Heterotheca Subaxillaris
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Heterotheca Subaxillaris
''Heterotheca subaxillaris'', known by the common name camphorweed, is a North American species of flowering plant in the family Asteraceae. It is widespread across much of the United States (from California to Massachusetts) as well as Mexico and Belize. ''Heterotheca subaxillaris'' is a perennial, aromatic herb up to 203 centimeters (80 inches or 6 2/3 feet) in height, often with several erect stems. The stems are hairy to bristly. The inflorescence contains 3-180 flower heads in a flat-topped array. Each head contains 15–35; yellow ray florets surrounding 25–60 disc florets at the center. Chemistry The leaf volatiles from which the name "camphorweed" is derived include camphor, but as a minor constituent (less than 2%); of 41 documented volatiles, for example, caryophyllene, pinene, borneol, myrcene, and limonene Limonene is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the oil of citrus fruit peels. The - ...
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Jean-Baptiste Lamarck
Jean-Baptiste Pierre Antoine de Monet, chevalier de Lamarck (1 August 1744 – 18 December 1829), often known simply as Lamarck (; ), was a French naturalist, biologist, academic, and soldier. He was an early proponent of the idea that biological evolution occurred and proceeded in accordance with Naturalism (philosophy), natural laws. Lamarck fought in the Seven Years' War against Prussia, and was awarded a commission for bravery on the battlefield. Posted to Monaco, Lamarck became interested in natural history and resolved to study medicine.#Packard, Packard (1901), p. 15. He retired from the army after being injured in 1766, and returned to his medical studies. Lamarck developed a particular interest in botany, and later, after he published the three-volume work ''Flore françoise'' (1778), he gained membership of the French Academy of Sciences in 1779. Lamarck became involved in the Jardin des Plantes and was appointed to the Chair of Botany in 1788. When the French Nationa ...
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Camphor
Camphor () is a waxy, colorless solid with a strong aroma. It is classified as a terpenoid and a cyclic ketone. It is found in the wood of the camphor laurel ('' Cinnamomum camphora''), a large evergreen tree found in East Asia; and in the kapur tree ( ''Dryobalanops'' sp.), a tall timber tree from South East Asia. It also occurs in some other related trees in the laurel family, notably '' Ocotea usambarensis''. Rosemary leaves (''Rosmarinus officinalis'') contain 0.05 to 0.5% camphor, while camphorweed (''Heterotheca'') contains some 5%. A major source of camphor in Asia is camphor basil (the parent of African blue basil). Camphor can also be synthetically produced from oil of turpentine. The compound is chiral, existing in two possible enantiomers as shown in the structural diagrams. The structure on the left is the naturally occurring (+)-camphor ((1''R'',4''R'')-bornan-2-one), while its mirror image shown on the right is the (−)-camphor ((1''S'',4''S'')-bornan-2-one). ...
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Heterotheca
''Heterotheca'', (common names goldenasters, camphorweed, or telegraph weed) are North American plants in the family Asteraceae. Etymology ''Heterotheca'' comes from Ancient Greek "other, different" and "case, chest", and refers to the fact that, in some species in the genus, the cypselae (achenes containing seed) of the disk and ray florets have different shapes. Description, biology These are annual and perennial herbs bearing daisy-like flower heads with yellow disc florets and usually yellow ray florets, associated with mesic to xeric habitats across North America. Several species now included in ''Heterotheca'' were previously classified in the genus '' Chrysopsis'' ''Heterotheca'' species are often used as food plants by the larvae of some Lepidoptera species including '' Schinia lynx'', ''Schinia nubila'' and '' Schinia saturata'' (all of which have been recorded on ''Heterotheca subaxillaris''). Chemistry The leaf volatiles from which the name "camphorweed" is deriv ...
