Hiyama Castle , a carbon-carbon bond-forming reaction
{{disambiguation, geo ...
Hiyama may refer to: *Hiyama (surname), a Japanese surname * Hiyama Subprefecture, a subprefecture of Hokkaidō, Japan *Hiyama District, Hokkaidō, a district in Hiyama Subprefecture See also *Hiyama coupling, a carbon-carbon bond-forming reaction *Nozaki–Hiyama–Kishi reaction The Nozaki–Hiyama–Kishi reaction is a nickel/ chromium coupling reaction forming an alcohol from the reaction of an aldehyde with an allyl or vinyl halide. In their original 1977 publication, Tamejiro Hiyama and Hitoshi Nozaki reported on ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Hiyama (surname)
Hiyama (written: , , , or ) is a Japanese surname. Notable people with the surname include: *, Japanese physicist *, Japanese jazz drummer *, Japanese voice actor *, Japanese baseball player *Tamejiro Hiyama Tamejiro Hiyama (born August 24, 1946) is a Japanese organic chemistry, organic chemist. He is best known for his work in developing the Nozaki-Hiyama-Kishi reaction and the Hiyama coupling. He is currently a professor at the Chuo University Rese ... (born 1946), Japanese chemist *, Japanese footballer {{surname Japanese-language surnames ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Hiyama Subprefecture
is a subprefecture of Hokkaido Prefecture, Japan located on the Oshima Peninsula on the Sea of Japan side. It includes Okushiri Island. It was established in 1897. Geography Mergers History *1897: Hiyama Subprefecture was established. *2005: Kumaishi Town ( Nishi District) was merged with Yakumo Town ( Yamakoshi District, Oshima Subprefecture) and transferred to Oshima Subprefecture. At the same time, Hiyama Subprefecture was divided between north and south. *2014: Esashi Line (from Kikonai Station to Esashi Station was a railway station on the Esashi Line in Esashi, Hokkaido, Japan, operated by Hokkaido Railway Company (JR Hokkaido). It opened in 1936 and closed in May 2014. Lines Esashi Station was formerly the terminus of the non-electrified section of ...) was abolished. Therefore, Hiyama Subprefecture became the only subprefecture in which there is no railway. External links Official Website {{Hokkaido-geo-stub Subprefectures in Hokkaido ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Hiyama District, Hokkaidō
is a district located in Hiyama Subprefecture, Hokkaido, Japan. As of 2004, the district has an estimated population of 21,896 and a density of 19.59 persons per km2. The total area is 1,117.57 km2. Towns and villages * Assabu * Esashi * Kaminokuni Notable place * Katsuyama Date - A castle ruin, was listed as one of the National Historic Site and Continued 100 Fine Castles of Japan The is a list of 100 castles, intended as a sequel of 100 Fine Castles of Japan. The castles were chosen for their significance in culture, history, and in their regions by the in 2017. Hokkaidō region Tōhoku region Kantō region Kōs .... References Districts in Hokkaido {{Hokkaido-geo-stub ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Hiyama Coupling
The Hiyama coupling is a palladium-catalyzed cross-coupling reaction of organosilanes with organic halides used in organic chemistry to form carbon–carbon bonds (C-C bonds). This reaction was discovered in 1988 by Tamejiro Hiyama and Yasuo Hatanaka as a method to form carbon-carbon bonds synthetically with chemo- and regioselectivity. The Hiyama coupling has been applied to the synthesis of various natural products. :\begin\\ \ce \end :* R: aryl, alkenyl or alkynyl :* R': aryl, alkenyl, alkynyl or alkyl :* R'': Cl, F or alkyl :* X: Cl, Br, I or OTf Reaction history The Hiyama coupling was developed to combat the issues associated with other organometallic reagents. The initial reactivity of organosilicon was not actually first reported by Hiyama, as Kumada reported a coupling reaction using organofluorosilicates shown below. Organosilanes were then discovered, by Hiyama, to have reactivity when activated by a fluoride source. This reactivity, when combined with a palladium s ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |