Heinrich Hubert Maria Josef Houben
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Heinrich Hubert Maria Josef Houben
Heinrich Hubert Maria Josef Houben (27 October 1875, in Waldfeucht (Rheinland) Germany – 28 June 1940, in Tübingen) was a German chemist. He made achievements within ketone synthesis, terpenes, and camphor studies. After being wounded several times on the front lines in World War I, Houben was made head of the war laboratory. He improved the Hoesch reaction which is now normally called Houben-Hoesch reaction. Houben organized and made a major rework of the book Methods of Organic Chemistry which is now referred to as Houben-Weyl Methods of Organic Chemistry. Life Houben studied at the University of Bonn and changed his subjects from mathematics and astronomy to chemistry under the influence of August Kekulé. He received his Ph.D. for work with Julius Bredt in 1898, and they collaborated on the initial 1902 publication of what became known as Bredt's Rule. After some time at the University of Aachen and University of Bonn Houben joined the laboratory of Emil Fischer at the Uni ...
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Waldfeucht
Waldfeucht ( li, Vuch ) is a German municipality in the Heinsberg district, in North Rhine-Westphalia, Federal Republic of Germany. It is situated on the border with the Kingdom of the Netherlands, approx. 15 km south of Roermond and 8 km west of Heinsberg. Geography Waldfeucht is located west of Heinsberg in the Selfkant natural area between the Wurm river in the east and the Meuse river in the west. To the west, the border between the Netherlands and Germany forms the municipal boundary over a length of about 10 km. The highest point in the community is 72.7 m above sea level, normalnull is located south of the "Breuner Maar" between Bocket and Breberen, the lowest point 31.7 m is in the Kitscher Bruch between the villages of Haaren and Karken on the municipal border. The municipal area extends 8.5 km north to south and it is 6.0 km from west to east. Population centers In addition to the town of Waldfeucht, these villages belong to the municipal ...
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University Of Bonn
The Rhenish Friedrich Wilhelm University of Bonn (german: Rheinische Friedrich-Wilhelms-Universität Bonn) is a public research university located in Bonn, North Rhine-Westphalia, Germany. It was founded in its present form as the ( en, Rhine University) on 18 October 1818 by Frederick William III, as the linear successor of the ( en, Academy of the Prince-elector of Cologne) which was founded in 1777. The University of Bonn offers many undergraduate and graduate programs in a range of subjects and has 544 professors. The University of Bonn is a member of the U15 (German universities), German U15 association of major research-intensive universities in Germany and has the title of "University of Excellence" under the German Universities Excellence Initiative; it is consistently ranked amongst the best German universities in the world rankings and is one of the most research intensive universities in Germany. Bonn has 6 Clusters of Excellence, the most of any German university; t ...
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1940 Deaths
Year 194 ( CXCIV) was a common year starting on Tuesday (link will display the full calendar) of the Julian calendar. At the time, it was known as the Year of the Consulship of Septimius and Septimius (or, less frequently, year 947 ''Ab urbe condita''). The denomination 194 for this year has been used since the early medieval period, when the Anno Domini calendar era became the prevalent method in Europe for naming years. Events By place Roman Empire * Emperor Septimius Severus and Decimus Clodius Septimius Albinus Caesar become Roman Consuls. * Battle of Issus: Septimius Severus marches with his army (12 legions) to Cilicia, and defeats Pescennius Niger, Roman governor of Syria. Pescennius retreats to Antioch, and is executed by Severus' troops. * Septimius Severus besieges Byzantium (194–196); the city walls suffer extensive damage. Asia * Battle of Yan Province: Warlords Cao Cao and Lü Bu fight for control over Yan Province; the battle lasts for over 100 ...
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1875 Births
Events January–March * January 1 – The Midland Railway of England abolishes the Second Class passenger category, leaving First Class and Third Class. Other British railway companies follow Midland's lead during the rest of the year (Third Class is renamed Second Class in 1956). * January 5 – The Palais Garnier, one of the most famous opera houses in the world, is inaugurated in Paris. * January 12 – Guangxu Emperor, Guangxu becomes the 11th Qing Dynasty Emperor of China at the age of 3, in succession to his cousin. * January 14 – The newly proclaimed King Alfonso XII of Spain (Queen Isabella II's son) arrives in Spain to restore the monarchy during the Third Carlist War. * February 3 – Third Carlist War – Battle of Lácar: Carlist commander Torcuato Mendiri, Torcuato Mendíri secures a brilliant victory, when he surprises and routs a Government force under General Enrique Bargés at Lácar, east of Estella, nearly capturing newly cr ...
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Organomagnesium Compound
Magnesium anthracenide with three thf ligands. Group 2 organometallic chemistry refers to the chemistry of compounds containing carbon bonded to any group 2 element. By far the most common group 2 organometallic compounds are the magnesium-containing Grignard reagents which are widely used in organic chemistry. Other organmetallic group 2 compounds are rare and are typically limited to academic interests. Characteristics As the group 2 elements (also referred to as the alkaline earth metals) contain two valence electrons, their chemistries have similarities group 12 organometallic compounds. Both readily assume a +2 oxidation states with higher and lower states being rare, and are less electronegative than carbon. However, as the group two elements (with the exception of beryllium) have considerably low electronegativity the resulting C-M bonds are more highly polarized and ionic-like, if not entirely ionic for the heavier barium compounds. The lighter organoberyllium and organom ...