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Limonene
Limonene is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the oil of citrus fruit peels. The -isomer, occurring more commonly in nature as the fragrance of oranges, is a flavoring agent in food manufacturing. It is also used in chemical synthesis as a precursor to carvone and as a renewables-based solvent in cleaning products. The less common -isomer has a piny, turpentine-like odor, and is found in the edible parts of such plants as caraway, dill, and bergamot orange plants. Limonene takes its name from Italian ''limone'' ("lemon"). Limonene is a chiral molecule, and biological sources produce one enantiomer: the principal industrial source, citrus fruit, contains -limonene ((+)-limonene), which is the (''R'')-enantiomer. Racemic limonene is known as dipentene. -Limonene is obtained commercially from citrus fruits through two primary methods: centrifugal separation or steam distillation. Chemical reactions Limon ...
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Myrcene
Myrcene, or β-myrcene, is a monoterpene. A colorless oil, it occurs widely in essential oils. It is produced mainly semi-synthetically from '' Myrcia'', from which it gets its name. It is an intermediate in the production of several fragrances. α-Myrcene is the name for the isomer 2-methyl-6-methylene-1,7-octadiene, which has not been found in nature. Production Myrcene is often produced commercially by the pyrolysis (400 °C) of β-pinene, which is obtained from turpentine. It is rarely obtained directly from plants. Plants biosynthesize myrcene via geranyl pyrophosphate (GPP), which isomerizes into linalyl pyrophosphate. The release of the pyrophosphate (OPP) and a proton completes the conversion. Occurrence It could in principle be extracted from any number of plants, such as verbena or wild thyme, the leaves of which contain up to 40% by weight of myrcene. Many other plants contain myrcene, sometimes in substantial amounts. Some of these include cannabis, hops, ''Hou ...
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Borneol
Borneol is a bicyclic organic compound and a terpene derivative. The hydroxyl group in this compound is placed in an '' endo'' position. The exo diastereomer is called isoborneol. Being chiral, borneol exists as enantiomers, both of which are found in nature. Reactions Borneol is oxidized to the ketone ( camphor). Occurrence The compound was named in 1842 by the French chemist Charles Frédéric Gerhardt. Borneol can be found in several species of ''Heterotheca'', ''Artemisia'', ''Rosmarinus officinalis'' (rosemary) ''Dipterocarpaceae'', ''Blumea balsamifera'' and '' Kaempferia galanga''. It is one of the chemical compounds found in castoreum. This compound is gathered from the beaver's plant food. Synthesis Borneol can be synthesized by reduction of camphor by the Meerwein–Ponndorf–Verley reduction (a reversible process). Reduction of camphor with sodium borohydride (fast and irreversible) gives instead the diastereomer isoborneol. : Uses Whereas ''d''-borneol w ...
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Pinene
Pinene is a collection of unsaturated bicyclic monoterpenes. Two geometric isomers of pinene are found in nature, α-pinene and β-pinene. Both are chiral. As the name suggests, pinenes are found in pines. Specifically, pinene is the major component of the liquid extracts of conifers. Pinenes are also found in many non-coniferous plants such as camphorweed (''Heterotheca'') and big sagebrush (''Artemisia tridentata''). Isomers Biosynthesis α-Pinene and β-pinene are both produced from geranyl pyrophosphate, via cyclisation of linaloyl pyrophosphate followed by loss of a proton from the carbocation equivalent. Researchers at the Georgia Institute of Technology and the Joint BioEnergy Institute have been able to synthetically produce pinene with a bacterium. Plants Alpha-pinene is the most widely encountered terpenoid in nature and is highly repellent to insects. Alpha-pinene appears in conifers and numerous other plants. Pinene is a major component of the essential oil ...
