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Helmholtz Theorem (classical Mechanics)
The Helmholtz theorem of classical mechanics reads as follows: Let H(x,p;V) = K(p) + \varphi(x;V) be the Hamiltonian of a one-dimensional system, where K = \frac is the kinetic energy and \varphi(x;V) is a "U-shaped" potential energy profile which depends on a parameter V. Let \left\langle \cdot \right\rangle _ denote the time average. Let *E = K + \varphi, *T = 2\left\langle K\right\rangle _, *P = \left\langle -\frac\right\rangle _, *S(E,V)=\log \oint \sqrt\,dx. Then dS = \frac. Remarks The thesis of this theorem of classical mechanics reads exactly as the heat theorem of thermodynamics. This fact shows that thermodynamic-like relations exist between certain mechanical quantities. This in turn allows to define the "thermodynamic state" of a one-dimensional mechanical system. In particular the temperature T is given by time average of the kinetic energy, and the entropy S by the logarithm of the action (i.e., \oint dx \sqrt). The importance of this theorem has been ...
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Hamiltonian (quantum Mechanics)
Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian with two-electron nature ** Molecular Hamiltonian, the Hamiltonian operator representing the energy of the electrons and nuclei in a molecule * Hamiltonian (control theory), a function used to solve a problem of optimal control for a dynamical system * Hamiltonian path, a path in a graph that visits each vertex exactly once * Hamiltonian group, a non-abelian group the subgroups of which are all normal * Hamiltonian economic program, the economic policies advocated by Alexander Hamilton, the first United States Secretary of the Treasury See also * Alexander Hamilton (1755 or 1757–1804), American statesman and one of the Founding Fathers of the US * Hamilton (other) Hamilton may refer to: People * Hamilton (name), a common ...
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Ludwig Boltzmann
Ludwig Eduard Boltzmann (; 20 February 1844 – 5 September 1906) was an Austrian physicist and philosopher. His greatest achievements were the development of statistical mechanics, and the statistical explanation of the second law of thermodynamics. In 1877 he provided the current definition of entropy, S = k_ \ln \Omega \!, where Ω is the number of microstates whose energy equals the system's energy, interpreted as a measure of statistical disorder of a system. Max Planck named the constant the Boltzmann constant. Statistical mechanics is one of the pillars of modern physics. It describes how macroscopic observations (such as temperature and pressure) are related to microscopic parameters that fluctuate around an average. It connects thermodynamic quantities (such as heat capacity) to microscopic behavior, whereas, in classical thermodynamics, the only available option would be to measure and tabulate such quantities for various materials. Biography Childhood and educatio ...
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Classical Mechanics
Classical mechanics is a physical theory describing the motion of macroscopic objects, from projectiles to parts of machinery, and astronomical objects, such as spacecraft, planets, stars, and galaxies. For objects governed by classical mechanics, if the present state is known, it is possible to predict how it will move in the future (determinism), and how it has moved in the past (reversibility). The earliest development of classical mechanics is often referred to as Newtonian mechanics. It consists of the physical concepts based on foundational works of Sir Isaac Newton, and the mathematical methods invented by Gottfried Wilhelm Leibniz, Joseph-Louis Lagrange, Leonhard Euler, and other contemporaries, in the 17th century to describe the motion of bodies under the influence of a system of forces. Later, more abstract methods were developed, leading to the reformulations of classical mechanics known as Lagrangian mechanics and Hamiltonian mechanics. These advances, ma ...
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Generalized Helmholtz Theorem
The generalized Helmholtz theorem is the multi-dimensional generalization of the Helmholtz theorem which is valid only in one dimension. The generalized Helmholtz theorem reads as follows. Let :\mathbf=(p_1,p_2,...,p_s), :\mathbf=(q_1,q_2,...,q_s), be the canonical coordinates of a ''s''-dimensional Hamiltonian system, and let : H(\mathbf,\mathbf;V)=K(\mathbf)+\varphi(\mathbf;V) be the Hamiltonian function, where :K=\sum_^\frac, is the kinetic energy and :\varphi(\mathbf;V) is the potential energy which depends on a parameter V. Let the hyper-surfaces of constant energy in the 2''s''-dimensional phase space of the system be metrically indecomposable and let \left\langle \cdot \right\rangle_t denote time average. Define the quantities E, P, T, S, as follows: :E = K + \varphi , :T = \frac\left\langle K\right\rangle _, :P = \left\langle -\frac\right\rangle _, :S(E,V) = \log \int_ d^s\mathbfd^s \mathbf. Then: :dS = \frac. Remarks The thesis of this theorem of cla ...
