Hans Theodor Bucherer
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Hans Theodor Bucherer
Hans Theodor Bucherer (19 May 1869 – 29 May 1949) was a German chemist and gave name to several chemical reactions, for example the Bucherer carbazole synthesis, the Bucherer reaction, and the Bucherer–Bergs reaction Life Bucherer started studying chemistry at the University of Munich, University of Karlsruhe and later with Johannes Wislicenus at the University of Leipzig. After he received his Ph.D in 1893 he worked at BASF. He became professor at Technical University of Dresden in 1901 changed to the Technical University of Berlin in 1913 and became professor at the Technical University of Munich The Technical University of Munich (TUM or TU Munich; german: Technische Universität München) is a public research university in Munich, Germany. It specializes in engineering, technology, medicine, and applied and natural sciences. Establis ... in 1926. References 1869 births 1949 deaths 20th-century German chemists Academic staff of the Technical University o ...
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Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated between the Baltic and North seas to the north, and the Alps to the south; it covers an area of , with a population of almost 84 million within its 16 constituent states. Germany borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France, Luxembourg, Belgium, and the Netherlands to the west. The nation's capital and most populous city is Berlin and its financial centre is Frankfurt; the largest urban area is the Ruhr. Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity. A region named Germania was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire. During the 16th ce ...
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BASF
BASF Societas Europaea, SE () is a German multinational corporation, multinational chemical company and the List of largest chemical producers, largest chemical producer in the world. Its headquarters is located in Ludwigshafen, Germany. The BASF Group comprises subsidiary, subsidiaries and joint ventures in more than 80 countries and operates six integrated production sites and 390 other production sites in Europe, Asia, Australia, the Americas and Africa. BASF has customers in over 190 countries and supplies products to a wide variety of industries. Despite its size and global presence, BASF has received relatively little public attention since it abandoned the manufacture and sale of BASF-branded consumer electronics products in the 1990s. At the end of 2019, the company employed 117,628 people, with over 54,000 in Germany. , BASF posted sales of €59.3 billion and income from operations before special items of about €4.5 billion. Between 1990 and 2005, the co ...
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Technical University Of Dresden
TU Dresden (for german: Technische Universität Dresden, abbreviated as TUD and often wrongly translated as "Dresden University of Technology") is a public research university, the largest institute of higher education in the city of Dresden, the largest university in Saxony and one of the 10 largest universities in Germany with 32,389 students . The name Technische Universität Dresden has only been used since 1961; the history of the university, however, goes back nearly 200 years to 1828. This makes it one of the oldest colleges of technology in Germany, and one of the country’s oldest universities, which in German today refers to institutes of higher education that cover the entire curriculum. The university is a member of TU9, a consortium of the nine leading German Institutes of Technology. The university is one of eleven German universities which succeeded in the German Universities Excellence Initiative, Excellence Initiative in 2012, thus getting the title of a "Univer ...
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Technical University Of Berlin
The Technical University of Berlin (official name both in English and german: link=no, Technische Universität Berlin, also known as TU Berlin and Berlin Institute of Technology) is a public research university located in Berlin, Germany. It was the first German university to adopt the name "Technische Universität" (Technical University). The university alumni and professor list includes several US National Academies members, two National Medal of Science laureates and ten Nobel Prize laureates. TU Berlin is a member of TU9, an incorporated society of the largest and most notable German institutes of technology and of the Top International Managers in Engineering network, which allows for student exchanges between leading engineering schools. It belongs to the Conference of European Schools for Advanced Engineering Education and Research. The TU Berlin is home of two innovation centers designated by the European Institute of Innovation and Technology. The university is labeled ...
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Technical University Of Munich
The Technical University of Munich (TUM or TU Munich; german: Technische Universität München) is a public research university in Munich, Germany. It specializes in engineering, technology, medicine, and applied and natural sciences. Established in 1868 by King Ludwig II of Bavaria, the university now has additional campuses in Garching, Freising, Heilbronn, Straubing, and Singapore, with the Garching campus being its largest. The university is organized into eight schools and departments, and is supported by numerous research centers. It is one of the largest universities in Germany, with 50,000 students and an annual budget of €1,770.3 million (including university hospital). A ''University of Excellence'' under the German Universities Excellence Initiative, TUM is considered the top university in Germany according to major rankings as of 2022 and is among the leading universities in the European Union. Its researchers and alumni include 18 Nobel laureates and 23 Leib ...