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University Of Berlin
Humboldt-Universität zu Berlin (german: Humboldt-Universität zu Berlin, abbreviated HU Berlin) is a German public research university in the central borough of Mitte in Berlin. It was established by Frederick William III on the initiative of Wilhelm von Humboldt, Johann Gottlieb Fichte and Friedrich Ernst Daniel Schleiermacher as the University of Berlin () in 1809, and opened in 1810, making it the oldest of Berlin's four universities. From 1828 until its closure in 1945, it was named Friedrich Wilhelm University (german: Friedrich-Wilhelms-Universität). During the Cold War, the university found itself in  East Berlin and was ''de facto'' split in two when the Free University of Berlin opened in West Berlin. The university received its current name in honour of Alexander and Wilhelm von Humboldt in 1949. The university is divided into nine faculties including its medical school shared with the Freie Universität Berlin. The university has a student enrollment of around ...
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Hermann Emil Fischer
Hermann Emil Louis Fischer (; 9 October 1852 – 15 July 1919) was a German chemist and 1902 recipient of the Nobel Prize in Chemistry. He discovered the Fischer esterification. He also developed the Fischer projection, a symbolic way of drawing asymmetric carbon atoms. He also hypothesized lock and key mechanism of enzyme action. He never used his first given name, and was known throughout his life simply as Emil Fischer. Early years and career Fischer was born in Euskirchen, near Cologne, the son of Laurenz Fischer, a businessman, and his wife Julie Poensgen. After graduating he wished to study natural sciences, but his father compelled him to work in the family business until determining that his son was unsuitable. Fischer then attended the University of Bonn in 1871, but switched to the University of Strasbourg in 1872. He earned his doctorate in 1874 under Adolf von Baeyer with his study of phthaleins, and was appointed to a position at the university. After eight ye ...
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University Of Aachen
RWTH Aachen University (), also known as North Rhine-Westphalia Technical University of Aachen, Rhine-Westphalia Technical University of Aachen, Technical University of Aachen, University of Aachen, or ''Rheinisch-Westfälische Technische Hochschule Aachen'', is a German public research university located in Aachen, North Rhine-Westphalia, Germany. With more than 47,000 students enrolled in 144 study programs, it is the largest technical university in Germany. In 2018, the university was ranked 31st in the world university rankings in the field of engineering and technology, and 36th world-wide in the category of natural sciences.Daten & Fakten – RWTH AACHEN UNIVERSITY – Deutsch
Rwth-aachen.de (12 December 2011). Retrieved on 2013-09-18.

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Bredt's Rule
Bredt's rule is an empirical observation in organic chemistry that states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. The rule is named after Julius Bredt, who first discussed it in 1902 and codified it in 1924. It primarily relates to bridgeheads with carbon-carbon and carbon-nitrogen double bonds. For example, two of the following isomers of norbornene violate Bredt's rule, which makes them too unstable to prepare: In the figure, the bridgehead atoms involved in Bredt's rule violation are highlighted in red. Bredt's rule is a consequence of the fact that having a double bond on a bridgehead, carbons from which three bonds radiate and which the rings share a single covalent bond, would be equivalent to having a trans double bond on a ring, which is not stable for small rings (fewer than eight atoms) due to a combination of ring strain, and angle strain (nonplanar alkene). The p orbitals of the bridgehead ...
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August Kekulé
Friedrich August Kekulé, later Friedrich August Kekule von Stradonitz ( , ; 7 September 1829 – 13 July 1896), was a German organic chemist. From the 1850s until his death, Kekulé was one of the most prominent chemists in Europe, especially in theoretical chemistry. He was the principal founder of the theory of chemical structure and in particular the Kekulé structure of benzene. Name Kekulé never used his first given name; he was known throughout his life as August Kekulé. After he was ennobled by the Kaiser in 1895, he adopted the name August Kekule von Stradonitz, without the French acute accent over the second "e". The French accent had apparently been added to the name by Kekulé's father during the Napoleonic occupation of Hesse by France, to ensure that French-speaking people pronounced the third syllable. Early years The son of a civil servant, Kekulé was born in Darmstadt, the capital of the Grand Duchy of Hesse. After graduating from secondary school (the Grand ...
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World War I
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fighting occurring throughout Europe, the Middle East, Africa, the Pacific, and parts of Asia. An estimated 9 million soldiers were killed in combat, plus another 23 million wounded, while 5 million civilians died as a result of military action, hunger, and disease. Millions more died in genocides within the Ottoman Empire and in the 1918 influenza pandemic, which was exacerbated by the movement of combatants during the war. Prior to 1914, the European great powers were divided between the Triple Entente (comprising France, Russia, and Britain) and the Triple Alliance (containing Germany, Austria-Hungary, and Italy). Tensions in the Balkans came to a head on 28 June 1914, following the assassination of Archduke Franz Ferdin ...
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