High-performance Plastics
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High-performance Plastics
High-performance plastics are plastics that meet higher requirements than ''standard'' or ''engineering'' plastics. They are more expensive and used in smaller amounts. Definition High performance plastics differ from standard plastics and engineering plastics primarily by their temperature stability, but also by their chemical resistance and mechanical properties, production quantity, and price... There are many synonyms for the term high-performance plastics, such as: high temperature plastics, high-performance polymers, high performance thermoplastics or high-tech plastics. The name high temperature plastics is in use due to their continuous service temperature (CST), which is always higher than 150 °C by definition (although this is not their only feature, as it can be seen above). The term "polymers" is often used instead of "plastics" because both terms are used as synonyms in the field of engineering. If the term "high-performance thermoplastics" is used, it is ...
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Nuclear Technology
Nuclear technology is technology that involves the nuclear reactions of atomic nuclei. Among the notable nuclear technologies are nuclear reactors, nuclear medicine and nuclear weapons. It is also used, among other things, in smoke detectors and gun sights. History and scientific background Discovery The vast majority of common, natural phenomena on Earth only involve gravity and electromagnetism, and not nuclear reactions. This is because atomic nuclei are generally kept apart because they contain positive electrical charges and therefore repel each other. In 1896, Henri Becquerel was investigating phosphorescence in uranium salts when he discovered a new phenomenon which came to be called radioactivity. He, Pierre Curie and Marie Curie began investigating the phenomenon. In the process, they isolated the element radium, which is highly radioactive. They discovered that radioactive materials produce intense, penetrating rays of three distinct sorts, which they labeled al ...
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Linearity
Linearity is the property of a mathematical relationship ('' function'') that can be graphically represented as a straight line. Linearity is closely related to '' proportionality''. Examples in physics include rectilinear motion, the linear relationship of voltage and current in an electrical conductor (Ohm's law), and the relationship of mass and weight. By contrast, more complicated relationships are ''nonlinear''. Generalized for functions in more than one dimension, linearity means the property of a function of being compatible with addition and scaling, also known as the superposition principle. The word linear comes from Latin ''linearis'', "pertaining to or resembling a line". In mathematics In mathematics, a linear map or linear function ''f''(''x'') is a function that satisfies the two properties: * Additivity: . * Homogeneity of degree 1: for all α. These properties are known as the superposition principle. In this definition, ''x'' is not necessarily a r ...
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Electrophilic Synthesis
In chemistry, an electrophile is a chemical species that forms bonds with nucleophiles by accepting an electron pair. Because electrophiles accept electrons, they are Lewis acids. Most electrophiles are positively charged, have an atom that carries a partial positive charge, or have an atom that does not have an octet of electrons. Electrophiles mainly interact with nucleophiles through addition and substitution reactions. Frequently seen electrophiles in organic syntheses include cations such as H+ and NO+, polarized neutral molecules such as HCl, alkyl halides, acyl halides, and carbonyl compounds, polarizable neutral molecules such as Cl2 and Br2, oxidizing agents such as organic peracids, chemical species that do not satisfy the octet rule such as carbenes and radicals, and some Lewis acids such as BH3 and DIBAL. Organic chemistry Addition of halogens These occur between alkenes and electrophiles, often halogens as in halogen addition reactions. Common reaction ...
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Raychem
The Raychem Corporation was founded in Redwood City, California, in 1957 by Paul M. Cook, James B. Meikle, and Richard W. Muchmore. Led by Cook and second-in-command Robert M. Halperin, Raychem became a pioneer of commercial products realized through radiation chemistry. History The original name of the company was RayTherm Wire and Cable and later formed a subsidiary named RayClad Tubes. The company changed names to avoid confusion with Raytheon. The company was a spin-off from SRI International, and their founding technology was wire and cable that used radiation cross-linked polymer insulation targeted at military and aerospace applications. This was the first known use of radiation chemistry for commercial products. The company soon invented heat-shrinkable tubing also targeted at electronic applications. By 1980 the company had expanded to over 30 countries, including a major branch in Swindon, UK and made the Fortune 500 list. It was recognized as one of the fastest-grow ...
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Polycondensation
In polymer chemistry, condensation polymers are any kind of polymers whose process of polymerization involves a condensation reaction (i.e. a small molecule, such as water or methanol, is produced as a byproduct). Condensation polymers are formed by polycondensation, when the polymer is formed by condensation reactions between species of all degrees of polymerization, or by condensative chain polymerization, when the polymer is formed by sequential addition of monomers to an active site in a chain reaction. The main alternative forms of polymerization are chain polymerization and polyaddition, both of which give addition polymers. Condensation polymerization is a form of step-growth polymerization. Linear polymers are produced from bifunctional monomers, i.e. compounds with two reactive end-groups. Common condensation polymers include polyamides, polyacetals, and proteins. Polyamides One important class of condensation polymers are polyamides. They arise from the r ...
