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Lead Oxychloride
Lead oxychlorides are halide compounds of lead with the general formula PbClO(H). Occurrence in nature Lead oxychlorides are found naturally in the minerals hereroite as Pb32O212Cl10, in rickturnerite as Pb7O4(OH)Cl3, in vladkrivovichevite as Pb32O18Cl14, in asisite as Pb7SiO4O4Cl2, in damaraite as Pb3Cl(OH)O2, in hereroite as Pb3Cl(OH)O2, in Mendipite as Pb3Cl2O2, and in the dimorph minerals laurionite and paralaurionite, which are PbCl(OH) members of the matlockite group. Usage Historically, the primary use of lead oxychlorides was in a mixture with other lead compounds (e.g. lead carbonate "white lead") as a pigment in lead paints. The lead compounds were first fused, and the product then ground to fine powder. The powder was then suspended in drying oils (e.g. linseed), to produce e.g. Pattinson's white (PbCl2 2Pb(OH)2) or Turner's yellow (PbCl2 5-7PbO). Turner's yellow is also known as Patent yellow, Cassel yellow, Montpelier yellow, Kassler yellow, mineral yellow, an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halide
In chemistry, a halide (rarely halogenide) is a binary chemical compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluoride, chloride, bromide, iodide, astatide, or theoretically tennesside compound. The alkali metals combine directly with halogens under appropriate conditions forming halides of the general formula, MX (X = F, Cl, Br or I). Many salts are halides; the ''hal-'' syllable in ''halide'' and ''halite'' reflects this correlation. All Group 1 metals form halides that are white solids at room temperature. A halide ion is a halogen atom bearing a negative charge. The halide anions are fluoride (), chloride (), bromide (), iodide () and astatide (). Such ions are present in all ionic halide salts. Halide minerals contain halides. All these halides are colourless, high melting crystalline solids having high negative enthalpies of formation. Test ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Matlockite
Matlockite is a rare lead halide mineral, named after the town of Matlock in Derbyshire, England, where it was first discovered in a nearby mine. Matlockite (chemical formula: PbFCl) gives its name to the matlockite group which consists of rare minerals of a similar structure. Description The mineral, a lead fluorochloride (formula PbFCl), was discovered sometime around the early 1800s at Bage Mine at Bolehill near Matlock, together with specimens of phosgenite and anglesite. Although phosgenite was known at this time, it seems likely that matlockite itself remained unappreciated as a new mineral for some fifty years. It was given the name by Greg in 1851. The first mention of Matlockite may have been in Mawe's Mineralogy of Derbyshire in 1802 in which he gives a detailed description of phosgenite, which is then followed by a mention of a mineral he refers to as "glass lead" - a description which does rather equate to the appearance of matlockite. It is a light, translucent cr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Peroxide
Lead(IV) oxide is the inorganic compound with the formula PbO2. It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries. Properties Physical Lead dioxide has two major polymorphs, alpha and beta, which occur naturally as rare minerals scrutinyite and plattnerite, respectively. Whereas the beta form had been identified in 1845, α-PbO2 was first identified in 1946 and found as a naturally occurring mineral 1988. The alpha form has orthorhombic symmetry, space group Pbcn (No. 60), Pearson symbol ''oP''12, lattice constants ''a'' = 0.497 nm, ''b'' = 0.596 nm, ''c'' = 0.544 nm, ''Z'' = 4 (four formula units per unit cell). The lead atoms are six-coordinate. The symmetry of the beta form is tetragonal, space group P42/mnm (No. 136), Pearson symbol ''tP''6 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Sulfate
Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as ''fast white'', ''milk white'', ''sulfuric acid lead salt'' or ''anglesite''. It is often seen in the plates/electrodes of car batteries, as it is formed when the battery is discharged (when the battery is recharged, then the lead sulfate is transformed back to metallic lead and sulfuric acid on the negative terminal or lead dioxide and sulfuric acid on the positive terminal). Lead sulfate is poorly soluble in water. Manufacturing Lead(II) sulfate is prepared by treating lead oxide, hydroxide or carbonate with warm sulfuric acid or by treating a soluble lead salt with sulfuric acid. Alternatively, it can be made by the interaction of solutions of lead nitrate and sodium sulfate. Toxicology Lead sulfate is toxic by inhalation, ingestion and skin contact. It is a cumulative poison, and repeated exposure may lead to anemia, kidney damage, eyesight damage or damage to the ce ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Charles Francis Brush
Charles Francis Brush (March 17, 1849 – June 15, 1929) was an American engineer, inventor, entrepreneur, and philanthropist. Biography Brush was born in Euclid Township, Ohio to Isaac Elbert Brush and Delia Williams Phillips. Isaac Brush was a distant cousin of Delia on the Phillips side. Through Delia he was a descendant of the Rev. George Phillips, who settled Watertown, Massachusetts in 1630, and Samuel Appleton. Delia was also a descendant of Henry Wisner, member of the First and Second Continental Congresses during the American Revolution, as well as Thomas Cornell (settler) and the Winthrop family. Brush was raised on a farm about 10 miles from downtown Cleveland. He had a great interest in science, particularly with Humphry Davy's experiments with the arc light; he tinkered with and built simple electrical devices such as a static electricity machine at age 12, experimenting in a workshop on his parents' farm. Brush attended Central High School in Cleveland wher ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Drying Oil
