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Lead(IV) Hydroxide
Lead(IV) hydroxide, , also called ortho-plumbic acid, is the notional conjugate acid of the ortho- plumbate(IV) ion, , found in compounds such as calcium orthoplumbate, . Like its tin analog , has not been isolated. References Hydroxides Lead(IV) compounds Hypothetical chemical compounds {{Base-stub ...
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Plumbate
In chemistry, a plumbate often refers to compounds that can be viewed as derivatives of the hypothetical anion. The term also refers to any anion of lead or any salt thereof. So the term is vague and somewhat archaic. Examples Halides Salts of , , , etc. are labeled as iodoplumbates. Lead perovskite semiconductors are often described as plumbates. Lead oxyanions Plumbates are formed by the reaction of lead(IV) oxide, , with alkali. Plumbate salts contain either the hydrated ''hexahydroxoplumbate(IV)'' or ''plumbate'' anion , or the anhydrous anions (''meta-plumbate'') or (''ortho-plumbate''). For example, dissolving in a hot, concentrated aqueous solution of potassium hydroxide forms the potassium hexahydroxoplumbate(IV) salt . The anhydrous salts may be synthesized by heating metal oxides or hydroxides with . The most widely discussed plumbates are derivatives of barium plumbate . When doped with some bismuth in place of lead, the material exhibits superconductivity at 13 K. ...
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Calcium Orthoplumbate
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth's crust, and the third most abundant metal, after iron and aluminium. The most common calcium compound on Earth is calcium carbonate, found in limestone and the fossilised remnants of early sea life; gypsum, anhydrite, fluorite, and apatite are also sources of calcium. The name derives from Latin ''calx'' " lime", which was obtained from heating limestone. Some calcium compounds were known to the ancients, though their chemistry was unknown until the seventeenth century. Pure calcium was isolated in 1808 via electrolysis of its oxide by Humphry Davy, who named the element. Calcium compounds are widely used in many industries: in foods an ...
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Hydroxides
Hydroxide is a polyatomic ion, diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually Self-ionization of water, minor constituent of water. It functions as a base (chemistry), base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salt (chemistry), salts, some of which dissociation (chemistry), dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemicals, commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalent bond, covalently bound functional group, group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names ...
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Lead(IV) Compounds
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the grou ...
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