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LiOH
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide. Production The preferred feedstock is hard-rock spodumene, where the lithium content is expressed as % lithium oxide. Lithium carbonate route Lithium hydroxide is often produced industrially from lithium carbonate in a metathesis reaction with calcium hydroxide: : The initially produced hydrate is dehydrated by heating under vacuum up to 180 °C. Lithium sulfate route An alternative route involves the intermediacy of lithium sulfate: :α-spodumene → β-spodumene :β-spodumene + CaO → + ... : : The main by-products are gypsum and sodium sulphate, which have some market value. Commercial setting According to Bloomberg, Ganfeng Lit ...
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Lithium
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. When cut, it exhibits a metallic luster, but moist air corrodes it quickly to a dull silvery gray, then black tarnish. It never occurs freely in nature, but only in (usually ionic) compounds, such as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride. The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes ...
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Lithium Oxide
Lithium oxide ( O) or lithia is an inorganic chemical compound. It is a white solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium mineral spodumene (LiAlSi2O6) is 8.03%. Production Lithium oxide is produced by thermal decomposition of lithium peroxide at 300–400 °C.Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH: Weinheim. . Lithium oxide forms along with small amounts of lithium peroxide when lithium metal is burned in the air at and combines with oxygen at temperatures above 100 °C: :4Li + → 2. Pure can be produced by the thermal decomposition of lithium peroxide, , at 450 °C :2 → 2 + Structure Solid lithium oxide adopts an antifluorite structure with four-coordinated Li+ centers and eight-coordinated oxides. The ground state gas phase molec ...
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Lithium Sulfate
Lithium sulfate is a white inorganic salt with the formula Li2 S O4. It is the lithium salt of sulfuric acid. Properties Physical properties Lithium sulfate is soluble in water, though it does not follow the usual trend of increasing solubility of most salts with temperature. To the contrary, its solubility in water decreases with increasing temperature, as its dissolution is an exothermic process. This relatively unusual property, also called retrograde solubility, is shared with few inorganic compounds, such as calcium hydroxide ( portlandite, an important mineral phase of hydrated cement paste), the calcium sulfates (gypsum, bassanite, and anhydrite) and lanthanoid sulfates whose dissolution reactions are also exothermic. The retrograde solubility is common for gases dissolution in water, but less frequently encountered for the dissolution of solids. Calcium carbonate also exhibits a retrograde solubility, but it also depends on the behavior of dissolution in the calco- ...
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Lithium Oxide
Lithium oxide ( O) or lithia is an inorganic chemical compound. It is a white solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium mineral spodumene (LiAlSi2O6) is 8.03%. Production Lithium oxide is produced by thermal decomposition of lithium peroxide at 300–400 °C.Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH: Weinheim. . Lithium oxide forms along with small amounts of lithium peroxide when lithium metal is burned in the air at and combines with oxygen at temperatures above 100 °C: :4Li + → 2. Pure can be produced by the thermal decomposition of lithium peroxide, , at 450 °C :2 → 2 + Structure Solid lithium oxide adopts an antifluorite structure with four-coordinated Li+ centers and eight-coordinated oxides. The ground state gas phase molec ...
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Strong Base
In chemistry, there are three definitions in common use of the word base, known as Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century. In 1884, Svante Arrhenius proposed that a base is a substance which dissociates in aqueous solution to form Hydroxide ions OH−. These ions can react with hydrogen ions (H+ according to Arrhenius) from the dissociation of acids to form water in an acid–base reaction. A base was therefore a metal hydroxide such as NaOH or Ca(OH)2. Such aqueous hydroxide solutions were also described by certain characteristic properties. They are slippery to the touch, can taste bitter and change the color of pH indicators (e.g., turn red litmus paper blue). In water, by altering the autoionization equilibrium, bases yield solutions in which the hydrogen ion activity is lower than it is in pure water, i.e., the water h ...
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Debye
The debye (symbol: D) (; ) is a CGS unit (a non- SI metric unit) of electric dipole momentTwo equal and opposite charges separated by some distance constitute an electric dipole. This dipole possesses an electric dipole moment whose value is given as charge times length of separation, it is a vector whose direction is in the direction of the unit vector of the position vector of the positive charge w.r.t negative charge: :p = ''q''r. named in honour of the physicist Peter J. W. Debye. It is defined as statcoulomb-centimeters.The statcoulomb is also known as the franklin or electrostatic unit of charge. :1 statC = 1 Fr = 1 esu = 1 cm3/2⋅g1/2⋅s−1. Historically the debye was defined as the dipole moment resulting from two charges of opposite sign but an equal magnitude of 10−10 statcoulomb10−10 statcoulomb corresponds to approximately 0.2083 units of elementary charge. (generally called e.s.u. (electrostatic unit) in older scienti ...
