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Labeling Of Fertilizers
Many countries have standardized the labeling of fertilizers to indicate their contents of major nutrients. The most common labeling convention, the NPK or N-P-K label, shows the amounts of the chemical elements nitrogen, phosphorus, and potassium. Common labeling conventions The NPK analysis label Fertilizers are usually labeled with three numbers, as in 18-20-10, indicating the relative content of the primary macronutrients nitrogen (N), phosphorus (P), and potassium (K), respectively. More precisely, the first number ("N value") is the percentage of elemental nitrogen by weight in the fertilizer; that is, the mass fraction of nitrogen times 100. The second number ("P value") is the percentage by weight of phosphorus pentoxide in a fertilizer with the same amount of phosphorus that gets all of its phosphorus from P2O5. The third number ("K value") is analogous, based on the equivalent content of potassium oxide . For example, a 15-13-20 fertilizer would contain 15% by w ...
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Chemical Elements
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler substances by any chemical reaction. The number of protons in the nucleus is the defining property of an element, and is referred to as its atomic number (represented by the symbol ''Z'') – all atoms with the same atomic number are atoms of the same element. Almost all of the baryonic matter of the universe is composed of chemical elements (among rare exceptions are neutron stars). When different elements undergo chemical reactions, atoms are rearranged into new compounds held together by chemical bonds. Only a minority of elements, such as silver and gold, are found uncombined as relatively pure native element minerals. Nearly all other naturally occurring elements occur in the Earth as compounds or mixtures. Air is primarily a mixture ...
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Isobutylidenediurea
Isobutylidenediurea (abbreviated IBDU) is an organic compound with the formula (CH3)2CHCH2. It is a derivative of urea (OC(NH2)2), which itself is highly soluble in water, but IBDU is not. It functions as a controlled-release fertiliser owing to its low solubility, which limits the rate of its hydrolysis to urea, which is a fast-acting fertiliser. It is produced by the condensation reaction of isobutyraldehyde and two equivalents of urea: : (CH3)2CHCHO + 2 OC(NH2)2 → (CH3)2CHCH2 + H2O The controlled-release process is the reverse of the above reaction, which only occurs after the IBDU dissolves. Related materials A number of CRF's have been developed based on urea. Related to IBDU is crotonylidene diurea (Crotodur). Simpler are various urea-formaldehyde materials such as ureaform, which consists of methylene diurea Methylene diurea (MDU) is the organic compound with the formula CH2(NHC(O)NH2)2. It is a white water-soluble solid. The compound is formed by the co ...
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Kainite
Kainite ( or ) (KMg(SO4)Cl·3H2O) is an evaporite mineral in the class of "Sulfates (selenates, etc.) with additional anions, with H2O" according to the Nickel–Strunz classification. It is a hydrated potassium-magnesium sulfate-chloride, naturally occurring in irregular granular masses or as crystalline coatings in cavities or fissures. This mineral is dull and soft, and is colored white, yellowish, grey, reddish, or blue to violet. Its name is derived from Greek καινος ainos("(hitherto) unknown"), as it was the first mineral discovered that contained both sulfate and chloride as anions. Kainite forms monoclinic crystals. Properties Kainite is of bitter taste and soluble in water. On recrystallization picromerite is deposited from the solution. Genesis and occurrence Kainite was discovered in the Stassfurt salt mines in today's Saxony-Anhalt, Germany in 1865 by the mine official Schöne and was first described by Carl Friedrich Jacob Zincken. Kainite is a typic ...
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Potassium Chloride
Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. KCl is used as a fertilizer, in medicine, in scientific applications, domestic water softeners (as a substitute for sodium chloride salt), and in food processing, where it may be known as E number additive E508. It occurs naturally as the mineral sylvite, and in combination with sodium chloride as sylvinite. Uses Fertilizer The majority of the potassium chloride produced is used for making fertilizer, called potash, since the growth of many plants is limited by potassium availability. Potassium chloride sold as fertilizer is known as muriate of potash (MOP). The vast majority of potash fertilizer worldwide is sold as MOP. Medical use Potassium is vital ...
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Guano
Guano (Spanish from qu, wanu) is the accumulated excrement of seabirds or bats. As a manure, guano is a highly effective fertilizer due to the high content of nitrogen, phosphate, and potassium, all key nutrients essential for plant growth. Guano was also, to a lesser extent, sought for the production of gunpowder and other explosive materials. The 19th-century seabird guano trade played a pivotal role in the development of modern input-intensive farming. The demand for guano spurred the human colonization of remote bird islands in many parts of the world. Unsustainable seabird guano mining processes can result in permanent habitat destruction and the loss of millions of seabirds. Bat guano is found in caves throughout the world. Many cave ecosystems are wholly dependent on bats to provide nutrients via their guano which supports bacteria, fungi, invertebrates, and vertebrates. The loss of bats from a cave can result in the extinction of species that rely on their guano. U ...
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Guano
Guano (Spanish from qu, wanu) is the accumulated excrement of seabirds or bats. As a manure, guano is a highly effective fertilizer due to the high content of nitrogen, phosphate, and potassium, all key nutrients essential for plant growth. Guano was also, to a lesser extent, sought for the production of gunpowder and other explosive materials. The 19th-century seabird guano trade played a pivotal role in the development of modern input-intensive farming. The demand for guano spurred the human colonization of remote bird islands in many parts of the world. Unsustainable seabird guano mining processes can result in permanent habitat destruction and the loss of millions of seabirds. Bat guano is found in caves throughout the world. Many cave ecosystems are wholly dependent on bats to provide nutrients via their guano which supports bacteria, fungi, invertebrates, and vertebrates. The loss of bats from a cave can result in the extinction of species that rely on their guano. U ...