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Caryophyllene
Caryophyllene (), more formally (−)-β-caryophyllene, (BCP), is a natural bicyclic sesquiterpene that is a constituent of many essential oils, especially clove oil, the oil from the stems and flowers of '' Syzygium aromaticum'' (cloves), the essential oil of ''Cannabis sativa'', rosemary, and hops. It is usually found as a mixture with isocaryophyllene (the ''cis'' double bond isomer) and α-humulene (obsolete name: α-caryophyllene), a ring-opened isomer. Caryophyllene is notable for having a cyclobutane ring, as well as a ''trans''-double bond in a 9-membered ring, both rarities in nature. β-Caryophyllene acts as a full agonist of the Cannabinoid receptor type 2 (CB2 receptor) in rats. β-Caryophyllene has a binding affinity of Ki = 155nM at the CB2 receptors in mice. β-Caryophyllene has been shown to have anti-inflammatory action linked to its CB2 receptor activity in a study comparing the pain killing effects in mice with and without CB2 receptors with the group of mice w ...
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Head (botany)
A pseudanthium (Greek for "false flower"; ) is an inflorescence that resembles a flower. The word is sometimes used for other structures that are neither a true flower nor a true inflorescence. Examples of pseudanthia include flower heads, composite flowers, or capitula, which are special types of inflorescences in which anything from a small cluster to hundreds or sometimes thousands of flowers are grouped together to form a single flower-like structure. Pseudanthia take various forms. The real flowers (the florets) are generally small and often greatly reduced, but the pseudanthium itself can sometimes be quite large (as in the heads of some varieties of sunflower). Pseudanthia are characteristic of the daisy and sunflower family (Asteraceae), whose flowers are differentiated into ray flowers and disk flowers, unique to this family. The disk flowers in the center of the pseudanthium are actinomorphic and the corolla is fused into a tube. Flowers on the periphery are zygomorp ...
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Nathaniel Lord Britton
Nathaniel Lord Britton (January 15, 1859 – June 25, 1934) was an American botanist and taxonomist who co-founded the New York Botanical Garden in the Bronx, New York (state), New York. Early life Britton was born in New Dorp, Staten Island, New Dorp in Staten Island, New York to Jasper Alexander Hamilton Britton and Harriet Lord Turner. His parents wanted him to study religion, but he was attracted to nature study at an early age. He was a graduate of the School of Engineering and Applied Science (Columbia University), Columbia University School of Mines and afterwards taught geology and botany at Columbia University. He joined the Torrey Botanical Society, Torrey Botanical Club soon after graduation and was a member his entire life. He married Elizabeth Gertrude Britton, Elizabeth Gertrude Knight, a Bryophyte, bryologist, on August 27, 1885. They had met when she joined the club and were lifelong collaborators in botanical research. New York Botanical Garden During their h ...
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Inflorescence
An inflorescence is a group or cluster of flowers arranged on a stem that is composed of a main branch or a complicated arrangement of branches. Morphologically, it is the modified part of the shoot of seed plants where flowers are formed on the axis of a plant. The modifications can involve the length and the nature of the internodes and the phyllotaxis, as well as variations in the proportions, compressions, swellings, adnations, connations and reduction of main and secondary axes. One can also define an inflorescence as the reproductive portion of a plant that bears a cluster of flowers in a specific pattern. The stem holding the whole inflorescence is called a peduncle. The major axis (incorrectly referred to as the main stem) above the peduncle bearing the flowers or secondary branches is called the rachis. The stalk of each flower in the inflorescence is called a pedicel. A flower that is not part of an inflorescence is called a solitary flower and its stalk is al ...
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Belize
Belize (; bzj, Bileez) is a Caribbean and Central American country on the northeastern coast of Central America. It is bordered by Mexico to the north, the Caribbean Sea to the east, and Guatemala to the west and south. It also shares a water boundary with Honduras to the southeast. It has an area of and a population of 441,471 (2022). Its mainland is about long and wide. It is the least populated and least densely populated country in Central America. Its population growth rate of 1.87% per year (2018 estimate) is the second-highest in the region and one of the highest in the Western Hemisphere. Its capital is Belmopan, and its largest city is the namesake city of Belize City. Belize is often thought of as a Caribbean country in Central America because it has a history similar to that of English-speaking Caribbean nations. Indeed, Belize’s institutions and official language reflect its history as a British colony. The Maya civilization spread into the area of Beli ...
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