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Hydromelonate
Hydromelonic acid, is an elusive chemical compound with formula or , whose molecule would consist of a heptazine molecule, with three cyanamido groups or substituted for the hydrogen atoms. The compound had not been properly isolated as of 2010, due to its tendency to polymerize. However, removal of three protons yields the melonate (formerly hydromelonate) anion , whose salts are stable and have been known since the 19th century. Removal of only two protons yields the divalent hydrogenmelonate anion . History In 1834 Justus von Liebig described the compounds that he named melamine, melam, and melon. In 1835 Leopold Gmelin prepared a potassium salt (later identified as ) by heating potassium ferrocyanide with sulfur); recognizing their connection to the compounds described by Liebig, he named the salt "hydromelonate" and the corresponding acid "hydromelonic". In the following years Liebig prepared the same salt by other methods, such as by fusing potassium thiocyanate ...
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Cyameluric Acid
Cyameluric acid or 2,5,8-trihydroxy-''s''-heptazine is a chemical compound with formula , usually described as a heptazine molecule with the hydrogen atoms replaced by hydroxyl groups ; or any of its tautomers. The substance exists as an equilibrium of 17 tautomers that easily interconvert among each other. Calculations show that the symmetric tri-oxo form (1,4,7-trihydro-2,5,8-trioxo-''s''-heptazine) is the most stable. Therefore, this compound contains amide groups rather than imidic acids. History In 1834 Justus von Liebig described the compounds that he named melamine, melam, and melon. In 1835 Leopold Gmelin prepared novel salts by heating potassium ferrocyanide with sulfur); recognizing their connection to the compounds described by Liebig, he named the salts " hydromelonates" and the corresponding acid " hydromelonic". In the following years Liebig prepared the same salts by other methods, such as by fusing potassium thiocyanate with antimony trichloride, and eventually dete ...
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Melonate
Hydromelonic acid, is an elusive chemical compound with formula or , whose molecule would consist of a heptazine molecule, with three cyanamido groups or substituted for the hydrogen atoms. The compound had not been properly isolated as of 2010, due to its tendency to polymerize. However, removal of three protons yields the melonate (formerly hydromelonate) anion , whose salts are stable and have been known since the 19th century. Removal of only two protons yields the divalent hydrogenmelonate anion . History In 1834 Justus von Liebig described the compounds that he named melamine, melam, and melon. In 1835 Leopold Gmelin prepared a potassium salt (later identified as ) by heating potassium ferrocyanide with sulfur); recognizing their connection to the compounds described by Liebig, he named the salt "hydromelonate" and the corresponding acid "hydromelonic". In the following years Liebig prepared the same salt by other methods, such as by fusing potassium thiocyanate ...
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Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, using the s ...
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Carbon Nitride
In organic chemistry, carbon nitrides are compounds consisting only of carbon and nitrogen atoms. Covalent network compounds * Beta carbon nitride - a solid with a formula β-, which is predicted to be harder than diamond. * Graphitic carbon nitride - g-, with important catalytic and sensor properties. Azafullerenes * Azafullerenes are a class of heterofullerenes in which the element substituting for carbon is nitrogen. Examples include (biazafullerenyl),Hummelen et al, Isolation of the Heterofullerene C59N as Its Dimer (C59N)2, Science 269: 1554-1556 (1995) (diaza 0ullerene), (triaza 0ullerene) and . Cyanofullerenes * Cyanofullerenes are a class of modified fullerenes in which cyano- groups are attached to a fullerene skeleton. These have the formula , where ''n'' takes the values 1 to 9. Cyanogen * Cyanogen - (NCCN) * Isocyanogen - (CNCN) * Diisocyanogen - (CNNC) * Paracyanogen - a cyanogen polymer, * Paraisocyanogen - a cyanogen polymer, Percyanoal ...
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Carbon Nanotube
A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon nanotubes'' (''SWCNTs'') are one of the allotropes of carbon, intermediate between fullerene cages and flat graphene, with diameters in the range of a nanometre. Although not made this way, single-wall carbon nanotubes can be idealized as cutouts from a two-dimensional Hexagonal tiling, hexagonal lattice of carbon atoms rolled up along one of the Bravais lattice vectors of the hexagonal lattice to form a hollow cylinder. In this construction, periodic boundary conditions are imposed over the length of this roll-up vector to yield a helical lattice of seamlessly bonded carbon atoms on the cylinder surface. ''Multi-wall carbon nanotubes'' (''MWCNTs'') consisting of nested single-wall carbon nanotubes weakly bound together by van der Waals ...