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Polyetherimide
Polyetherimide (PEI) is an amorphous, amber-to-transparent thermoplastic with characteristics similar to the related plastic PEEK. When comparing PEI to PEEK, the former is cheaper but has lower impact strength and a tighter temperature range. Due to its adhesive properties and chemical stability it became a popular bed material for FFF 3D printers. Structure The molecular formula of the PEI monomer is and the molecular weight is 592.61 g/mol. It contains phthalimide and bisphenol A sub-units. Properties The glass transition temperature of PEI is 217 °C (422 °F). Its amorphous density at 25 °C is 1.27 g/cm3(.046 lb/in³). It is prone to stress cracking in chlorinated solvent An organochloride, organochlorine compound, chlorocarbon, or chlorinated hydrocarbon is an organic compound containing at least one covalently bonded atom of chlorine. The chloroalkane class (alkanes with one or more hydrogens substituted by chlor ...s. Polyetherimide is ...
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PEEK
Polyether ether ketone (PEEK) is a colourless organic thermoplastic polymer in the polyaryletherketone (PAEK) family, used in engineering applications. The polymer was first developed in November 1978, later being introduced to the market by Victrex PLC, then Imperial Chemical Industries (ICI) in the early 1980s. Synthesis PEEK polymers are obtained by step-growth polymerization by the dialkylation of bisphenolate salts. Typical is the reaction of 4,4'-difluorobenzophenone with the disodium salt of hydroquinone, which is generated in situ by deprotonation with sodium carbonate. The reaction is conducted around 300 °C in polar aprotic solvents - such as diphenyl sulfone. Properties PEEK is a semicrystalline thermoplastic with excellent mechanical and chemical resistance properties that are retained to high temperatures. The processing conditions used to mould PEEK can influence the crystallinity and hence the mechanical properties. Its Young's modulus is 3.6 GP ...
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Market Entry
Market is a term used to describe concepts such as: *Market (economics), system in which parties engage in transactions according to supply and demand *Market economy *Marketplace, a physical marketplace or public market Geography *Märket, an island shared by Finland and Sweden Art, entertainment, and media Films *Market (1965 film), ''Market'' (1965 film), 1965 South Korean film *Market (2003 film), ''Market'' (2003 film), 2003 Hindi film *''The Market: A Tale of Trade'', a Turkish film Television *The Market (TV series), ''The Market'' (TV series), a New Zealand television drama Brands or enterprises *The Market (company), a concept grocery store *The Market, a specialized Safeway Inc., Safeway store Types of economic markets *Agricultural marketing *Emerging market *Energy market *Financial market *Foreign exchange market *Grey market, commodity trade outside of original producer's distribution channel *Media market, geographic area with mostly the same set of media outle ...
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Union Carbide
Union Carbide Corporation is an American chemical corporation wholly owned subsidiary (since February 6, 2001) by Dow Chemical Company. Union Carbide produces chemicals and polymers that undergo one or more further conversions by customers before reaching consumers. Some are high-volume commodities and others are specialty products meeting the needs of smaller markets. Markets served include paints and coatings, packaging, wire and cable, household products, personal care, pharmaceuticals, automotive, textiles, agriculture, and oil and gas. The company is a former component of the Dow Jones Industrial Average. Founded in 1917 as the Union Carbide and Carbon Corporation, from a merger with National Carbon Company, the company's researchers developed an economical way to make ethylene from natural gas liquids, such as ethane and propane, giving birth to the modern petrochemical industry. The company divested consumer products businesses Eveready and Energizer batteries, Gla ...
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Imperial Chemical Industries
Imperial Chemical Industries (ICI) was a British chemical company. It was, for much of its history, the largest manufacturer in Britain. It was formed by the merger of four leading British chemical companies in 1926. Its headquarters were at Millbank in London. ICI was a constituent of the FT 30 and later the FTSE 100 indices. ICI made general chemicals, plastics, paints, pharmaceuticals and speciality products, including food ingredients, speciality polymers, electronic materials, fragrances and flavourings. In 2008, it was acquired by AkzoNobel, which immediately sold parts of ICI to Henkel and integrated ICI's remaining operations within its existing organisation. History Development of the business (1926–1944) The company was founded in December 1926 from the merger of four companies: Brunner Mond, Nobel Explosives, the United Alkali Company, and British Dyestuffs Corporation. It established its head office at Millbank in London in 1928. Competing with DuPo ...
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Philips
Koninklijke Philips N.V. (), commonly shortened to Philips, is a Dutch multinational conglomerate corporation that was founded in Eindhoven in 1891. Since 1997, it has been mostly headquartered in Amsterdam, though the Benelux headquarters is still in Eindhoven. Philips was formerly one of the largest electronics companies in the world, but is currently focused on the area of health technology, having divested its other divisions. The company was founded in 1891 by Gerard Philips and his father Frederik, with their first products being light bulbs. It currently employs around 80,000 people across 100 countries. The company gained its royal honorary title (hence the ''Koninklijke'') in 1998 and dropped the "Electronics" in its name in 2013, due to its refocusing from consumer electronics to healthcare technology. Philips is organized into three main divisions: Personal Health (formerly Philips Consumer Electronics and Philips Domestic Appliances and Personal Care), Connecte ...
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