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Hydrogen Safety
Hydrogen safety covers the safe production, handling and use of hydrogen, particularly hydrogen gas fuel and liquid hydrogen. Hydrogen possesses the NFPA 704's highest rating of 4 on the flammability scale because it is flammable when mixed even in small amounts with ordinary air; ignition can occur at a volumetric ratio of hydrogen to air as low as 4% due to the oxygen in the air and the simplicity and chemical properties of the reaction. However, hydrogen has no rating for innate hazard for reactivity or toxicity. The storage and use of hydrogen poses unique challenges due to its ease of leaking as a gaseous fuel, low- energy ignition, wide range of combustible fuel-air mixtures, buoyancy, and its ability to embrittle metals that must be accounted for to ensure safe operation. Liquid hydrogen poses additional challenges due to its increased density and the extremely low temperatures needed to keep it in liquid form. Moreover, its demand and use in industry—as rocket ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Haber Process
The Haber process, also called the Haber–Bosch process, is an artificial nitrogen fixation process and is the main industrial procedure for the production of ammonia today. It is named after its inventors, the German chemists Fritz Haber and Carl Bosch, who developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using a metal catalyst under high temperatures and pressures: : \ce \quad \Delta H^\circ = -91.8~\text Though this reaction is exothermic (i.e. it releases energy, albeit not very much), it results in a decrease in entropy, which is the central reason why it is very challenging to carry out. Before the development of the Haber process, it had been difficult to produce ammonia on an industrial scale, with early methods, such as the Birkeland–Eyde process and the Frank–Caro process, all highly inefficient. During World War I, the Haber process provided Germany with a s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Passive Autocatalytic Recombiner
Passive autocatalytic recombiner (PAR) is a device that removes hydrogen from the containment of a nuclear power plant during an accident. Its purpose is to prevent hydrogen explosions. Recombiners come into action spontaneously as soon as the hydrogen concentration increases. They are passive devices because their operation does not require external energy. Hydrogen may be generated in a nuclear accident if the reactor fuel overheats and zirconium cladding of the fuel rods reacts chemically with steam. If the hydrogen is released from the reactor to the containment, it may get mixed with air and form a flammable or even explosive mixture. A hydrogen explosion could break the containment and cause radioactive materials to be released to the environment. Recombiners aim at removing hydrogen and thereby preventing explosions. Inside a recombiner there are plates or pellets that are coated with platinum or palladium catalyst. On the surface of the catalyst, hydrogen and oxygen molecu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zirconium Alloy
Zirconium alloys are solid solutions of zirconium or other metals, a common subgroup having the trade mark Zircaloy. Zirconium has very low absorption cross-section of thermal neutrons, high hardness, ductility and corrosion resistance. One of the main uses of zirconium alloys is in nuclear technology, as cladding of fuel rods in nuclear reactors, especially water reactors. A typical composition of nuclear-grade zirconium alloys is more than 95 weight percent zirconium and less than 2% of tin, niobium, iron, chromium, nickel and other metals, which are added to improve mechanical properties and corrosion resistance. The water cooling of reactor zirconium alloys elevates requirement for their resistance to oxidation-related nodular corrosion. Furthermore, oxidative reaction of zirconium with water releases hydrogen gas, which partly diffuses into the alloy and forms zirconium hydrides. The hydrides are less dense and are weaker mechanically than the alloy; their formation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Relief Valve
A relief valve or pressure relief valve (PRV) is a type of safety valve used to control or limit the pressure in a system; pressure might otherwise build up and create a process upset, instrument or equipment failure, or fire. The pressure is relieved by allowing the pressurized fluid to flow from an auxiliary passage out of the system. The relief valve is designed or set to open at a predetermined set pressure to protect pressure vessels and other equipment from being subjected to pressures that exceed their design limits. When the set pressure is exceeded, the relief valve becomes the " path of least resistance" as the valve is forced open and a portion of the fluid is diverted through the auxiliary route. In systems containing flammable fluids, the diverted fluid (liquid, gas or liquid-gas mixture) is either recaptured by a low pressure, high-flow vapor recovery system or is routed through a piping system known as a ''flare header'' or ''relief header'' to a central, elevated g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rupture Disc