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George David Birkhoff
George David Birkhoff (March 21, 1884 – November 12, 1944) was an American mathematician best known for what is now called the ergodic theorem. Birkhoff was one of the most important leaders in American mathematics in his generation, and during his time he was considered by many to be the preeminent American mathematician. The George D. Birkhoff House, his residence in Cambridge, Massachusetts, has been designated a National Historic Landmark. Personal life He was born in Overisel Township, Michigan, the son of David Birkhoff and Jane Gertrude Droppers. The mathematician Garrett Birkhoff (1911–1996) was his son. Career Birkhoff obtained his A.B. and A.M. from Harvard University. He completed his Ph.D. in 1907, on differential equations, at the University of Chicago. While E. H. Moore was his supervisor, he was most influenced by the writings of Henri Poincaré. After teaching at the University of Wisconsin–Madison and Princeton University, he taught at Harvard from 191 ...
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Ergodic Theorem
Ergodic theory (Greek: ' "work", ' "way") is a branch of mathematics that studies statistical properties of deterministic dynamical systems; it is the study of ergodicity. In this context, statistical properties means properties which are expressed through the behavior of time averages of various functions along trajectories of dynamical systems. The notion of deterministic dynamical systems assumes that the equations determining the dynamics do not contain any random perturbations, noise, etc. Thus, the statistics with which we are concerned are properties of the dynamics. Ergodic theory, like probability theory, is based on general notions of measure theory. Its initial development was motivated by problems of statistical physics. A central concern of ergodic theory is the behavior of a dynamical system when it is allowed to run for a long time. The first result in this direction is the Poincaré recurrence theorem, which claims that almost all points in any subset of the p ...
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Ergodic Hypothesis
In physics and thermodynamics, the ergodic hypothesis says that, over long periods of time, the time spent by a system in some region of the phase space of microstates with the same energy is proportional to the volume of this region, i.e., that all accessible microstates are equiprobable over a long period of time. Liouville's theorem states that, for Hamiltonian systems, the local density of microstates following a particle path through phase space is constant as viewed by an observer moving with the ensemble (i.e., the convective time derivative is zero). Thus, if the microstates are uniformly distributed in phase space initially, they will remain so at all times. But Liouville's theorem does ''not'' imply that the ergodic hypothesis holds for all Hamiltonian systems. The ergodic hypothesis is often assumed in the statistical analysis of computational physics. The analyst would assume that the average of a process parameter over time and the average over the statistical ...
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Equilibrium Thermodynamics
{{thermodynamics, cTopic=Branches Equilibrium Thermodynamics is the systematic study of transformations of matter and energy in systems in terms of a concept called thermodynamic equilibrium. The word equilibrium implies a state of balance. Equilibrium thermodynamics, in origins, derives from analysis of the Carnot cycle. Here, typically a system, as cylinder of gas, initially in its own state of internal thermodynamic equilibrium, is set ''out of balance'' via heat input from a combustion reaction. Then, through a series of steps, as the system settles into its final equilibrium state, work is extracted. In an equilibrium state the potentials, or driving forces, within the system, are in exact balance. A central aim in equilibrium thermodynamics is: given a system in a well-defined initial state of thermodynamic equilibrium, subject to accurately specified constraints, to calculate, when the constraints are changed by an externally imposed intervention, what the state of th ...
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Action (physics)
In physics, action is a scalar quantity describing how a physical system has dynamics (physics), changed over time. Action is significant because the equations of motion of the system can be derived through the principle of stationary action. In the simple case of a single particle moving with a constant velocity (uniform linear motion), the action is the momentum of the particle times the distance it moves, integral (mathematics), added up along its path; equivalently, action is twice the particle's kinetic energy times the duration for which it has that amount of energy. For more complicated systems, all such quantities are combined. More formally, action is a functional (mathematics), mathematical functional which takes the trajectory (also called path or history) of the system as its argument and has a real number as its result. Generally, the action takes different values for different paths. Action has dimensional analysis, dimensions of energy × time or momentu ...
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Kinetic Energy
In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acceleration, the body maintains this kinetic energy unless its speed changes. The same amount of work is done by the body when decelerating from its current speed to a state of rest. Formally, a kinetic energy is any term in a system's Lagrangian which includes a derivative with respect to time. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2. In relativistic mechanics, this is a good approximation only when ''v'' is much less than the speed of light. The standard unit of kinetic energy is the joule, while the English unit of kinetic energy is the foot-pound. History and etymology The adjective ''kinetic'' has its roots in the Greek word κίνησις ''kinesis'', m ...
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Entropy
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication. The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names ''thermodynamic function'' and ''heat-potential''. In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of hea ...
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Temperature
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called ''centigrade''), the Fahrenheit scale (°F), and the Kelvin scale (K), the latter being used predominantly for scientific purposes. The kelvin is one of the seven base units in the International System of Units (SI). Absolute zero, i.e., zero kelvin or −273.15 °C, is the lowest point in the thermodynamic temperature scale. Experimentally, it can be approached very closely but not actually reached, as recognized in the third law of thermodynamics. It would be impossible to extract energy as heat from a body at that temperature. Temperature is important in all fields of natur ...
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