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Hydrocyanonium
HCNH+, also known as protonated hydrogen cyanide, is a molecular ion of astrophysical interest. It also exists in the condensed state when formed by superacids. Structure In the ground state, HCH is a simple linear molecule, whereas its excited triplet state is expected to have ''cis'' and ''trans'' isomeric forms. The higher-energy structural isomers H2CN+ and CH2 have also been studied theoretically. Laboratory studies As a relatively simple molecular ion, HCNH+ has been extensively studied in the laboratory. The very first spectrum taken at any wavelength focused on the ''ν''2 (C−H stretch) ro-vibrational band in the infrared. Soon afterward, the same authors reported on their investigation of the ''ν''1 (N−H stretch) band. Following these initial studies, several groups published manuscripts on the various ro-vibrational spectra of HCNH+, including studies of the ''ν''3 band (C≡N stretch), the ''ν''4 band (H−C≡N bend), and the ''ν''5 band (H−N≡C b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroisocyanic Acid
Hydrogen isocyanide is a chemical with the molecular formula HNC. It is a minor tautomer of hydrogen cyanide (HCN). Its importance in the field of astrochemistry is linked to its ubiquity in the interstellar medium. Nomenclature Both ''hydrogen isocyanide'' and ''azanylidyniummethanide'' are correct IUPAC names for HNC. There is no preferred IUPAC name. The second one is according to the ''substitutive nomenclature rules'', derived from the ''parent hydride'' azane () and the anion methanide (). Molecular properties Hydrogen isocyanide (HNC) is a linear triatomic molecule with C∞v point group symmetry. It is a zwitterion and an isomer of hydrogen cyanide (HCN). Both HNC and HCN have large, similar dipole moments, with ''μ''HNC = 3.05 Debye and ''μ''HCN = 2.98 Debye respectively. These large dipole moments facilitate the easy observation of these species in the interstellar medium. HNC−HCN tautomerism As HNC is higher in energy than HCN by 3920 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Cyanide
Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on an industrial scale and is a highly valued precursor to many chemical compounds ranging from polymers to pharmaceuticals. Large-scale applications are for the production of potassium cyanide and adiponitrile, used in mining and plastics, respectively. It is more toxic than solid cyanide compounds due to its volatile nature. Structure and general properties Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen. The tautomer of HCN is HNC, hydrogen isocyanide. Hydrogen cyanide is weakly acidic with a p''K''a of 9.2. It partially ionizes in water solution to give the cyanide anion, CN−. A solution of hydrogen cyanide in water, represented as HCN, is called ''hydrocyanic acid''. The salts of the cyanide ani ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Isocyanide
Hydrogen isocyanide is a chemical with the molecular formula HNC. It is a minor tautomer of hydrogen cyanide (HCN). Its importance in the field of astrochemistry is linked to its ubiquity in the interstellar medium. Nomenclature Both ''hydrogen isocyanide'' and ''azanylidyniummethanide'' are correct IUPAC names for HNC. There is no preferred IUPAC name. The second one is according to the ''substitutive nomenclature rules'', derived from the ''parent hydride'' azane () and the anion methanide (). Molecular properties Hydrogen isocyanide (HNC) is a linear triatomic molecule with C∞v point group symmetry. It is a zwitterion and an isomer of hydrogen cyanide (HCN). Both HNC and HCN have large, similar dipole moments, with ''μ''HNC = 3.05 Debye and ''μ''HCN = 2.98 Debye respectively. These large dipole moments facilitate the easy observation of these species in the interstellar medium. HNC−HCN tautomerism As HNC is higher in energy than HCN by 3920&nb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ChemSpider
ChemSpider is a database of chemicals. ChemSpider is owned by the Royal Society of Chemistry. Database The database contains information on more than 100 million molecules from over 270 data sources including: * EPA DSSTox * U.S. Food and Drug Administration (FDA) * Human Metabolome Database * Journal of Heterocyclic Chemistry * KEGG * KUMGM * LeadScope * LipidMAPS * Marinlit * MDPI * MICAD * MLSMR * MMDB * MOLI * MTDP * Nanogen * Nature Chemical Biology * NCGC * NIAID * National Institutes of Health (NIH) * NINDS Approved Drug Screening Program * NIST * NIST Chemistry WebBook * NMMLSC * NMRShiftDB * PANACHE * PCMD * PDSP * Peptides * Prous Science Drugs of the Future * QSAR * R&D Chemicals * San Diego Center for Chemical Genomics * SGCOxCompounds, SGCStoCompounds * SMID * Specs * Structural Genomics Consortium * SureChem * Synthon-Lab * Thomson Pharma * Total TOSLab Building-Blocks * UM-BBD * UPCMLD * UsefulChem * Web of Science * xPharm Each chemical is given a unique i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
NRAO
The National Radio Astronomy Observatory (NRAO) is a federally funded research and development center of the United States National Science Foundation operated under cooperative agreement by Associated Universities, Inc. for the purpose of radio astronomy. NRAO designs, builds, and operates its own high-sensitivity radio telescopes for use by scientists around the world. Locations Charlottesville, Virginia The NRAO headquarters is located on the campus of the University of Virginia in Charlottesville, Virginia. The North American ALMA Science Center and the NRAO Technology Center and Central Development Laboratory are also in Charlottesville. Green Bank, West Virginia NRAO was, until October 2016, the operator of the world's largest fully steerable radio telescope, the Robert C. Byrd Green Bank Telescope, which stands near Green Bank, West Virginia. The observatory contains several other telescopes, among them the telescope that utilizes an equatorial mount uncommon for radio te ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Comet