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Carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an ...—its atom making four electrons available to form covalent bond, covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three Isotopes of carbon, isotopes occur naturally, Carbon-12, C and Carbon-13, C being stable, while Carbon-14, C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the Timeline of chemical element discoveries#Ancient discoveries, few elements known since antiquity. Carbon is the 15th Abundance of elements in Earth's crust, most abundant element in the Earth's crust, and the Abundance of the c ...
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Iron(III) Melonate
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundance of the chemical elements#Earth, by mass, the most common element on Earth, right in front of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer core, outer and inner core. It is the fourth most common abundance of elements in Earth's crust, element in the Earth's crust. In its metallic state, iron is rare in the Earth's crust, limited mainly to deposition by meteorites. Iron ores, by contrast, are among the most abundant in the Earth's crust, although extracting usable metal from them requires kilns or Metallurgical furnace, furnaces capable of reaching or higher, about higher than that required to smelting, smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BC, 2nd millennium BCE ...
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Triazine
Triazines are a class of nitrogen-containing heterocycles. The parent molecules' molecular formula is . They exist in three isomeric forms, 1,3,5-triazines being common. Structure The triazines have planar six-membered benzene-like ring but with three carbons replaced by nitrogens. The three isomers of triazine are distinguished by the positions of their nitrogen atoms, and are referred to as 1,2,3-triazine, 1,2,4-triazine, and 1,3,5-triazine. Other aromatic nitrogen heterocycles are pyridines with one ring nitrogen atom, diazines with 2 nitrogen atoms in the ring, triazoles with 3 nitrogens in a 5 membered ring, and tetrazines with 4 ring nitrogen atoms. Uses Melamine A well known triazine is melamine (2,4,6-triamino-1,3,5-triazine). With three amino substituents, melamine is a precursor to commercial resins. Guanamines are closely related to melamine, except with one amino substituent replaced by an organic group. This difference is exploited in the use of guanamines t ...
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Cyanate
Cyanate is an anion with the structural formula , usually written . It also refers to any salt containing it, such as ammonium cyanate. It is an isomer of the much less stable fulminate anion .William R. Martin and David W. Ball (2019): "Small organic fulminates as high energy materials. Fulminates of acetylene, ethylene, and allene". ''Journal of Energetic Materials'', volume 31, issue 7, pages 70-79. A cyanate ester is an organic compound containing the cyanate group. The cyanate ion is an ambidentate ligand, forming complexes with a metal ion in which either the nitrogen or oxygen atom may be the electron-pair donor. It can also act as a bridging ligand. Cyanate ion The three atoms in a cyanate ion lie on a straight line, giving the ion a linear structure. The electronic structure is described most simply as : :Ö̤−C≡N: with a single C−O bond and a triple C≡N bond. The infrared spectrum of a cyanate salt has a band at ca. 2096 cm−1; such a high frequen ...
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Double Displacement Reaction
A salt metathesis reaction, sometimes called a double displacement reaction, is a chemical process involving the exchange of bonds between two reacting chemical species which results in the creation of products with similar or identical bonding affiliations. This reaction is represented by the general scheme: :AB + CD -> AD + CB The bond between the reacting species can be either ionic or covalent. Classically, these reactions result in the precipitation of one product. In older literature, the term double decomposition is frequently encountered. The term double decomposition is more specifically used when at least one of the substances does not dissolve in the solvent, as the ligand or ion exchange takes place in the solid state of the reactant. For example: :AX(aq) + BY(s) → AY(aq) + BX(s). Types of reactions Counterion exchange Salt metathesis is a common technique for exchanging counterions. The choice of reactants is guided by a solubility chart or lattice energy. ...
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Sodium Thiocyanate
Sodium thiocyanate (sometimes called sodium sulphocyanide) is the chemical compound with the formula NaSCN. This colorless deliquescent salt is one of the main sources of the thiocyanate anion. As such, it is used as a precursor for the synthesis of pharmaceuticals and other specialty chemicals. Thiocyanate salts are typically prepared by the reaction of cyanide with elemental sulfur: :8 NaCN + S8 → 8 NaSCN Sodium thiocyanate crystallizes in an orthorhombic cell. Each Na+ center is surrounded by three sulfur and three nitrogen ligands provided by the triatomic thiocyanate anion. It is commonly used in the laboratory as a test for the presence of Fe3+ ions. Applications in chemical synthesis Sodium thiocyanate is employed to convert alkyl halides into the corresponding alkylthiocyanates. Closely related reagents include ammonium thiocyanate and potassium thiocyanate, which has twice the solubility in water. Silver thiocyanate may be used as well; the precipitation ...
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