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Isoindenone
Isoindenone is a polycyclic ketone with chemical formula C9H6O. It is a cross-conjugated. It is unstable. See also * Indene * Indenone * Isoindene Isoindene is a flammable polycyclic hydrocarbon with chemical formula C9H8. It is composed of a cyclohexadiene ring fused with a cyclopentadiene ring. See also * Indene * Isoindole * Isoindenone Isoindenone is a polycyclic ketone with chemica ... References Enones {{ketone-stub ...
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Indenone
Indenone is a polycyclic ketone with chemical formula C9H6O. It is composed of a benzene ring fused with a cyclopentenone ring. Indenones can be used as intermediates in the synthesis of more complex molecules. See also * Indene * Isoindenone Isoindenone is a polycyclic ketone with chemical formula C9H6O. It is a cross-conjugated. It is unstable. See also * Indene * Indenone * Isoindene Isoindene is a flammable polycyclic hydrocarbon with chemical formula C9H8. It is composed o ... References Indenes Aromatic ketones {{ketone-stub ...
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Isoindene
Isoindene is a flammable polycyclic hydrocarbon with chemical formula C9H8. It is composed of a cyclohexadiene ring fused with a cyclopentadiene ring. See also * Indene * Isoindole * Isoindenone Isoindenone is a polycyclic ketone with chemical formula C9H6O. It is a cross-conjugated. It is unstable. See also * Indene * Indenone * Isoindene Isoindene is a flammable polycyclic hydrocarbon with chemical formula C9H8. It is composed o ... Polycyclic nonaromatic hydrocarbons {{hydrocarbon-stub ...
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Ketone
In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' is methyl), with the formula . Many ketones are of great importance in biology and in industry. Examples include many sugars (ketoses), many steroids (e.g., testosterone), and the solvent acetone. Nomenclature and etymology The word ''ketone'' is derived from ''Aketon'', an old German word for ''acetone''. According to the rules of IUPAC nomenclature, ketone names are derived by changing the suffix ''-ane'' of the parent alkane to ''-anone''. Typically, the position of the carbonyl group is denoted by a number, but traditional nonsystematic names are still generally used for the most important ketones, for example acetone and benzophenone. These nonsystematic names are considere ...
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Chemical Formula
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include Subscript and superscript, subscripts and superscripts. A chemical formula is not a chemical nomenclature, chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called ''empirical formulae'', which use letters and numbers ind ...
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Cross-conjugation
Cross-conjugation is a special type of conjugation in a molecule, when in a set of three pi bonds only two pi bonds interact with each other by conjugation, while the third one is excluded from interaction. Whereas a normal conjugated system such as a polyene typically has alternating single and double bonds along consecutive atoms, a cross-conjugated system has an alkene unit bonded to one of the middle atoms of another conjugated chain through a single bond. In classical terms, one of the double-bonds branches off rather than continuing consecutively: the main chain is conjugated, and part of that same main chain is conjugated with the side group, but all parts are not conjugated together as strongly. Examples of cross-conjugation can be found in molecules such as benzophenone, divinylketones, ''p''-quinones, dendralenes, radialenes, fullerene, and Indigo dye. The type of conjugation affects reactivity and molecular electronic transition Molecular electronic transitions take pl ...
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Indene
Indene is a flammable polycyclic hydrocarbon with chemical formula . It is composed of a benzene ring fused with a cyclopentene ring. This aromatic liquid is colorless although samples often are pale yellow. The principal industrial use of indene is in the production of indene/coumarone thermoplastic resins. Substituted indenes and their closely related indane derivatives are important structural motifs found in many natural products and biologically active molecules, such as sulindac. Isolation Indene occurs naturally in coal-tar fractions boiling around 175–185 °C. It can be obtained by heating this fraction with sodium to precipitate solid "sodio-indene". This step exploits indene's weak acidity evidenced by its deprotonation by sodium to give the indenyl derivative. The sodio-indene is converted back to indene by steam distillation. Reactivity Indene readily polymerises. Oxidation of indene with acid dichromate yields homophthalic acid (''o''-carboxylphenylace ...
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