chemistry)) to line up exactly. The number of stereoisomers a molecule has can be determined by the number of chiral carbons it has. Stereoisomers include both enantiomers and diastereomers. Diastereomers, like enantiomers, share the same molecular formula and are non-superposable onto each other however, they are not mirror images of each other. A molecule with chirality rotates plane-polarized light. A mixture of equals a ...
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Enantiomer
In chemistry, an enantiomer ( /ɪˈnænti.əmər, ɛ-, -oʊ-/ ''ih-NAN-tee-ə-mər''; from Ancient Greek ἐνάντιος ''(enántios)'' 'opposite', and μέρος ''(méros)'' 'part') – also called optical isomer, antipode, or optical antipode – is one of two stereoisomers that are non-superposable onto their own mirror image. Enantiomers are much like one's right and left hands, when looking at the same face, they cannot be superposed onto each other. No amount of reorientation will allow the four unique groups on the chiral carbon (see Chirality (chemistry)) to line up exactly. The number of stereoisomers a molecule has can be determined by the number of chiral carbons it has. Stereoisomers include both enantiomers and diastereomers. Diastereomers, like enantiomers, share the same molecular formula and are non-superposable onto each other however, they are not mirror images of each other. A molecule with chirality rotates plane-polarized light. A mixture of equals a ...
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Parts Per Billion
In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, they are pure numbers with no associated units of measurement. Commonly used are parts-per-million (ppm, ), parts-per-billion (ppb, ), parts-per-trillion (ppt, ) and parts-per-quadrillion (ppq, ). This notation is not part of the International System of Units (SI) system and its meaning is ambiguous. Overview Parts-per notation is often used describing dilute solutions in chemistry, for instance, the relative abundance of dissolved minerals or pollutants in water. The quantity "1 ppm" can be used for a mass fraction if a water-borne pollutant is present at one-millionth of a gram per gram of sample solution. When working with aqueous solutions, it is common to assume that the density of water is 1.00 g/mL. Therefore, it is common to equate ...
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Petitgrain
Petitgrain () is an essential oil that is extracted from the leaves and green twigs of the bitter orange tree (''Citrus aurantium'' ssp. ''amara'') via steam distillation. It is also known as petitgrain bigarade. Etymology Petitgrain (Fr.: “little grain”) gains its name from the fact that it used to be extracted from the unripe small green fruits of the plant. Production Its main regions of production are Paraguay and France, with the former's product being of higher odour tenacity. The oil has a greenish woody orange smell that is widely used in perfumery and found in colognes. Though distilled from the same botanical species as neroli and bitter orange essential oil, petitgrain bigarade oil possesses its own characteristically unique aroma. The oil is distilled from the leaves and sometimes the twigs and branches of the tree, whereas neroli is distilled from the blossoms and bitter orange oil is typically cold pressed from the rinds of the fruits. Petitgrain mandarin ...
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Scent
An odor (American English) or odour (Commonwealth English; see spelling differences) is caused by one or more volatilized chemical compounds that are generally found in low concentrations that humans and animals can perceive via their sense of smell. An odor is also called a "smell" or a "scent", which can refer to either a pleasant or an unpleasant odor. While "odor" and "smell" can refer to pleasant and unpleasant odors, the terms "scent", "aroma", and "fragrance" are usually reserved for pleasant-smelling odors and are frequently used in the food and cosmetic industry to describe floral scents or to refer to perfumes. Physiology of smell Sense of smell The perception of odors, or sense of smell, is mediated by the olfactory nerve. The olfactory receptor (OR) cells are neurons present in the olfactory epithelium, which is a small patch of tissue at the back of the nasal cavity. There are millions of olfactory receptor neurons that act as sensory signaling cells. ...
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Sweet Basil
Basil (, ; ''Ocimum basilicum'' , also called great basil, is a culinary herb of the family Lamiaceae (mints). It is a tender plant, and is used in cuisines worldwide. In Western cuisine, the generic term "basil" refers to the variety also known as sweet basil or Genovese basil. Basil is native to tropical regions from Central Africa to Southeast Asia. In temperate climates basil is treated as an annual plant, however, basil can be grown as a short-lived perennial or biennial in warmer horticultural zones with tropical or Mediterranean climates. There are many varieties of basil including sweet basil, Thai basil (''O. basilicum'' var. ''thyrsiflora''), and Mrs. Burns' Lemon (''O. basilicum var. citriodora''). ''O. basilicum'' can cross-pollinate with other species of the ''Ocimum'' genus, producing hybrids such as lemon basil (''O. × citriodorum'') and African blue basil (''O. × kilimandscharicum''). Etymology The name "basil" comes from the Latin , and the Greek (), m ...
