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Laundry Sour
A laundry sour is a chemical added to clothing during the final rinse cycle of a washing machine to lower the pH of the water and to assist with the removal of detergents and rust stains. Most such sours are fluoride-based, including ammonium silicofluoride, ammonium bifluoride, and hydrofluosilicic acid; glycolic acid Glycolic acid (or hydroxyacetic acid; chemical formula HOCH2CO2H) is a colorless, odorless and hygroscopic crystalline solid, highly soluble in water. It is used in various skin-care products. Glycolic acid is widespread in nature. A glycolate (s ... is also used. The US Department of Defense recognizes two "types" of laundry sours: type I is sodium silicofluoride and sodium acid fluoride in powdered, crystal, or flake form; type II is ammonium bifluoride in flake form. References {{reflist Laundry substances ...
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Washing Machine
A washing machine (laundry machine, clothes washer, washer, or simply wash) is a home appliance used to wash laundry. The term is mostly applied to machines that use water as opposed to dry cleaning (which uses alternative cleaning fluids and is performed by specialist businesses) or ultrasonic cleaners. The user adds laundry detergent, which is sold in liquid or powder form, to the wash water. History Washing by hand Laundering by hand involves soaking, beating, scrubbing, and rinsing dirty textiles. Before indoor plumbing, individuals also had to carry all the water used for washing, boiling, and rinsing the laundry from a pump, well, or spring. Water for the laundry would be hand carried, heated on a fire for washing, then poured into the tub. That made the warm soapy water precious; it would be reused, first to wash the least soiled clothing, then to wash progressively dirtier laundry. Removal of soap and water from the clothing after washing was a separate process. Fi ...
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Fluoride
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nom ...
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Ammonium Silicofluoride
Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid.Wiberg, E., Wiberg, N., and Holleman, A. F. (2001) ''Inorganic chemistry''. Academic Press, San Diego. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite. Structure Ammonium fluorosilicate has three major polymorphs: α-(NH4)2 iF6form is cubic (space group Fm3m, No. 225) and corresponds to the mineral cryptohalite. The β form is trigonal (scalenohedral) and occurs in nature as mineral bararite. A third (γ) form was discovered in 2001 and identified with the hexagonal 6mm symmetry. In all three configurations, the iF6sup>2− octahedra are arranged in layers. In the α form, these layers are perpendicular to 11directions. In the β- and γ- forms, the layers are perpendicular to the c-axis. ( ...
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Ammonium Bifluoride
Ammonium hydrogen fluoride is the inorganic compound with the formula or . It is produced from ammonia and hydrogen fluoride. This colourless salt is a glass- etchant and an intermediate in a once-contemplated route to hydrofluoric acid. Structure Ammonium bifluoride, as its name indicates, contains an ammonium cation (), and a bifluoride or hydrogen(difluoride) anion (). The centrosymmetric triatomic bifluoride anion features the strongest known hydrogen bond, with a F− H length of 114 pm. and a bond energy greater than 155 kJ/mol. In solid , each ammonium cation is surrounded by four fluoride centers in a tetrahedron, with hydrogen-fluorine hydrogen bonds present between the hydrogen atoms of the ammonium ion and the fluorine atoms. Solutions contain tetrahedral cations and linear anions. Production and applications Ammonium bifluoride is a component of some etchants. It attacks silica component of glass: : Potassium bifluoride is a related more commonly used etc ...
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Hydrofluosilicic Acid
Hexafluorosilicic acid is an inorganic compound with the chemical formula . Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless. Hexafluorosilicic acid is produced naturally on a large scale in volcanoes.Palache, C., Berman, H., and Frondel, C. (1951) Dana’s System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, etc. John Wiley and Sons, Inc., New York, 7th edition.Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (1997) Handbook of Mineralogy, Volume III: Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson.link to bararite It is manufactured as a coproduct in the production of phosphate fertilizers. The resulting hexafluorosilicic acid is almost exclusively consumed as a precursor to aluminum trifluoride and synthetic cryolite, which are used in aluminium processing. Salts d ...
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Glycolic Acid
Glycolic acid (or hydroxyacetic acid; chemical formula HOCH2CO2H) is a colorless, odorless and hygroscopic crystalline solid, highly soluble in water. It is used in various skin-care products. Glycolic acid is widespread in nature. A glycolate (sometimes spelled "glycollate") is a salt or ester of glycolic acid. History The name "glycolic acid" was coined in 1848 by French chemist Auguste Laurent (1807–1853). He proposed that the amino acid glycine—which was then called ''glycocolle''—might be the amine of a hypothetical acid, which he called "glycolic acid" (''acide glycolique''). Glycolic acid was first prepared in 1851 by German chemist Adolph Strecker (1822–1871) and Russian chemist Nikolai Nikolaevich Sokolov (1826–1877). They produced it by treating hippuric acid with nitric acid and nitrogen dioxide to form an ester of benzoic acid and glycolic acid (C6H5C(=O)OCH2COOH), which they called "benzoglycolic acid" (''Benzoglykolsäure''; also benzoyl glycolic acid). ...
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Sodium Fluorosilicate
Sodium fluorosilicate is a compound with the chemical formula Na2 iF6 Natural occurrence Sodium hexafluorosilicate occurs naturally as the rare mineral malladrite found within some volcanic fumaroles. Manufacturing Sodium fluorosilicate is made by neutralizing fluorosilicic acid with sodium chloride or sodium sulfate. :H2 iF6+ 2 NaCl → Na2 iF6+ 2 HCl Possible application It is used in some countries as additives for water fluoridation, opal glass raw material, ore refining, or other fluoride chemical (like sodium fluoride, magnesium silicofluoride, cryolite, aluminum fluoride) production. See also * Fluorosilicic acid Hexafluorosilicic acid is an inorganic compound with the chemical formula . Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless. Hexaflu ... * Ammonium fluorosilicate References {{silicon compounds Sodium compounds Hexafluorosilicates
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Sodium Acid Fluoride
Sodium bifluoride is the inorganic compound with the formula . It is a salt of sodium cation () and bifluoride anion (). It is a white, water-soluble solid that decomposes upon heating . Sodium bifluoride is non-flammable, hygroscopic, and has a pungent smell. Sodium bifluoride has a number of applications in industry. Reactions Sodium bifluoride dissociates to hydrofluoric acid and sodium fluoride: : The reverse of this reaction is employed to remove HF from elemental fluorine () produced by electrolysis. This equilibrium is manifested when the salt is dissolved and when the solid is heated. Characteristic of other bifluorides, it reacts with acids to give HF. Illustrative is its reaction with bisulfate to form sodium sulfate and hydrogen fluoride. Strong bases deprotonate bifluoride. For example, calcium hydroxide gives calcium fluoride. Production Sodium bifluoride is produced by neutralizing waste hydrogen fluoride, which results from the production of superphosphate ...
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