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Lithium Carbonate
Lithium carbonate is an inorganic compound, the lithium salt of carbonate with the formula . This white salt is widely used in the processing of metal oxides. It is listed on the World Health Organization's List of Essential Medicines because it can be used as a treatment for mood disorders such as bipolar disorder. Uses Lithium carbonate is an important industrial chemical. Its main use is as a precursor for compounds used in lithium-ion batteries. Glasses derived from lithium carbonate are useful in ovenware. Lithium carbonate is a common ingredient in both low-fire and high-fire ceramic glaze. It forms low-melting fluxes with silica and other materials. Its alkaline properties are conducive to changing the state of metal oxide colorants in glaze, particularly red iron oxide (). Cement sets more rapidly when prepared with lithium carbonate, and is useful for tile adhesives. When added to aluminium trifluoride, it forms LiF which gives a superior electrolyte for the processi ...
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Tianqi Lithium
Tianqi Lithium Corp (; previously Sichuan Tianqi Lithium Industries, Inc.) is a Chinese mining and manufacturing company based in Sichuan. As of 2018, the company controls more 46% of the production of lithium worldwide. Production World production of lithium via spodumene was around 80,000 metric tonnes per annum in 2018, primarily from the Greenbushes pegmatite of Western Australia and from some Chinese and Chilean sources. The Talison mine in Greenbushes, Western Australia, is reported to be the 2nd largest and to have the highest grade of ore at 2.4% Li2O (2012 figures). Acquisitions Tianqi has owned a 51% ownership stake in Talison Lithium, which operates the Greenbushes mine in Australia, since 2009. Tianqi announced in 2018 that it would invest US$600 million to construct a lithium processing plant in Kwinana, Western Australia. In 2018, Tianqi acquired a 24% stake in the Chilean mining company Sociedad Química y Minera (SQM) for approximately $4.1 billion. Tianqi ...
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Kemerton, Western Australia
Wellesley is a locality in the Bunbury region of Western Australia, about 10 km north-east of Australind. Its local government area is the Shire of Harvey. It is bordered on the south and east by the Brunswick River and the Wellesley River. The main feature of the locality is the Kemerton Industrial Park. Kemerton Industrial Park The estate was established in 1985 as a "strategic industrial area" to provide appropriate buffered land for heavy industry. It covers an area of 7543 ha, comprising an industrial core of 2100 ha, a support industry area of 300 ha, an inter-industry buffer of 175 ha and a buffer area of 5437 ha which includes bushland, wetland, protection zones and recreational areas. A rail link connecting with the Perth-Bunbury railway is proposed. It is coordinated by the Department of Industry and Resources (WA), South West Development Commission and the Shire of Harvey. History Little is known of the area prior to 1980 - a report in 1988 noted that (p.&n ...
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Sociedad Química Y Minera
Sociedad Química y Minera de Chile (SQM) is a Chilean chemical company and a supplier of plant nutrients, iodine, lithium and industrial chemicals. It is the world’s biggest lithium producer. SQM's natural resources and its main production facilities are located in the Atacama Desert in Tarapacá and Antofagasta regions. History State company (1968-1983) Created in 1968 as a ''Sociedad Minera Mixta'' between private investors and the State of Chile (Compañía Salitrera Anglo-Lautaro 62.5% and CORFO 37.5%). The new company was made up of the combination of the deposits and assets of the Compañía Salitrera Anglo-Lautaro and the Empresa Salitrera Victoria owned by CORFO. At the end of 1966 the problem of the expiration of the state enterprise managed by COVENSA 30 July 1968 and how to organize the nitrate industry arose. Negotiations with Anglo-Lautaro to establish a partnership led to the creation of SQM, with the intent to restructure the declining nitrate production ...
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Albemarle Corporation
Albemarle Corporation is a specialty chemicals manufacturing company based in Charlotte, North Carolina. It operates 3 divisions: lithium (41.0% of 2021 revenues), bromine specialties (33.9% of 2021 revenues) and catalysts (22.9% of 2021 revenues). , Albemarle was the largest provider of lithium for electric vehicle batteries. Albemarle, Sociedad Química y Minera, and FMC Corporation collectively produce just over half of the world's lithium and lithium storage products, while just under half is produced by China. Albemarle is a large developer of flame retardant chemicals technologies, with production plants in the United States, China, the Netherlands, Belgium, Germany, France, Austria, and the United Kingdom. It also has a line of antioxidants and blends which concentrate on improving storage life and stability of fuel and other lubricant products. It produces products used in rigid and flexible polyurethane foam applications and ammonium polyphosphate products, pigmen ...
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Ganfeng Lithium
Ganfeng Lithium Co., Ltd. is a company that produces lithium, lithium products, other metals, and batteries in mainland China and globally. It was founded by Li Liangbin in 2000 and is headquartered in Xinyu, Jiangxi. It is the largest lithium salt producer in China and the third largest in the world, as well as the second largest lithium processor in the world (after the Chilean Sociedad Química y Minera). It is traded on both the Shenzhen Stock Exchange () and the Hong Kong Stock Exchange () and has a market capitalization of US$26 billion. Origins Ganfeng Lithium was founded in 2000 by Li Liangbin (李良彬) and Li Huabiao (李华彪) in Xinyu City, Jiangxi. In 2003, the company built a lithium production base. The company's leaders, Li Liangbin and Wang Xiaoshen (王晓申), are both of poor, rural origins. The company started out in chemical processing, but it has expanded its scope by developing mines internationally. In 2017 it began producing batteries for the ...
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