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Köhler Theory
Köhler theory describes the vapor pressure of aqueous aerosol particles in thermodynamic equilibrium with a humid atmosphere. It is used in atmospheric sciences and meteorology to determine the humidity at which a cloud is formed. Köhler theory combines the Kelvin effect, which describes the change in vapor pressure due to a curved surface, with Raoult's Law, which relates the vapor pressure to the solute concentration. It was initially published in 1936 by Hilding Köhler, Professor of Meteorology in the Uppsala University. The Köhler equation relates the saturation ratio S over an aqueous solution droplet of fixed dry mass to its wet diameter D as:S(D)=a_w \exp,with: * S = saturation ratio over the droplet surface defined as S=p_w / p_w^0, where p_w is the water vapor pressure of the solution droplet and p_w^0 is the vapor pressure of pure water with a flat surface * D = diameter of the solution droplet ("wet" diameter) * a_w = water activity of the solution droplet * \sigm ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kohler Curves
Kohler is an occupational surname of German origin. It means "charcoal burner". Notable people with the surname include: * Alan Kohler (born 1952), Australian journalist * Anton Kohler (1907–1961), German chess player * Berthold Kohler (born 1961), German journalist * Charles-Amédée Kohler (1790–1874), Swiss chocolate maker *Ernesto Kohler (1849–1907), flautist and composer *Fred Kohler (1888–1938), American actor * Josef Kohler (1849–1919), German jurist *Juliane Köhler (born 1965), German actress *Jürgen Kohler (born 1965), former German football player *Kaufmann Kohler (1843–1926), Reform rabbi * Klaus J. Kohler, German phonetician * Max J. Kohler (1871–1934), American lawyer * Richie Kohler, shipwreck diver and historian * Robert E. Kohler (born 1937), American chemist and historian of science * Sheila Kohler (born 1941), South African writer Kohler family of Wisconsin * David Kohler, businessman, President and CEO of Kohler Co. * Herbert Kohler Jr., ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Supersaturation
In physical chemistry, supersaturation occurs with a solution (chemistry), solution when the concentration of a solute exceeds the concentration specified by the value of solubility at Solubility equilibrium, equilibrium. Most commonly the term is applied to a solution of a solid in a liquid, but it can also be applied to liquids and gases dissolved in a liquid. A supersaturated solution is in a metastable state; it may return to equilibrium by separation process, separation of the excess of solute from the solution, by dilution of the solution by adding solvent, or by increasing the solubility of the solute in the solvent. History Early studies of the phenomenon were conducted with sodium sulfate, also known as Glauber's Salt because, unusually, the solubility of this salt in water may decrease with increasing temperature. Early studies have been summarised by Tomlinson. It was shown that the crystallization of a supersaturated solution does not simply come from its agitation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cloud And Fog Physics
In meteorology, a cloud is an aerosol consisting of a visible mass of miniature liquid droplets, ice crystals, frozen crystals, or other particulates, particles, suspended in the atmosphere of a planetary body or similar space. Water or various other chemicals may compose the droplets and crystals. On Earth, clouds are formed as a result of saturation of the air when it is cooled to its dew point, or when it gains sufficient moisture (usually in the form of water vapor) from an adjacent source to raise the dew point to the ambient temperature. Clouds are seen in the Earth's homosphere, which includes the troposphere, stratosphere, and mesosphere. Nephology is the science of clouds, which is undertaken in the cloud physics branch of meteorology. The World Meteorological Organization uses two methods of naming clouds in their respective layers of the homosphere, Latin and common name. Genus types in the troposphere, the atmospheric layer closest to Earth's surface, have Latin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Raoult's Law
Raoult's law ( law) is a relation of physical chemistry, with implications in thermodynamics. Proposed by French chemist François-Marie Raoult in 1887, it states that the partial pressure of each component of an ideal mixture of ''liquids'' is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture. In consequence, the relative lowering of vapor pressure of a dilute solution of nonvolatile solute is equal to the mole fraction of solute in the solution. Mathematically, Raoult's law for a single component in an ideal solution is stated as : p_i = p_i^\star x_i where p_i is the partial pressure of the component i in the gaseous mixture above the solution, p_i^\star is the equilibrium vapor pressure of the pure component i, and x_i is the mole fraction of the component i in the liquid or solid solution. Where two volatile liquids A and B are mixed with each other to form a solution, the vapor phase consists of both compo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Particulates
Particulate matter (PM) or particulates are microscopic particles of solid or liquid matter suspension (chemistry), suspended in the atmosphere of Earth, air. An ''aerosol'' is a mixture of particulates and air, as opposed to the particulate matter alone, though it is sometimes defined as a subset of aerosol terminology. Sources of particulate matter can be natural or anthropogenic hazard, anthropogenic. Particulates have impacts on climate and precipitation that adversely affect human health. Types of atmosphere, atmospheric particles include suspended particulate matter; thoracic and respirable particles; inhalable coarse particles, designated PM, which are granularity, coarse particles with a particle size, diameter of 10 micrometre, micrometers (μm) or less; fine particles, designated PM, with a diameter of 2.5 μm or less; ultrafine particles, with a diameter of 100 nm or less; and soot. Airborne particulate matter is a List of IARC Group 1 carcinogens, Group ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cloud Condensation Nuclei
