Laplace Expansion (potential)
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Laplace Expansion (potential)
In physics, the Laplace expansion of potentials that are directly proportional to the inverse of the distance ( 1/r ), such as Newton's gravitational potential or Coulomb's electrostatic potential, expresses them in terms of the spherical Legendre polynomials. In quantum mechanical calculations on atoms the expansion is used in the evaluation of integrals of the inter-electronic repulsion. The Laplace expansion is in fact the expansion of the inverse distance between two points. Let the points have position vectors \textbf and \textbf' , then the Laplace expansion is : \frac = \sum_^\infty \frac \sum_^ (-1)^m \frac Y^_\ell(\theta, \varphi) Y^m_\ell(\theta', \varphi'). Here \textbf has the spherical polar coordinates (r, \theta, \varphi) and \textbf' has (r', \theta', \varphi') with homogeneous polynomials of degree \ell . Further ''r''< is min(''r'', ''r''′) and ''r''> is max(''r'', ''r''′). The function Y^m_\ell is a normalized ...
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Newton's Law Of Universal Gravitation
Newton's law of universal gravitation is usually stated as that every particle attracts every other particle in the universe with a force that is proportional to the product of their masses and inversely proportional to the square of the distance between their centers.It was shown separately that separated spherically symmetrical masses attract and are attracted as if all their mass were concentrated at their centers. The publication of the law has become known as the " first great unification", as it marked the unification of the previously described phenomena of gravity on Earth with known astronomical behaviors. This is a general physical law derived from empirical observations by what Isaac Newton called inductive reasoning. It is a part of classical mechanics and was formulated in Newton's work '' Philosophiæ Naturalis Principia Mathematica'' ("the ''Principia''"), first published on 5 July 1687. When Newton presented Book 1 of the unpublished text in April 1686 to the Ro ...
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Coulomb's Law
Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is conventionally called ''electrostatic force'' or Coulomb force. Although the law was known earlier, it was first published in 1785 by French physicist Charles-Augustin de Coulomb, hence the name. Coulomb's law was essential to the development of the theory of electromagnetism, maybe even its starting point, as it made it possible to discuss the quantity of electric charge in a meaningful way. The law states that the magnitude of the electrostatic force of attraction or repulsion between two point charges is directly proportional to the product of the magnitudes of charges and inversely proportional to the square of the distance between them. Coulomb studied the repulsive force between bodies having electrical charges of the same sign: Coulomb also ...
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Spherical Harmonics
In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. Since the spherical harmonics form a complete set of orthogonal functions and thus an orthonormal basis, each function defined on the surface of a sphere can be written as a sum of these spherical harmonics. This is similar to periodic functions defined on a circle that can be expressed as a sum of circular functions (sines and cosines) via Fourier series. Like the sines and cosines in Fourier series, the spherical harmonics may be organized by (spatial) angular frequency, as seen in the rows of functions in the illustration on the right. Further, spherical harmonics are basis functions for irreducible representations of SO(3), the group of rotations in three dimensions, and thus play a central role in the group theoretic discussion of SO(3). Spherical harmonics originate ...
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Solid Harmonics
In physics and mathematics, the solid harmonics are solutions of the Laplace equation in spherical polar coordinates, assumed to be (smooth) functions \mathbb^3 \to \mathbb. There are two kinds: the ''regular solid harmonics'' R^m_\ell(\mathbf), which are well-defined at the origin and the ''irregular solid harmonics'' I^m_(\mathbf), which are singular at the origin. Both sets of functions play an important role in potential theory, and are obtained by rescaling spherical harmonics appropriately: R^m_(\mathbf) \equiv \sqrt\; r^\ell Y^m_(\theta,\varphi) I^m_(\mathbf) \equiv \sqrt \; \frac Derivation, relation to spherical harmonics Introducing , , and for the spherical polar coordinates of the 3-vector , and assuming that \Phi is a (smooth) function \mathbb^3 \to \mathbb, we can write the Laplace equation in the following form \nabla^2\Phi(\mathbf) = \left(\frac \fracr - \frac\right)\Phi(\mathbf) = 0 , \qquad \mathbf \ne \mathbf, where is the square of the nondimensional ...
