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Industrial Dye Degradation
Industrial dye degradation is any of a number of processed by which dyes are broken down, ideally into innocuous products. Many dyes, specifically in the textile industry such as methylene blue or methyl red, are released into ecosystems through water waste. Many of these dyes can be carcinogenic. In paper recycling dyes can be removed from fibres during a deinking stage prior to degradation. Methods Heterogeneous photocataylsis is one approach to the degradation of dyes. As applied to dye-containing effluents from the textile industry, several approaches are standardized for removal or degradation of dyes. These include oxidation, e.g. using air or hydrogen peroxide, ozone, or Fenton chemistry. One challenge is that oxidants can be indiscriminent such that large amounts of reagents can be required (see Chemical oxygen demand). One promising approach combines oxidation with photocatalysis. Reduction is also employed, a standard reagent being dithionite, which traditionally ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Common Industrial Dyes
Common may refer to: Places * Common, a townland in County Tyrone, Northern Ireland * Boston Common, a central public park in Boston, Massachusetts * Cambridge Common, common land area in Cambridge, Massachusetts * Clapham Common, originally common land, now a park in London, UK * Common Moss, a townland in County Tyrone, Northern Ireland * Lexington Common, a common land area in Lexington, Massachusetts * Salem Common Historic District, a common land area in Salem, Massachusetts People * Common (rapper) (born 1972), American hip hop artist, actor, and poet * Andrew Ainslie Common (born 1841), English amateur astronomer * Andrew Common (born 1889), British shipping director * John Common, American songwriter, musician and singer * Thomas Common (born 1850), Scottish translator and literary critic Arts, entertainment, and media * ''Common'' (film), a 2014 BBC One film, written by Jimmy McGovern, on the UK's Joint Enterprise Law * Dol Common, a character in ''The Alchemist'' b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Paper Recycling
The recycling of paper is the process by which waste paper is turned into new paper products. It has a number of important benefits: It saves waste paper from occupying homes of people and producing methane as it breaks down. Because paper fibre contains carbon (originally absorbed by the tree from which it was produced), recycling keeps the carbon locked up for longer and out of the atmosphere. Around two-thirds of all paper products in the US are now recovered and recycled, although it does not all become new paper. After repeated processing the fibres become too short for the production of new paper, which is why virgin fibre (from sustainably farmed trees) is frequently added to the pulp recipe. There are three categories of paper that can be used as feedstocks for making ''recycled paper'': mill broke, pre-consumer waste, and post-consumer waste. ''Mill broke'' is paper trimmings and other paper scrap from the manufacture of paper, and is recycled in a paper mill. ''Pre-c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Deinking
Deinking is the industrial process of removing printing ink from paperfibers of recycled paper to make deinked pulp. The key in the deinking process is the ability to detach ink from the fibers. This is achieved by a combination of mechanical action and chemical means. In Europe the most common process is froth flotation deinking. Paper is one of the main targets for recycling. A concern about recycling wood pulp paper is that the fibers are degraded with each cycle and after being recycled 4–6 times the fibers become too short and weak to be useful in making paper. History Before the invention of the paper machine in 1799 the most common fibre source was recycled fibres from used textiles, hence the name rag paper. The rags were from hemp, linen and cotton. It was not until the introduction of wood pulp in 1843 that paper production was independent of recycled materials. Recycling of used paper before the industrialisation of paper production, rag paper was recycled to m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photocatalysis Dye Degredation
In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a catalyst. In catalyzed photolysis, light is absorbed by an adsorbed substrate. In photogenerated catalysis, the photocatalytic activity depends on the ability of the catalyst to create electron–hole pairs, which generate free radicals (e.g. hydroxyl radicals: •OH) able to undergo secondary reactions. Its practical application was made possible by the discovery of water electrolysis by means of titanium dioxide (). History Early mentions (1911–1938) The earliest mention came in 1911, when German chemist Dr. Alexander Eibner integrated the concept in his research of the illumination of zinc oxide (ZnO) on the bleaching of the dark blue pigment, Prussian blue. Around this time, Bruner and Kozak published an article discussing the deterioration of oxalic acid in the presence of uranyl salts under illumination, while in 1913, Landau published an article explaining the phenomenon of pho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Textile Industry
The textile industry is primarily concerned with the design, production and distribution of yarn, cloth and clothing. The raw material may be natural, or synthetic using products of the chemical industry. Industry process Cotton manufacturing Cotton is the world's most important natural fibre. In the year 2007, the global yield was 25 million tons from 35 million hectares cultivated in more than 50 countries. There are five stages of cotton manufacturing: * Cultivating and Harvesting * Preparatory Processes * Spinning — giving yarn * Weaving — giving fabrics * Finishing — giving textiles Synthetic fibres Artificial fibres can be made by extruding a polymer, through a spinneret (polymers) into a medium where it hardens. Wet spinning (rayon) uses a coagulating medium. In dry spinning (acetate and triacetate), the polymer is contained in a solvent that evaporates in the heated exit chamber. In melt spinning (nylons and polyesters) the extruded polymer is cooled in gas or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%–6% by weight) in water for consumer use, and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or " high-test peroxide", decomposes explosively when heated and has been used as a propellant in rocketry. Hydrogen peroxide is a reactive oxygen species and the simplest peroxide, a compound having an oxygen–oxygen single bond. It decomposes slowly when exposed to light, and rapidly in the presence of organic or reactive compounds. It is typically stored with a stabilizer in a weakly acidic solution in a dark bottle to block light. Hydrogen peroxide is found in biological systems including the human body. Enzymes that use or decompose hydrogen peroxide are classified as peroxidases. Properties The boiling poi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ozone
Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lower atmosphere to (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the latter, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation. Ozone's odour is reminiscent of chlorine, and detectable by many people at concentrations of as little as in air. Ozone's O3 structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetic. In standard conditions, ozone is a pale blue gas that condenses at cryogenic temperatures to a dark blue liquid and finally a violet-black soli ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fenton Chemistry
Fenton's reagent is a solution of hydrogen peroxide (H2O2) with ferrous iron (typically iron(II) sulfate, FeSO4) as a catalyst that is used to oxidize contaminants or waste waters as part of an advanced oxidation process. Fenton's reagent can be used to destroy organic compounds such as trichloroethylene (TCE) and tetrachloroethylene (perchloroethylene, PCE). It was developed in the 1890s by Henry John Horstman Fenton as an analytical reagent. Overview Iron(II) is oxidized by hydrogen peroxide to iron(III), forming a hydroxyl radical and a hydroxide ion in the process. Iron(III) is then reduced back to iron(II) by another molecule of hydrogen peroxide, forming a hydroperoxyl radical and a proton. The net effect is a disproportionation of hydrogen peroxide to create two different oxygen-radical species, with water (H+ + OH−) as a byproduct. The free radicals generated by this process then engage in secondary reactions. For example, the hydroxyl is a powerful, no ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Oxygen Demand
In environmental chemistry, the chemical oxygen demand (COD) is an indicative measure of the amount of oxygen that can be consumed by reactions in a measured solution. It is commonly expressed in mass of oxygen consumed over volume of solution which in SI units is milligrams per litre ( mg/ L). A COD test can be used to easily quantify the amount of organics in water. The most common application of COD is in quantifying the amount of oxidizable pollutants found in surface water (e.g. lakes and rivers) or wastewater. COD is useful in terms of water quality by providing a metric to determine the effect an effluent will have on the receiving body, much like biochemical oxygen demand (BOD). Overview The basis for the COD test is that nearly all organic compounds can be fully oxidized to carbon dioxide with a strong oxidizing agent under acidic conditions. The amount of oxygen required to oxidize an organic compound to carbon dioxide, ammonia, and water is given by: :\mbox_n\mbox_a\mb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photocatalysis
In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a catalyst. In catalyzed photolysis, light is absorbed by an adsorbed substrate. In photogenerated catalysis, the photocatalytic activity depends on the ability of the catalyst to create electron–hole pairs, which generate free radicals (e.g. hydroxyl radicals: •OH) able to undergo secondary reactions. Its practical application was made possible by the discovery of water electrolysis by means of titanium dioxide (). History Early mentions (1911–1938) The earliest mention came in 1911, when German chemist Dr. Alexander Eibner integrated the concept in his research of the illumination of zinc oxide (ZnO) on the bleaching of the dark blue pigment, Prussian blue. Around this time, Bruner and Kozak published an article discussing the deterioration of oxalic acid in the presence of uranyl salts under illumination, while in 1913, Landau published an article explaining the phenomenon of pho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dithionite
The dithionite is the oxyanion with the formula 2O4sup>2−. It is commonly encountered as the salt sodium dithionite. For historical reasons, it is sometimes called hydrosulfite, but it contains no hydrogen and is not a sulfite. The dianion has a steric number of 4 and trigonal pyramidal geometry. Production and reactions In its main applications, dithionite is generally prepared in situ by reduction of sulfur dioxide by sodium borohydride, described by the following idealized equation:. : Dithionite is a reducing agent. At pH 7, the potential is −0.66 V vs NHE. Redox occurs with formation of sulfite: : + 2 H2O → 2 + 2 e− + 2 H+ Dithionite undergoes acid hydrolytic disproportionation to thiosulfate and bisulfite: :2 + H2O → + 2 It also undergoes alkaline hydrolytic disproportionation to sulfite and sulfide: :3 Na2S2O4 + 6 NaOH → 5 Na2SO3 + Na2S + 3 H2O It is formally derived from dithionous acid (H2S2O4), but this acid does not exist i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flocculation
Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from precipitation in that, prior to flocculation, colloids are merely suspended, under the form of a stable dispersion (where the internal phase (solid) is dispersed throughout the external phase (fluid) through mechanical agitation) and are not truly dissolved in solution. Coagulation and flocculation are important processes in water treatment with coagulation aimed to destabilize and aggregate particles through chemical interactions between the coagulant and colloids, and flocculation to sediment the destabilized particles by causing their aggregation into floc. Term definition According to the IUPAC definition, flocculation is "a process of contact and adhesion whereby the particles of a dispersion form larger-size clusters". Flocculation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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