A comet is an icy, small Solar System body that, when passing close to the Sun, warms and begins to release gases, a process that is called outgassing. This produces a visible atmosphere or coma, and sometimes also a tail. These phenomena are due to the effects of solar radiation and the solar wind acting upon the nucleus of the comet. Comet nuclei range from a few hundred meters to tens of kilometers across and are composed of loose collections of ice, dust, and small rocky particles. The coma may be up to 15 times Earth's diameter, while the tail may stretch beyond one astronomical unit. If sufficiently bright, a comet may be seen from Earth without the aid of a telescope and may subtend an arc of 30° (60 Moons) across the sky. Comets have been observed and recorded since ancient times by many cultures and religions. Comets usually have highly eccentric elliptical orbits, and they have a wide range of orbital periods, ranging from several years to potentially several mill ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyanide
Cyanide is a naturally occurring, rapidly acting, toxic chemical that can exist in many different forms. In chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom. In inorganic cyanides, the cyanide group is present as the anion . Soluble salts such as sodium cyanide (NaCN) and potassium cyanide (KCN) are highly toxic. Hydrocyanic acid, also known as hydrogen cyanide, or HCN, is a highly volatile liquid that is produced on a large scale industrially. It is obtained by acidification of cyanide salts. Organic cyanides are usually called nitriles. In nitriles, the group is linked by a covalent bond to carbon. For example, in acetonitrile (), the cyanide group is bonded to methyl (). Although nitriles generally do not release cyanide ions, the cyanohydrins do and are thus rather toxic. Bonding The cyanide ion is isoelectronic with carbon monoxide a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Comet Hale-Bopp
A comet is an icy, small Solar System body that, when passing close to the Sun, warms and begins to release gases, a process that is called outgassing. This produces a visible atmosphere or coma, and sometimes also a tail. These phenomena are due to the effects of solar radiation and the solar wind acting upon the nucleus of the comet. Comet nuclei range from a few hundred meters to tens of kilometers across and are composed of loose collections of ice, dust, and small rocky particles. The coma may be up to 15 times Earth's diameter, while the tail may stretch beyond one astronomical unit. If sufficiently bright, a comet may be seen from Earth without the aid of a telescope and may subtend an arc of 30° (60 Moons) across the sky. Comets have been observed and recorded since ancient times by many cultures and religions. Comets usually have highly eccentric elliptical orbits, and they have a wide range of orbital periods, ranging from several years to potentially several milli ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titan (moon)
Titan is the largest moon of Saturn and the second-largest natural satellite in the Solar System. It is the only moon known to have a dense atmosphere, and is the only known object in space other than Earth on which clear evidence of stable bodies of surface liquid has been found. Titan is one of the seven gravitationally rounded moons in orbit around Saturn, and the second most distant from Saturn of those seven. Frequently described as a planet-like moon, Titan is 50% larger (in diameter) than Earth's Moon and 80% more massive. It is the second-largest moon in the Solar System after Jupiter's moon Ganymede, and is larger than the planet Mercury, but only 40% as massive. Discovered in 1655 by the Dutch astronomer Christiaan Huygens, Titan was the first known moon of Saturn, and the sixth known planetary satellite (after Earth's moon and the four Galilean moons of Jupiter). Titan orbits Saturn at 20 Saturn radii. From Titan's surface, Saturn subtends an arc of 5.09 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Saturn
Saturn is the sixth planet from the Sun and the second-largest in the Solar System, after Jupiter. It is a gas giant with an average radius of about nine and a half times that of Earth. It has only one-eighth the average density of Earth; however, with its larger volume, Saturn is over 95 times more massive. Saturn's interior is most likely composed of a core of iron–nickel and rock (silicon and oxygen compounds). Its core is surrounded by a deep layer of metallic hydrogen, an intermediate layer of liquid hydrogen and liquid helium, and finally, a gaseous outer layer. Saturn has a pale yellow hue due to ammonia crystals in its upper atmosphere. An electrical current within the metallic hydrogen layer is thought to give rise to Saturn's planetary magnetic field, which is weaker than Earth's, but which has a magnetic moment 580 times that of Earth due to Saturn's larger size. Saturn's magnetic field strength is around one-twentieth of Jupiter's. The outer atmosphere is g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lucy Ziurys
Lucy Marie Ziurys (born May 6, 1957) is an American astrochemist known for her work on high-resolution molecular spectroscopy. She is Regent's Professor of Chemistry & Biology and of Astronomy at the University of Arizona. Contributions Ziurys's work has discovered new molecules in interstellar space and in carbon-rich circumstellar envelopes, found unexpectedly long molecular lifetimes in planetary nebulae, and made pioneering high-resolution submillimeter astronomy observations of supermassive black holes using very-long-baseline interferometry. In earthbound experiments, she has also found models for the interstellar creation of buckminsterfullerene. Education and career Ziurys is originally from Annapolis, Maryland. She majored in chemistry, chemical physics, and physics at Rice University, graduating summa cum laude in 1978. She went to the University of California, Berkeley for graduate study in physical chemistry, completing a Ph.D. in 1984 under the supervision of R ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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