A drying oil is an oil that hardens to a tough, solid film after a period of exposure to air, at room temperature. The oil hardens through a chemical reaction in which the components crosslink (and hence, polymerize) by the action of oxygen (not through the evaporation of water or other solvents). Drying oils are a key component of oil paint and some varnishes. Some commonly used drying oils include linseed oil, tung oil, poppy seed oil, perilla oil, and walnut oil. Their use has declined over the past several decades, as they have been replaced by alkyd resins and other binders. Since oxidation is the key to curing in these oils, those that are susceptible to chemical drying are often unsuitable for cooking, and are also highly susceptible to becoming rancid through autoxidation, the process by which fatty foods develop off-flavors. Rags, cloth, and paper saturated with drying oils may spontaneously combust (ignite) after a few hours as heat is released during the oxidation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Paint
Lead paint or lead-based paint is paint containing lead. As pigment, lead(II) chromate (, "chrome yellow"), lead(II,IV) oxide, (, "red lead"), and lead(II) carbonate (, "white lead") are the most common forms.. Lead is added to paint to accelerate drying, increase durability, maintain a fresh appearance, and resist moisture that causes corrosion. It is one of the main health and environmental hazards associated with paint. Lead paint has been generally phased out of use due to the toxic nature of lead. Alternatives such as water-based, lead-free traffic paint are readily available. In some countries, lead continues to be added to paint intended for domestic use, whereas countries such as the United States and the United Kingdom have regulations prohibiting its use. However, lead paint may still be found in older properties painted prior to the introduction of such regulations. Although lead has been banned from household paints in the United States since 1978, it may still be f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
White Lead
White lead is the basic lead carbonate 2PbCO3·Pb(OH)2. It is a complex salt, containing both carbonate and hydroxide ions. White lead occurs naturally as a mineral, in which context it is known as hydrocerussite, a hydrate of cerussite. It was formerly used as an ingredient for lead paint and a cosmetic called Venetian ceruse, because of its opacity and the satiny smooth mixture it made with dryable oils. However, it tended to cause lead poisoning, and its use has been banned in most countries. White lead compounds known as lead soap were also used as additive for lubricants for bearings and in machine shops. Lead soap was also used as an oil drying agent for paints made with drying oil or air drying paints made with alkyd resins. Lead is often used with cobalt driers. Lead free substitutes have been developed to replace this use of lead in paint. History What is commonly known today as the "Dutch method" for the preparation of white lead was described as early as Theoph ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Carbonate
Lead(II) carbonate is the chemical compound with the chemical formula . It is a white solid with several practical uses, despite its toxicity. It occurs naturally as the mineral cerussite. Structure Like all metal carbonates, lead(II) carbonate adopts a dense, highly crosslinked structure consisting of intact and metal cation sites. As verified by X-ray crystallography, the Pb(II) centers are seven-coordinate, being surrounded by multiple carbonate ligands. The carbonate centers are bonded to bidentate to a single Pb and bridge to five other Pb sites. Production and use Lead carbonate is manufactured by passing carbon dioxide into a cold dilute solution of lead(II) acetate, or by shaking a suspension of a lead salt more soluble than the carbonate with ammonium carbonate at a low temperature to avoid formation of basic lead carbonate. : Lead carbonate is used as a catalyst to polymerize formaldehyde to poly(oxymethylene). It improves the bonding of chloroprene to wire. Regulat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Paralaurionite
Paralaurionite is a colorless mineral consisting of a basic lead chloride PbCl(OH) that is dimorphous with laurionite. It is a member of the matlockite group. The name is derived from para-, the Greek for "near", and laurionite, because of its polymorphic relationship to it. Bright, yellow tips of thorikosite can form on paralaurionite crystals and paralaurionite may also be intergrown with mendipite. Occurrence It was first described in 1899 for an occurrence in slag in Laurium, Attica, Greece. In 1952 an occurrences of it was reported from the Mammoth Mine, Arizona. It occurs in lead bearing slag which has been exposed to seawater. It also occurs in polymetallic ore deposits. It occurs associated with laurionite, penfieldite, fiedlerite, phosgenite in slag deposits; and with leadhillite, matlockite, cerussite, hydrocerussite, diaboleite Diaboleite is a blue-colored mineral with formula Pb2CuCl2(OH)4. It was discovered in England in 1923 and named ''diaboleite'', from the Gr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laurionite
Laurionite (PbCl(OH)) is a lead halide mineral. It forms colorless to white crystals in the orthorhombic crystal system and is dimorphous with paralaurionite, both members of the matlockite group. It was first described in 1887 for an occurrence in the Laurium District, Attica, Greece, and named after the town Laurium. It occurs as an oxidation product in lead ore deposits, and is also produced on lead-bearing slag by reaction with saline solutions. It occurs associated with paralaurionite, penfieldite, fiedlerite, phosgenite, cerussite and anglesite Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and .... References Halide minerals Orthorhombic minerals Minerals in space group 62 Lead minerals {{halide-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
