|
Hexafluorides
A hexafluoride is a chemical compound with the general formula QXnF6, QXnF6m−, or QXnF6m+. Many molecules fit this formula. An important hexafluoride is hexafluorosilicic acid (H2SiF6), which is a byproduct of the mining of phosphate rock. In the nuclear industry, uranium hexafluoride (UF6) is an important intermediate in the purification of this element. Hexafluoride cations Cationic hexafluorides exist but are rarer than neutral or anionic hexafluorides. Examples are the hexafluorochlorine (ClF6+), and hexafluorobromine (BrF6+) Ion, cations. Hexafluoride anions Many elements form anionic hexafluorides. Members of commercial interest are hexafluorophosphate (PF6−) and hexafluorosilicate (SiF62−). Many transition metals form hexafluoride anions. Often the monoanions are generated by reduction of the neutral hexafluorides. For example, Dioxygenyl hexafluoroplatinate, PtF6− arises by reduction of PtF6 by O2. Because of its highly basic nature and its resistance to oxida ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Hexafluoride
Uranium hexafluoride, sometimes called hex, is the inorganic compound with the formula . Uranium hexafluoride is a volatile, white solid that is used in enriching uranium for nuclear reactors and nuclear weapons. Preparation Uranium dioxide is converted with hydrofluoric acid (HF) to uranium tetrafluoride: : The resulting is subsequently oxidized with fluorine to give the hexafluoride: : In samples contaminated with uranium trioxide, uranyl fluoride, an oxyfluoride compound is produced in the HF step: : which can be fluorinated to produce the same product, uranium hexafluoride. : The fluorination step in both reactions above are highly exothermic. Properties Physical properties At atmospheric pressure, sublimes at 56.5 °C. The solid-state structure was determined by neutron diffraction at 77 K and 293 K.J. C. Taylor, P. W. Wilson, J. W. Kelly: „The structures of fluorides. I. Deviations from ideal symmetry in the structure of crystalline UF6: a neutron diffract ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polonium Hexafluoride
Polonium hexafluoride () is a possible chemical compound of polonium and fluorine and one of the seventeen known binary hexafluorides. Synthesis The synthesis of via the reaction : was attempted in 1945, but the attempt was unsuccessful. The boiling point was predicted to be about −40 °C. was probably successfully synthesised via the same reaction in 1960 with the more stable isotope , where a volatile polonium fluoride was produced, but it was not fully characterized before it underwent radiolysis Radiolysis is the dissociation of molecules by ionizing radiation. It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux. The radiation in this context is associated with ionizing radiation; radiolysis is ... and decomposed to polonium tetrafluoride. References {{Polonium compounds Polonium compounds Metal halides Hexafluorides Chalcohalides Substances discovered in the 1960s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Xenon Hexafluoride
Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon that have been studied experimentally, the other two being XeF2 and XeF4. All of them are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinating agent of the series. It is a colorless solid that readily sublimes into intensely yellow vapors. Preparation Xenon hexafluoride can be prepared by heating of XeF2 at about 300 °C under 6 MPa (60 atmospheres) of fluorine. With as catalyst, however, this reaction can proceed at 120 °C even in xenon-fluorine molar ratios as low as 1:5. Structure The structure of XeF6 required several years to establish in contrast to the cases of and . In the gas phase the compound is monomeric. VSEPR theory predicts that due to the presence of six fluoride ligands and one lone pair of electrons the structure lacks perfect octahedral symmetry, and indeed electron diffraction combined with high-level cal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Noble Gas
The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of Group (periodic table), group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some cases, oganesson (Og). Under Standard temperature and pressure, standard conditions, the first six of these Chemical element, elements are odorless, colorless, monatomic gases with very low chemical reactivity and cryogenics, cryogenic boiling points. The properties of oganesson are uncertain. The intermolecular force between noble gas atoms is the very weak London dispersion force, so their boiling points are all cryogenic, below . The noble gases' Chemically inert, inertness, or tendency not to Chemical reaction, react with other chemical substances, results from their electron configuration: their Electron shell, outer shell of valence electrons is "full", giving them little tendency to participate in chemical reactions. Only a few hun ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hexafluorosilicic Acid
Hexafluorosilicic acid is an inorganic compound with the chemical formula . Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless. Hexafluorosilicic acid is produced naturally on a large scale in volcanoes.Palache, C., Berman, H., and Frondel, C. (1951) Dana’s System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, etc. John Wiley and Sons, Inc., New York, 7th edition.Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (1997) Handbook of Mineralogy, Volume III: Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson.Bararite It is manufactured as a coproduct in the production of phosphate fertilizers. The resulting hexafluorosilicic acid is almost exclusively consumed as a precursor to aluminum trifluoride and synthetic cryolite, which are used in aluminium processing. Salts derived f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Group 6 Element
