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Jacobi Coordinates
In the theory of many-particle systems, Jacobi coordinates often are used to simplify the mathematical formulation. These coordinates are particularly common in treating polyatomic molecules and chemical reactions, and in celestial mechanics Celestial mechanics is the branch of astronomy that deals with the motions of objects in outer space. Historically, celestial mechanics applies principles of physics (classical mechanics) to astronomical objects, such as stars and planets, to .... For example, see An algorithm for generating the Jacobi coordinates for ''N'' bodies may be based upon binary trees. In words, the algorithm is described as follows: Let ''m''''j'' and ''m''''k'' be the masses of two bodies that are replaced by a new body of virtual mass ''M'' = ''m''''j'' + ''m''''k''. The position coordinates x''j'' and x''k'' are replaced by their relative position r''jk'' = x''j'' − x''k'' and by the vector to their center of mass R''jk'' = ('' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Center Of Mass
In physics, the center of mass of a distribution of mass in space (sometimes referred to as the balance point) is the unique point where the weighted relative position of the distributed mass sums to zero. This is the point to which a force may be applied to cause a linear acceleration without an angular acceleration. Calculations in mechanics are often simplified when formulated with respect to the center of mass. It is a hypothetical point where the entire mass of an object may be assumed to be concentrated to visualise its motion. In other words, the center of mass is the particle equivalent of a given object for application of Newton's laws of motion. In the case of a single rigid body, the center of mass is fixed in relation to the body, and if the body has uniform density, it will be located at the centroid. The center of mass may be located outside the physical body, as is sometimes the case for hollow or open-shaped objects, such as a horseshoe. In the case of a dist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lagrangian Mechanics
In physics, Lagrangian mechanics is a formulation of classical mechanics founded on the stationary-action principle (also known as the principle of least action). It was introduced by the Italian-French mathematician and astronomer Joseph-Louis Lagrange in his 1788 work, '' Mécanique analytique''. Lagrangian mechanics describes a mechanical system as a pair (M,L) consisting of a configuration space M and a smooth function L within that space called a ''Lagrangian''. By convention, L = T - V, where T and V are the kinetic and potential energy of the system, respectively. The stationary action principle requires that the action functional of the system derived from L must remain at a stationary point (a maximum, minimum, or saddle) throughout the time evolution of the system. This constraint allows the calculation of the equations of motion of the system using Lagrange's equations. Introduction Suppose there exists a bead sliding around on a wire, or a swinging simple p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hamiltonian Mechanics
Hamiltonian mechanics emerged in 1833 as a reformulation of Lagrangian mechanics. Introduced by Sir William Rowan Hamilton, Hamiltonian mechanics replaces (generalized) velocities \dot q^i used in Lagrangian mechanics with (generalized) ''momenta''. Both theories provide interpretations of classical mechanics and describe the same physical phenomena. Hamiltonian mechanics has a close relationship with geometry (notably, symplectic geometry and Poisson structures) and serves as a link between classical and quantum mechanics. Overview Phase space coordinates (p,q) and Hamiltonian H Let (M, \mathcal L) be a mechanical system with the configuration space M and the smooth Lagrangian \mathcal L. Select a standard coordinate system (\boldsymbol,\boldsymbol) on M. The quantities \textstyle p_i(\boldsymbol,\boldsymbol,t) ~\stackrel~ / are called ''momenta''. (Also ''generalized momenta'', ''conjugate momenta'', and ''canonical momenta''). For a time instant t, the Legendre transformat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Reactions
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of acti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Geometry
Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that determine the position of each atom. Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism and biological activity. The angles between bonds that an atom forms depend only weakly on the rest of molecule, i.e. they can be understood as approximately local and hence transferable properties. Determination The molecular geometry can be determined by various spectroscopic methods and diffraction methods. IR, microwave and Raman spectroscopy can give information about the molecule geometry from the details of the vibrational and rotational absorbance detected by these techniques. X-ray crystallography, neutron diffraction and electron diffraction can give molecular ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Vibration
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 1013 Hz to approximately 1014 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm−1 and wavelengths of approximately 30 to 3 µm. For a diatomic molecule A−B, the vibrational frequency in s−1 is given by \nu = \frac \sqrt , where k is the force constant in dyne/cm or erg/cm2 and μ is the reduced mass given by \frac = \frac+\frac. The vibrational wavenumber in cm−1 is \tilde \;= \frac \sqrt, where c is the speed of light in cm/s. Vibrations of polyatomic molecules are described in terms of normal modes, which are independent of each other, but each normal mode involves simultaneous vibrations of different parts of the molecule. In general, a non-linear molecule with ''N'' atoms has 3''N'' – 6 normal modes of vibration, but a ''linear'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jacobian Matrix And Determinant
In vector calculus, the Jacobian matrix (, ) of a vector-valued function of several variables is the matrix of all its first-order partial derivatives. When this matrix is square, that is, when the function takes the same number of variables as input as the number of vector components of its output, its determinant is referred to as the Jacobian determinant. Both the matrix and (if applicable) the determinant are often referred to simply as the Jacobian in literature. Suppose is a function such that each of its first-order partial derivatives exist on . This function takes a point as input and produces the vector as output. Then the Jacobian matrix of is defined to be an matrix, denoted by , whose th entry is \mathbf J_ = \frac, or explicitly :\mathbf J = \begin \dfrac & \cdots & \dfrac \end = \begin \nabla^ f_1 \\ \vdots \\ \nabla^ f_m \end = \begin \dfrac & \cdots & \dfrac\\ \vdots & \ddots & \vdots\\ \dfrac & \cdots ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
N-body Problem
In physics, the -body problem is the problem of predicting the individual motions of a group of celestial objects interacting with each other gravitationally.Leimanis and Minorsky: Our interest is with Leimanis, who first discusses some history about the -body problem, especially Ms. Kovalevskaya's 1868–1888 twenty-year complex-variables approach, failure; Section 1: "The Dynamics of Rigid Bodies and Mathematical Exterior Ballistics" (Chapter 1, "The motion of a rigid body about a fixed point (Euler and Poisson equations)"; Chapter 2, "Mathematical Exterior Ballistics"), good precursor background to the -body problem; Section 2: "Celestial Mechanics" (Chapter 1, "The Uniformization of the Three-body Problem (Restricted Three-body Problem)"; Chapter 2, "Capture in the Three-Body Problem"; Chapter 3, "Generalized -body Problem"). Solving this problem has been motivated by the desire to understand the motions of the Sun, Moon, planets, and visible stars. In the 20th century, unde ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jacobi Coordinates — Illustration For Four Bodies
Jacobi may refer to: * People with the surname Jacobi Mathematics: * Jacobi sum, a type of character sum * Jacobi method, a method for determining the solutions of a diagonally dominant system of linear equations * Jacobi eigenvalue algorithm, a method for calculating the eigenvalues and eigenvectors of a real symmetric matrix * Jacobi elliptic functions, a set of doubly-periodic functions * Jacobi polynomials, a class of orthogonal polynomials * Jacobi symbol, a generalization of the Legendre symbol * Jacobi coordinates, a simplification of coordinates for an n-body system * Jacobi identity for non-associative binary operations * Jacobi's formula for the derivative of the determinant of a matrix * Jacobi triple product an identity in the theory of theta functions * Jacobi's theorem (other) (various) Other: * Jacobi Medical Center, New York * Jacobi (grape), another name for the French/German wine grape Pinot Noir Précoce * Jacobi (crater), a lunar impact crater in the s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Binary Trees
In computer science, a binary tree is a k-ary k = 2 tree data structure in which each node has at most two children, which are referred to as the ' and the '. A recursive definition using just set theory notions is that a (non-empty) binary tree is a tuple (''L'', ''S'', ''R''), where ''L'' and ''R'' are binary trees or the empty set and ''S'' is a singleton set containing the root. Some authors allow the binary tree to be the empty set as well. From a graph theory perspective, binary (and K-ary) trees as defined here are arborescences. A binary tree may thus be also called a bifurcating arborescence—a term which appears in some very old programming books, before the modern computer science terminology prevailed. It is also possible to interpret a binary tree as an undirected, rather than a directed graph, in which case a binary tree is an ordered, rooted tree. Some authors use rooted binary tree instead of ''binary tree'' to emphasize the fact that the tree is rooted, but ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Princeton University Press
Princeton University Press is an independent publisher with close connections to Princeton University. Its mission is to disseminate scholarship within academia and society at large. The press was founded by Whitney Darrow, with the financial support of Charles Scribner, as a printing press to serve the Princeton community in 1905. Its distinctive building was constructed in 1911 on William Street in Princeton. Its first book was a new 1912 edition of John Witherspoon's ''Lectures on Moral Philosophy.'' History Princeton University Press was founded in 1905 by a recent Princeton graduate, Whitney Darrow, with financial support from another Princetonian, Charles Scribner II. Darrow and Scribner purchased the equipment and assumed the operations of two already existing local publishers, that of the ''Princeton Alumni Weekly'' and the Princeton Press. The new press printed both local newspapers, university documents, ''The Daily Princetonian'', and later added book publishing to it ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
