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Isotopes Of Ruthenium
Naturally occurring ruthenium (44Ru) is composed of seven stable isotopes. Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are 106Ru, with a half-life of 373.59 days; 103Ru, with a half-life of 39.26 days and 97Ru, with a half-life of 2.9 days. Twenty-four other radioisotopes have been characterized with atomic weights ranging from 86.95  u (87Ru) to 119.95 u (120Ru). Most of these have half-lives that are less than five minutes, except 94Ru (half-life: 51.8 minutes), 95Ru (half-life: 1.643 hours), and 105Ru (half-life: 4.44 hours). The primary decay mode before the most abundant isotope, 102Ru, is electron capture and the primary mode after is beta emission. The primary decay product before 102Ru is technetium and the primary product after is rhodium. Because of the very high volatility of ruthenium tetroxide () ruthenium radioactive isotopes with their relative short half-life are considered as the second most hazard ...
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Ruthenium
Ruthenium is a chemical element with the Symbol (chemistry), symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to most other chemicals. Russian-born scientist of Baltic-German ancestry Karl Ernst Claus discovered the element in 1844 at Kazan State University and named ruthenium in honor of Russian Empire, Russia. Ruthenium is usually found as a minor component of platinum ores; the annual production has risen from about 19 tonnes in 2009Summary. Ruthenium
platinum.matthey.com, p. 9 (2009)
to some 35.5 tonnes in 2017. Most ruthenium produced is used in wear-resistant electrical contacts and thick-film resistors. A minor application for ruthenium is in platinu ...
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Iodine-131
Iodine-131 (131I, I-131) is an important radioisotope of iodine discovered by Glenn Seaborg and John Livingood in 1938 at the University of California, Berkeley. It has a radioactive decay half-life of about eight days. It is associated with nuclear energy, medical diagnostic and treatment procedures, and natural gas production. It also plays a major role as a radioactive isotope present in nuclear fission products, and was a significant contributor to the health hazards from open-air atomic bomb testing in the 1950s, and from the Chernobyl disaster, as well as being a large fraction of the contamination hazard in the first weeks in the Fukushima nuclear crisis. This is because 131I is a major fission product of uranium and plutonium, comprising nearly 3% of the total products of fission (by weight). See fission product yield for a comparison with other radioactive fission products. 131I is also a major fission product of uranium-233, produced from thorium. Due to its mode of be ...
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Isotopes Of Ruthenium
Naturally occurring ruthenium (44Ru) is composed of seven stable isotopes. Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are 106Ru, with a half-life of 373.59 days; 103Ru, with a half-life of 39.26 days and 97Ru, with a half-life of 2.9 days. Twenty-four other radioisotopes have been characterized with atomic weights ranging from 86.95  u (87Ru) to 119.95 u (120Ru). Most of these have half-lives that are less than five minutes, except 94Ru (half-life: 51.8 minutes), 95Ru (half-life: 1.643 hours), and 105Ru (half-life: 4.44 hours). The primary decay mode before the most abundant isotope, 102Ru, is electron capture and the primary mode after is beta emission. The primary decay product before 102Ru is technetium and the primary product after is rhodium. Because of the very high volatility of ruthenium tetroxide () ruthenium radioactive isotopes with their relative short half-life are considered as the second most hazard ...
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Atomic Mass
The atomic mass (''m''a or ''m'') is the mass of an atom. Although the SI unit of mass is the kilogram (symbol: kg), atomic mass is often expressed in the non-SI unit dalton (symbol: Da) – equivalently, unified atomic mass unit (u). 1 Da is defined as of the mass of a free carbon-12 atom at rest in its ground state. The protons and neutrons of the nucleus account for nearly all of the total mass of atoms, with the electrons and nuclear binding energy making minor contributions. Thus, the numeric value of the atomic mass when expressed in daltons has nearly the same value as the mass number. Conversion between mass in kilograms and mass in daltons can be done using the atomic mass constant m_= = 1\ \rm . The formula used for conversion is: :1\ = m_ = 1.660\ 539\ 066\ 60(50)\times 10^\ \mathrm , where M_ is the molar mass constant, N_ is the Avogadro constant, and M(^\mathrm) is the experimentally determined molar mass of carbon-12. The relative isotopic mass (see ...
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Neutron Emission
Neutron emission is a mode of radioactive decay in which one or more neutrons are ejected from a nucleus. It occurs in the most neutron-rich/proton-deficient nuclides, and also from excited states of other nuclides as in photoneutron emission and beta-delayed neutron emission. As only a neutron is lost by this process the number of protons remains unchanged, and an atom does not become an atom of a different element, but a different isotope of the same element. Neutrons are also produced in the spontaneous and induced fission of certain heavy nuclides. Spontaneous neutron emission As a consequence of the Pauli exclusion principle, nuclei with an excess of protons or neutrons have a higher average energy per nucleon. Nuclei with a sufficient excess of neutrons have a greater energy than the combination of a free neutron and a nucleus with one less neutron, and therefore can decay by neutron emission. Nuclei which can decay by this process are described as lying beyond the neutron ...