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Bay Laurel
''Laurus nobilis'' is an aromatic evergreen tree or large shrub with green, glabrous (smooth) leaves. It is in the flowering plant family Lauraceae. It is native to the Mediterranean region and is used as bay leaf for seasoning in cooking. Its common names include bay tree (esp. United Kingdom), bay laurel, sweet bay, true laurel, Grecian laurel, or simply laurel. ''Laurus nobilis'' figures prominently in classical Greco-Roman culture. Worldwide, many other kinds of plants in diverse families are also called "bay" or "laurel", generally due to similarity of foliage or aroma to ''Laurus nobilis''. Description The laurel is an evergreen shrub or small tree, variable in size and sometimes reaching tall. The genus ''Laurus'' includes four accepted species, whose diagnostic key characters often overlap. The bay laurel is dioecious (unisexual), with male and female flowers on separate plants. Each flower is pale yellow-green, about diameter, and they are borne in pairs besid ...
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Lavandula Officinalis
''Lavandula angustifolia'', formerly ''L. officinalis'', is a flowering plant in the family Lamiaceae, native to the Mediterranean (Spain, France, Italy, Croatia etc.). Its common names include lavender, true lavender and English lavender (though not native to England); also garden lavender, common lavender and narrow-leaved lavender. Description It is a strongly aromatic shrub growing as high as tall. The leaves are evergreen, long, and broad. The flowers are pinkish-purple (lavender-coloured), produced on spikes long at the top of slender, leafless stems long. Etymology The species name ''angustifolia'' is Latin for "narrow leaf". Previously, it was known as ''Lavandula officinalis'', referring to its medicinal properties. Cultivation English lavender is commonly grown as an ornamental plant. It is popular for its colourful flowers, its fragrance, and its ability to survive with low water consumption. It does not grow well in continuously damp soil and may be ...
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Lavender
''Lavandula'' (common name lavender) is a genus of 47 known species of flowering plants in the mint family, Lamiaceae. It is native to the Old World and is found in Cape Verde and the Canary Islands, and from Europe across to northern and eastern Africa, the Mediterranean, southwest Asia to India. Many members of the genus are cultivated extensively in temperate climates as ornamental plants for garden and landscape use, for use as culinary herbs, and also commercially for the extraction of essential oils. The most widely cultivated species, ''Lavandula angustifolia'', is often referred to as lavender, and there is a color named for the shade of the flowers of this species. Lavender has been used over centuries in traditional medicine and cosmetics. Description Plant and leaves The genus includes annual or short-lived herbaceous perennial plants, and shrub-like perennials, subshrubs or small shrubs. Leaf shape is diverse across the genus. They are simple in some commonly cult ...
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Citrus Sinensis
''Citrus'' is a genus of flowering plant, flowering trees and shrubs in the rue family, Rutaceae. Plants in the genus produce citrus fruits, including important crops such as Orange (fruit), oranges, Lemon, lemons, grapefruits, pomelos, and lime (fruit), limes. The genus ''Citrus'' is native to South Asia, East Asia, Southeast Asia, Melanesia, and Australia (continent), Australia. Various citrus species have been used and domesticated by indigenous cultures in these areas since ancient times. From there its cultivation spread into Micronesia and Polynesia by the Austronesian expansion (c. 3000–1500 BCE); and to the Middle East and the Mediterranean (c. 1200 BCE) via the incense trade route, and onwards to Europe and the Americas. History Citrus plants are native to subtropical and tropical regions of Asia, Island Southeast Asia, Near Oceania, and northeastern Australia. Domestication of citrus species involved much hybridization and introgression, leaving much uncertainty ab ...
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Sweet Orange
An orange is a fruit of various citrus species in the family Rutaceae The Rutaceae is a family, commonly known as the rueRUTACEAE
in BoDD – Botanical Derm ...
(see list of plants known as orange); it primarily refers to Citrus × sinensis, ''Citrus'' × ''sinensis'', which is also called sweet orange, to distinguish it from the related ''Citrus × aurantium'', referred to as bitter orange. The sweet orange reproduces asexually (apomixis through nucellar embryony); varieties of sweet orange arise through mutations. The orange is a Hybrid (biology), hybrid between pomelo (''Citrus maxima'') and Mandarin orange, mandarin (''Citrus reticulata''). The chloroplast genome, and therefore the maternal line, ...
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Cymbopogon Martini
''Cymbopogon martinii'' is a species of grass in the genus ''Cymbopogon'' (lemongrasses) native to India and Indochina, but widely cultivated in many places for its aromatic oil. It is best known by the common name palmarosa (''palm rose'') as it smells sweet and rose-like. Other common names include Indian geranium, gingergrass, rosha, and rosha grass. Palmarosa oil The essential oil of this plant, which contains the chemical compound geraniol, is valued for its scent and for a number of traditional medicinal and household uses. Palmarosa oil has been shown to be an effective insect repellent when applied to stored grain and beans, an antihelmintic against nematodes, and an antifungal and mosquito repellent.Duke, J. A. and J. duCellier. (1993). ''CRC Handbook of Alternative Cash Crops''. Boca Raton: CRC Press. 214. Palmarosa oil, which has a scent similar to roses, is added to soaps and cosmetics. Cultivation This grass grows fairly tall, ranging from in height with a pa ...
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