Cloud condensation nuclei (CCNs), also known as cloud seeds, are small particles typically 0.2 μm, or one hundredth the size of a cloud droplet. CCNs are a unique subset of aerosols in the atmosphere on which water vapour condenses. This can affect the radiative properties of clouds and the overall atmosphere. Water vapour requires a non- gaseous surface to make the transition to a liquid; this process is called condensation. In the atmosphere of Earth, this surface presents itself as tiny solid or liquid particles called CCNs. When no CCNs are present, water vapour can be supercooled at about for 5–6 hours before droplets spontaneously form. This is the basis of the cloud chamber for detecting subatomic particles. The concept of CCN (must associate to a supersaturation ratio) is used in cloud seeding, which tries to encourage rainfall by seeding the air with condensation nuclei (CN, which does not associate to supersaturation ratio). It has further been suggested that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ideal Solution
An ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. The enthalpy of mixing is zero as is the volume change on mixing. The vapor pressures of all components obey Raoult's law across the entire range of concentrations, and the activity coefficient (which measures deviation from ideality) is equal to one for each component. The concept of an ideal solution is fundamental to both thermodynamics and chemical thermodynamics and their applications, such as the explanation of colligative properties. Physical origin Ideality of solutions is analogous to ideality for gases, with the important difference that intermolecular interactions in liquids are strong and cannot simply be neglected as they can for ideal gases. Instead we assume that the mean strength of the interactions are the same between all the molecules of the solution. More formally, for a mix of molecules of A and B, then the interacti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van 't Hoff Factor
The van 't Hoff factor (named after Dutch chemist Jacobus Henricus van 't Hoff) is a measure of the effect of a solute on colligative properties such as osmotic pressure, relative lowering in vapor pressure, boiling-point elevation and freezing-point depression. The van 't Hoff factor is the ratio between the ''actual concentration'' of particles produced when the substance is dissolved and the ''formal concentration'' that would be expected from its chemical formula. For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1. For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance. This is true for ideal solutions only, as occasionally ion pairing occurs in solution. At a given instant a small percentage of the ions are paired and count as a single particle. Ion pairing occurs to some extent in all electrolyte solutions. This causes the measured van&nb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dissociation (chemistry)
Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salt (chemistry), salts, or coordination complex, complexes) separate or split into other things such as atoms, ions, or radical (chemistry), radicals, usually in a reversible manner. For instance, when an acid dissolves in water, a covalent bond between an electronegativity, electronegative atom and a hydrogen atom is broken by heterolytic fission, which gives a proton (H+) and a negative ion. Dissociation is the opposite of association or recombination. Dissociation constant For reversible dissociations in a chemical equilibrium :AB A + B the dissociation constant ''K''d is the ratio of dissociated to undissociated compound :K_d = \mathrm where the brackets denote the equilibrium concentrations of the species. Dissociation degree The dissociation degree \alpha is the fraction of original solute molecules that have dissociated. It is usually indicated by the Greek symbol α. More acc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolyte
An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solvent like water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also functi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Relative Humidity
Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation (meteorology), precipitation, dew, or fog to be present. Humidity depends on the temperature and pressure of the system of interest. The same amount of water vapor results in higher relative humidity in cool air than warm air. A related parameter is the dew point. The amount of water vapor needed to achieve saturation increases as the temperature increases. As the temperature of a parcel of air decreases it will eventually reach the saturation point without adding or losing water mass. The amount of water vapor contained within a parcel of air can vary significantly. For example, a parcel of air near saturation may contain 8 g of water per cubic metre of air at , and 28 g of water per cubic metre of air at Three primary measurements of humidity are widely employed: abso ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Sulfate
Ammonium sulfate (American English and international scientific usage; ammonium sulphate in British English); (NH4)2SO4, is an inorganic salt with a number of commercial uses. The most common use is as a soil fertilizer. It contains 21% nitrogen and 24% sulfur. Uses Agriculture The primary use of ammonium sulfate is as a fertilizer for alkaline soils. In the soil, the ammonium ion is released and forms a small amount of acid, lowering the pH balance of the soil, while contributing essential nitrogen for plant growth. One disadvantage to the use of ammonium sulfate is its low nitrogen content relative to ammonium nitrate, which elevates transportation costs. It is also used as an agricultural spray adjuvant for water-soluble insecticides, herbicides, and fungicides. There, it functions to bind iron and calcium cations that are present in both well water and plant cells. It is particularly effective as an adjuvant for 2,4-D (amine), glyphosate, and glufosinate herbicides. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