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Law Of Cosines
In trigonometry, the law of cosines (also known as the cosine formula, cosine rule, or al-Kashi's theorem) relates the lengths of the sides of a triangle to the cosine of one of its angles. Using notation as in Fig. 1, the law of cosines states :c^2 = a^2 + b^2 - 2ab\cos\gamma, where denotes the angle contained between sides of lengths and and opposite the side of length . For the same figure, the other two relations are analogous: :a^2=b^2+c^2-2bc\cos\alpha, :b^2=a^2+c^2-2ac\cos\beta. The law of cosines generalizes the Pythagorean theorem, which holds only for right triangles: if the angle is a right angle (of measure 90 degrees, or radians), then , and thus the law of cosines reduces to the Pythagorean theorem: :c^2 = a^2 + b^2. The law of cosines is useful for computing the third side of a triangle when two sides and their enclosed angle are known. History Though the notion of the cosine was not yet developed in his time, Euclid's '' Elements'', dating back to th ...
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Legendre Polynomials
In physical science and mathematics, Legendre polynomials (named after Adrien-Marie Legendre, who discovered them in 1782) are a system of complete and orthogonal polynomials, with a vast number of mathematical properties, and numerous applications. They can be defined in many ways, and the various definitions highlight different aspects as well as suggest generalizations and connections to different mathematical structures and physical and numerical applications. Closely related to the Legendre polynomials are associated Legendre polynomials, Legendre functions, Legendre functions of the second kind, and associated Legendre functions. Definition by construction as an orthogonal system In this approach, the polynomials are defined as an orthogonal system with respect to the weight function w(x) = 1 over the interval 1,1/math>. That is, P_n(x) is a polynomial of degree n, such that \int_^1 P_m(x) P_n(x) \,dx = 0 \quad \text n \ne m. With the additional standardization co ...
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Spherical Multipole Moments
Spherical multipole moments are the coefficients in a series expansion of a potential that varies inversely with the distance R to a source, ''i.e.'', as 1/''R''. Examples of such potentials are the electric potential, the magnetic potential and the gravitational potential. For clarity, we illustrate the expansion for a point charge, then generalize to an arbitrary charge density \rho(\mathbf r'). Through this article, the primed coordinates such as \mathbf r' refer to the position of charge(s), whereas the unprimed coordinates such as \mathbf refer to the point at which the potential is being observed. We also use spherical coordinates throughout, e.g., the vector \mathbf r' has coordinates ( r', \theta', \phi') where r' is the radius, \theta' is the colatitude and \phi' is the azimuthal angle. Spherical multipole moments of a point charge The electric potential due to a point charge located at \mathbf is given by \Phi(\mathbf) = \frac \frac = \frac \frac. where R \ ...
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Prolate Spheroidal Coordinates
Prolate spheroidal coordinates are a three-dimensional orthogonal coordinate system that results from rotating the two-dimensional elliptic coordinate system about the focal axis of the ellipse, i.e., the symmetry axis on which the foci are located. Rotation about the other axis produces oblate spheroidal coordinates. Prolate spheroidal coordinates can also be considered as a limiting case of ellipsoidal coordinates in which the two smallest principal axes are equal in length. Prolate spheroidal coordinates can be used to solve various partial differential equations in which the boundary conditions match its symmetry and shape, such as solving for a field produced by two centers, which are taken as the foci on the ''z''-axis. One example is solving for the wavefunction of an electron moving in the electromagnetic field of two positively charged nuclei, as in the hydrogen molecular ion, H2+. Another example is solving for the electric field generated by two small electro ...
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Potential Theory
In mathematics and mathematical physics, potential theory is the study of harmonic functions. The term "potential theory" was coined in 19th-century physics when it was realized that two fundamental forces of nature known at the time, namely gravity and the electrostatic force, could be modeled using functions called the gravitational potential and electrostatic potential, both of which satisfy Poisson's equation—or in the vacuum, Laplace's equation. There is considerable overlap between potential theory and the theory of Poisson's equation to the extent that it is impossible to draw a distinction between these two fields. The difference is more one of emphasis than subject matter and rests on the following distinction: potential theory focuses on the properties of the functions as opposed to the properties of the equation. For example, a result about the singularities of harmonic functions would be said to belong to potential theory whilst a result on how the solution depends ...
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Atomic Physics
Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned with the way in which electrons are arranged around the nucleus and the processes by which these arrangements change. This comprises ions, neutral atoms and, unless otherwise stated, it can be assumed that the term ''atom'' includes ions. The term ''atomic physics'' can be associated with nuclear power and nuclear weapons, due to the synonymous use of ''atomic'' and ''nuclear'' in standard English. Physicists distinguish between atomic physics—which deals with the atom as a system consisting of a nucleus and electrons—and nuclear physics, which studies nuclear reactions and special properties of atomic nuclei. As with many scientific fields, strict delineation can be highly contrived and atomic physics is often considered in the wider c ...
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