Group 6, numbered by IUPAC style, is a group of elements in the periodic table. Its members are chromium (Cr), molybdenum (Mo), tungsten (W), and seaborgium (Sg). These are all transition metals and chromium, molybdenum and tungsten are refractory metals. The electron configuration of these elements do not follow a unified trend, though the outermost shells do correlate with trends in chemical behavior: "Group 6" is the new IUPAC name for this group; the old style name was "''group VIB''" in the old US system (CAS) or "''group VIA''" in the European system (old IUPAC). Group 6 must not be confused with the group with the old-style group crossed names of either ''VIA'' (US system, CAS) or ''VIB'' (European system, old IUPAC). ''That'' group is now called group 16. History Discoveries Chromium was first reported on July 26, 1761, when Johann Gottlob Lehmann found an orange-red mineral in the Beryozovskoye mines in the Ural Mountains of Russia, which he named "Siberian red ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Octahedral Molecular Geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix '' octa''. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, , which is not octahedral in the mathematical sense due to the orientation of the bonds, is referred to as octahedral. The concept of octahedral coordination geometry was developed by Alfred ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Symmetry Group
In group theory, the symmetry group of a geometric object is the group of all transformations under which the object is invariant, endowed with the group operation of composition. Such a transformation is an invertible mapping of the ambient space which takes the object to itself, and which preserves all the relevant structure of the object. A frequent notation for the symmetry group of an object ''X'' is ''G'' = Sym(''X''). For an object in a metric space, its symmetries form a subgroup of the isometry group of the ambient space. This article mainly considers symmetry groups in Euclidean geometry, but the concept may also be studied for more general types of geometric structure. Introduction We consider the "objects" possessing symmetry to be geometric figures, images, and patterns, such as a wallpaper pattern. For symmetry of physical objects, one may also take their physical composition as part of the pattern. (A pattern may be specified formally as a scalar field, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
VSEPR Theory
Valence shell electron pair repulsion (VSEPR) theory ( , ) is a conceptual model, model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. It is also named the Gillespie-Nyholm theory after its two main developers, Ronald Gillespie and Ronald Sydney Nyholm, Ronald Nyholm. The premise of VSEPR is that the valence electron pairs surrounding an atom tend to repel each other. The greater the repulsion, the higher in energy (less stable) the molecule is. Therefore, the VSEPR-predicted molecular geometry of a molecule is the one that has as little of this repulsion as possible. Gillespie has emphasized that the electron-electron repulsion due to the Pauli exclusion principle is more important in determining molecular geometry than the electrostatic repulsion. The insights of VSEPR theory are derived from topological analysis of the electron density of molecules. Such quantum chemical topology (QCT) metho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lone Pair
In chemistry, a lone pair refers to a pair of valence electrons that are not shared with another atom in a covalent bondIUPAC ''Gold Book'' definition''lone (electron) pair''/ref> and is sometimes called an unshared pair or non-bonding pair. Lone pairs are found in the outermost electron shell of atoms. They can be identified by using a Lewis structure. Electron pair, Electron pairs are therefore considered lone pairs if two electrons are paired but are not used in chemical bonding. Thus, the number of electrons in lone pairs plus the number of electrons in bonds equals the number of valence electrons around an atom. Lone pair is a concept used in valence shell electron pair repulsion theory (VSEPR theory) which explains the Molecular geometry, shapes of molecules. They are also referred to in the chemistry of Lewis acids and bases. However, not all non-bonding pairs of electrons are considered by chemists to be lone pairs. Examples are the transition metals where the non-bonding ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boiling Point
The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum, i.e., under a lower pressure, has a lower boiling point than when that liquid is at atmospheric pressure. Because of this, water boils at 100°C (or with scientific precision: ) under standard pressure at sea level, but at at altitude. For a given pressure, different liquids will boiling, boil at different temperatures. The normal boiling point (also called the atmospheric boiling point or the atmospheric pressure boiling point) of a liquid is the special case in which the vapor pressure of the liquid equals the defined atmospheric pressure at sea level, one Atmosphere (unit), atmosphere. At that temperature, the vapor pressure of the liquid becomes sufficient to overcome atmospheric pre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