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Fission Product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release of heat energy (kinetic energy of the nuclei), and gamma rays. The two smaller nuclei are the ''fission products''. (See also Fission products (by element)). About 0.2% to 0.4% of fissions are ternary fissions, producing a third light nucleus such as helium-4 (90%) or tritium (7%). The fission products themselves are usually unstable and therefore radioactive. Due to being relatively neutron-rich for their atomic number, many of them quickly undergo beta decay. This releases additional energy in the form of beta particles, antineutrinos, and gamma rays. Thus, fission events normally result in beta and gamma radiation, even though this radiation is not produced directly by the fission event itself. The produced radionuclides have varyi ...
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Spontaneous Fission
Spontaneous fission (SF) is a form of radioactive decay that is found only in very heavy chemical elements. The nuclear binding energy of the elements reaches its maximum at an atomic mass number of about 56 (e.g., iron-56); spontaneous breakdown into smaller nuclei and a few isolated nuclear particles becomes possible at greater atomic mass numbers. History By 1908, physicists understood that alpha decay involved ejection of helium nuclei from a decaying atom. Like cluster decay, alpha decay is not typically categorized as a process of fission. The first nuclear fission process discovered was fission induced by neutrons. Because cosmic rays produce some neutrons, it was difficult to distinguish between induced and spontaneous events. Cosmic rays can be reliably shielded by a thick layer of rock or water. Spontaneous fission was identified in 1940 by Soviet physicists Georgy Flyorov and Konstantin Petrzhak by their observations of uranium in the Moscow Metro Dinamo station ...
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Observationally Stable
Stable nuclides are nuclides that are not radioactive and so (unlike radionuclides) do not spontaneously undergo radioactive decay. When such nuclides are referred to in relation to specific elements, they are usually termed stable isotopes. The 80 elements with one or more stable isotopes comprise a total of 251 nuclides that have not been known to decay using current equipment (see list at the end of this article). Of these 80 elements, 26 have only one stable isotope; they are thus termed monoisotopic. The rest have more than one stable isotope. Tin has ten stable isotopes, the largest number of stable isotopes known for an element. Definition of stability, and naturally occurring nuclides Most naturally occurring nuclides are stable (about 251; see list at the end of this article), and about 34 more (total of 286) are known to be radioactive with sufficiently long half-lives (also known) to occur primordially. If the half-life of a nuclide is comparable to, or greater ...
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Proton Emission
Proton emission (also known as proton radioactivity) is a rare type of radioactive decay in which a proton is ejected from a nucleus. Proton emission can occur from high-lying excited states in a nucleus following a beta decay, in which case the process is known as beta-delayed proton emission, or can occur from the ground state (or a low-lying isomer) of very proton-rich nuclei, in which case the process is very similar to alpha decay. For a proton to escape a nucleus, the proton separation energy must be negative—the proton is therefore unbound, and tunnels out of the nucleus in a finite time. Proton emission is not seen in naturally occurring isotopes; proton emitters can be produced via nuclear reactions, usually using linear particle accelerators. Although prompt (i.e. not beta-delayed) proton emission was observed from an isomer in cobalt-53 as early as 1969, no other proton-emitting states were found until 1981, when the proton radioactive ground states of lutetium-15 ...
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Isomeric Transition
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy higher energy levels than in the ground state of the same nucleus. "Metastable" describes nuclei whose excited states have half-lives 100 to 1000 times longer than the half-lives of the excited nuclear states that decay with a "prompt" half life (ordinarily on the order of 10−12 seconds). The term "metastable" is usually restricted to isomers with half-lives of 10−9 seconds or longer. Some references recommend 5 × 10−9 seconds to distinguish the metastable half life from the normal "prompt" gamma-emission half-life. Occasionally the half-lives are far longer than this and can last minutes, hours, or years. For example, the nuclear isomer survives so long (at least 1015 years) that it has never been observed to decay spontaneously. The half-life of a nuclear isomer can even exceed that of the ground state of the same nuclide, as shown by as well as , ...
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Beta Decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino; or, conversely a proton is converted into a neutron by the emission of a positron with a neutrino in so-called ''positron emission''. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability. For either electron or positron em ...
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Ruthenium Tetroxide
Ruthenium tetroxide is the inorganic compound with the formula RuO4. It is a yellow volatile solid that melts near room temperature. It has the odor of ozone. Samples are typically black due to impurities. The analogous OsO4 is more widely used and better known. One of the few solvents in which RuO4 forms stable solutions is CCl4. Preparation RuO4 is prepared by oxidation of ruthenium(III) chloride with NaIO4. :8 Ru3+(aq) + 5 IO4−(aq) + 12 H2O(l) → 8 RuO4(s) + 5 I−(aq) + 24 H+(aq) Due to its challenging reactivity, RuO4 it is always generated ''in situ'' and used in catalytic quantities, at least in organic reactions. Typically a solution of ruthenium trichloride is oxidized by sodium metaperiodate. Structure RuO4 forms two crystal structures, one with cubic symmetry and another with monoclinic symmetry, isotypic to OsO4. The molecule adopts a tetrahedral geometry, with the Ru–O distances ranging from 169 to 170 pm. Uses Isolation of ruthenium from ...
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