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Triple Superphosphate
Triple superphosphate is a component of fertilizer that primarily consists of monocalcium phosphate, Ca(H2PO4)2. Triple superphosphate is obtained by treating phosphate rock with phosphoric acid. Traditional routes for extraction of phosphate rock uses sulfuric acid gives single superphosphate, an approximate 1:1 mixture of Ca(H2PO4)2 and CaSO4 phosphogypsum). Double superphosphate refers to some average of triple- and single superphosphate, resulting from the extraction of phosphate rock with a mixture of phosphoric and sulfuric acids. Many fertilizers are derived from triple superphosphate, e.g. by blending with ammonium sulfate and potassium chloride Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt .... Typical fertilizer-grade triple superphosphate contains 45% P2O5eq, single supe ...
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Superphosphate
Triple superphosphate is a component of fertilizer that primarily consists of monocalcium phosphate, Ca(H2PO4)2. Triple superphosphate is obtained by treating phosphate rock with phosphoric acid. Traditional routes for extraction of phosphate rock uses sulfuric acid gives single superphosphate, an approximate 1:1 mixture of Ca(H2PO4)2 and CaSO4 phosphogypsum). Double superphosphate refers to some average of triple- and single superphosphate, resulting from the extraction of phosphate rock with a mixture of phosphoric and sulfuric acids. Many fertilizers are derived from triple superphosphate, e.g. by blending with ammonium sulfate and potassium chloride Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt .... Typical fertilizer-grade triple superphosphate contains 45% P2O5eq, single supe ...
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Potassium Nitrate
Potassium nitrate is a chemical compound with the chemical formula . This alkali metal nitrate salt is also known as Indian saltpetre (large deposits of which were historically mined in India). It is an ionic salt of potassium ions K+ and nitrate ions NO3−, and is therefore an alkali metal nitrate. It occurs in nature as a mineral, niter (or ''nitre'' in the UK). It is a source of nitrogen, and nitrogen was named after niter. Potassium nitrate is one of several nitrogen-containing compounds collectively referred to as saltpeter (or ''saltpetre'' in the UK). Major uses of potassium nitrate are in fertilizers, tree stump removal, rocket propellants and fireworks. It is one of the major constituents of gunpowder (black powder). In processed meats, potassium nitrate reacts with hemoglobin and myoglobin generating a red color. Etymology Potassium nitrate, because of its early and global use and production, has many names. Hebrew and Egyptian words for it had the consonants n-t-r ...
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Diammonium Phosphate
Diammonium phosphate (DAP; IUPAC name diammonium hydrogen phosphate; chemical formula (NH4)2(HPO4) is one of a series of water-soluble ammonium phosphate salts that can be produced when ammonia reacts with phosphoric acid. Solid diammonium phosphate shows a dissociation pressure of ammonia as given by the following expression and equation: : At 100 °C, the dissociation pressure of diammonium phosphate is approximately 5 mmHg. According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Decomposes to ammonia and monoammonium phosphate at around 70 °C (158 °F). At 155 °C (311 °F), DAP emits phosphorus oxides, nitrogen oxides and ammonia." Uses DAP is used as a fertilizer. When applied as plant food, it temporarily increases the soil pH, but over a long term the treated ground becomes more acidic than before, upon nitrif ...
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Monoammonium Phosphate
Ammonium dihydrogen phosphate (ADP), also known as monoammonium phosphate (MAP) is a chemical compound with the chemical formula (NH4)(H2PO4). ADP is a major ingredient of agricultural fertilizers and some fire extinguishers. It also has significant uses in optics and electronics. Chemical properties Monoammonium phosphate is soluble in water and crystallizes from it as the anhydrous salt in the tetragonal system, as elongated prisms or needles. It is practically insoluble in ethanol.Dejun Xu, Xing Xiong, Lin Yang, Zhiye Zhang, and Xinlong Wang (2016): "Determination of the Solubility of Ammonium Dihydrogen Phosphate in Water-Ethanol System at Different Temperatures from 283.2 to 343.2 K". ''Journal of Chemincal Engineering Data'', volume 61, issue 1, pages 78–82. Solid monoammonium phosphate can be considered stable in practice for temperatures up to 200 °C, when it decomposes into gaseous ammonia and molten phosphoric acid .G. O. Guerrant and D. E. Brown ( ...
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Ammonium Polyphosphate
Ammonium polyphosphate is an inorganic salt of polyphosphoric acid and ammonia containing both chains and possibly branching. Its chemical formula is H4 PO3sub>n(OH)2 showing that each monomer consists of an orthophosphate radical of a phosphorus atom with three oxygens and one negative charge neutralized by an ammonium cation leaving two bonds free to polymerize. In the branched cases some monomers are missing the ammonium anion and instead link to three other monomers. The properties of ammonium polyphosphate depend on the number of monomers in each molecule and to a degree on how often it branches. Shorter chains (n1000), but short polymer chains (''e.g.'' pyro-, tripoly-, and tetrapoly-) are more soluble and show increasing solubility with increasing chain length. Ammonium polyphosphate can be prepared by reacting concentrated phosphoric acid with ammonia. However, iron and aluminum impurities, soluble in concentrated phosphoric acid, form gelatinous precipitates or "slu ...
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