A rupture disk, also known as a pressure safety disc, burst disc, bursting disc, or burst diaphragm, is a non-reclosing pressure relief safety device that, in most uses, protects a pressure vessel, equipment or system from overpressurization or potentially damaging vacuum conditions. A rupture disk is a type of sacrificial part because it has a one-time-use membrane that fails at a predetermined differential pressure, either positive or vacuum. The membrane is usually made out of metal, but nearly any material (or different materials in layers) can be used to suit a particular application. Rupture disks provide instant response (within milliseconds or microseconds in very small sizes) to an increase or decrease in system pressure, but once the disk has ruptured it will not reseal. Major advantages of the application of rupture disks compared to using pressure relief valves include leak-tightness, cost, response time, size constraints, and ease of maintenance. Rupture disks ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Antistatic Device
An antistatic device is any device that reduces, dampens, or otherwise inhibits electrostatic discharge, or ESD, which is the buildup or discharge of static electricity. ESD can damage electrical components such as computer hard drives, and even ignite flammable liquids and gases. Many methods exist for neutralizing static electricity, varying in use and effectiveness depending on the application. Antistatic agents are chemical compounds that can be added to an object, or the packaging of an object, to help deter the buildup or discharge of static electricity. For the neutralization of static charge in a larger area, such as a factory floor, semiconductor cleanroom or workshop, antistatic systems may utilize electron emission effects such as corona discharge or photoemission that introduce ions into the area that combine with and neutralize any electrically charged object. In many situations, sufficient ESD protection can be achieved with electrical grounding. Symbology Various ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fukushima Daiichi Nuclear Disaster
The was a nuclear accident in 2011 at the Fukushima Daiichi Nuclear Power Plant in Ōkuma, Fukushima, Japan. The proximate cause of the disaster was the 2011 Tōhoku earthquake and tsunami, which occurred on the afternoon of 11 March 2011 and remains the most powerful earthquake ever recorded in Japan. The earthquake triggered a powerful tsunami, with 13–14-meter-high waves damaging the nuclear power plant's emergency diesel generators, leading to a loss of electric power. The result was the most severe nuclear accident since the Chernobyl disaster in 1986, classified as level seven on the International Nuclear Event Scale (INES) after initially being classified as level five, and thus joining Chernobyl as the only other accident to receive such classification. While the 1957 explosion at the Mayak facility was the second worst by radioactivity released, the INES ranks incidents by impact on population, so Chernobyl (335,000 people evacuated) and Fukushima (154,000 evacu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Deflagration
Deflagration (Lat: ''de + flagrare'', "to burn down") is subsonic combustion in which a pre-mixed flame propagates through a mixture of fuel and oxidizer. Deflagrations can only occur in pre-mixed fuels. Most fires found in daily life are diffusion flames. Deflagrations with flame speeds in the range of 1 m/sec differ from detonations which propagate supersonically through shock waves with speeds in the range of 1 km/sec. Applications Deflagrations are often used in engineering applications when the goal is to move an object such as a bullet in a firearm, or a piston in an internal combustion engine with the force of the expanding gas. Deflagration systems and products can also be used in mining, demolition and stone quarrying via gas pressure blasting as a beneficial alternative to high explosives. Flame physics The underlying flame physics can be understood with the help of an idealized model consisting of a uniform one-dimensional tube of unburnt and burned gaseous fuel, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. The detonation velocity , velocity of detonation in solid and liquid explosives is much higher than that in gaseous ones, which allows the wave system to be observed with greater detail (higher Image resolution , resolution). A very wide variety of fuels may occur as gases (e.g. hydrogen), droplet fogs, or dust suspensions. In addition to dioxygen, oxidants can include halogen compounds, ozone, hydrogen peroxide and Nitrogen oxide , oxides of nitrogen. Gaseous detonations are often associated with a mixture of fuel and oxidan ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flammability Limit
Mixtures of dispersed combustible materials (such as gaseous or vaporised fuels, and some dusts) and oxygen in the air will burn only if the fuel concentration lies within well-defined lower and upper bounds determined experimentally, referred to as flammability limits or explosive limits. Combustion can range in violence from deflagration through detonation. Limits vary with temperature and pressure, but are normally expressed in terms of volume percentage at 25 °C and atmospheric pressure. These limits are relevant both in producing and optimising explosion or combustion, as in an engine, or to preventing it, as in uncontrolled explosions of build-ups of combustible gas or dust. Attaining the best combustible or explosive mixture of a fuel and air (the stoichiometric proportion) is important in internal combustion engines such as gasoline or diesel engines. The standard reference work is still that elaborated by Michael George Zabetakis, a fire safety engineering specialist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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