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University Of Leipzig
Leipzig University (german: Universität Leipzig), in Leipzig in Saxony, Germany, is one of the world's oldest universities and the second-oldest university (by consecutive years of existence) in Germany. The university was founded on 2 December 1409 by Frederick I, Elector of Saxony and his brother William II, Margrave of Meissen, and originally comprised the four scholastic faculties. Since its inception, the university has engaged in teaching and research for over 600 years without interruption. Famous alumni include Gottfried Wilhelm von Leibniz, Johann Wolfgang von Goethe, Leopold von Ranke, Friedrich Nietzsche, Robert Schumann, Richard Wagner, Tycho Brahe, Georgius Agricola, Angela Merkel and ten Nobel laureates associated with the university. History Founding and development until 1900 The university was modelled on the University of Prague, from which the German-speaking faculty members withdrew to Leipzig after the Jan Hus crisis and the Decree of Kutná H ...
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Johannes Wislicenus
Johannes Wislicenus (24 June 1835 – 5 December 1902) was a German chemist, most famous for his work in early stereochemistry. Biography The son of the radical Protestant theologian Gustav Wislicenus, Johannes was born on 24 June 1835 in Kleineichstedt (now part of Querfurt, Saxony-Anhalt) in Prussian Saxony, and entered Halle University in 1853. In October 1853 he emigrated to the United States with his family. For a brief time he acted as assistant to Harvard chemist Eben Horsford, and in 1855 was appointed lecturer at the Mechanics' Institute in New York. Returning to Europe in 1856, he continued to study chemistry with Wilhelm Heinrich Heintz at the University of Halle. In 1860, he began lecturing at the University of Zürich, and at the Swiss Polytechnical Institute and by 1868 he was Professor of Chemistry at the university. In 1870, he was chosen to succeed Georg Staedeler as Professor of General Chemistry at the Swiss Polytechnical Institute in Zürich, retaining al ...
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Bucherer Carbazole Synthesis
The Bucherer carbazole synthesis is a chemical reaction used to synthesize carbazoles from naphthols and aryl hydrazines using sodium bisulfite. The reaction is named after Hans Theodor Bucherer. See also * Borsche-Drechsel cyclization *Bucherer reaction The Bucherer reaction in organic chemistry is the reversible conversion of a naphthol to a naphthylamine in the presence of ammonia and sodium bisulfite. The reaction is widely used in the synthesis of dye precursors aminonaphthalenesulfonic ac ... References * * {{Organic reactions Nitrogen heterocycle forming reactions Heterocycle forming reactions Name reactions ...
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Bucherer Reaction
The Bucherer reaction in organic chemistry is the reversible conversion of a naphthol to a naphthylamine in the presence of ammonia and sodium bisulfite. The reaction is widely used in the synthesis of dye precursors aminonaphthalenesulfonic acids. :C10H7-2-OH + NH3 C10H7-2-NH2 + H2O The French chemist Robert Lepetit was the first to discover the reaction in 1898. The German chemist Hans Theodor Bucherer (1869–1949) discovered (independent from Lepetit) its reversibility and its potential especially in industrial chemistry. Bucherer published his results in 1904 and his name is connected to this reaction. The organic reaction also goes by the name Bucherer-Lepetit reaction or (wrongly) the Bucherer-Le Petit reaction. The reaction is used to convert 1,7-dihydroxynaphthalene into 7-amino-1-naphthol and 1-aminonaphthalene-4-sulfonic acid into 1-hydroxynaphthalene-4-sulfonic acid. It is also useful for transamination reactions of 2-aminonaphthalenes. Mechanism In ...
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Bucherer–Bergs Reaction
The Bucherer–Bergs reaction is the chemical reaction of carbonyl compounds (aldehydes or ketones) or cyanohydrins with ammonium carbonate and potassium cyanide to give hydantoins. The reaction is named after Hans Theodor Bucherer. ''Overall Reaction'' Reaction Mechanism Following condensation of the carbonyl with the ammonium, the formed imine is attacked by the isocyanide to form the aminonitrile. Nucleophilic addition of aminonitrile to CO2 leads to cyano-carbamic acid, which undergoes an intramolecular ring closing to 5-imino-oxazolidin-2-one. The 5-imino-oxazolidin-2-one rearranges to form the hydantoin product via an isocyanate intermediate. History Reactions similar to the Bucherer–Bergs reaction were first seen in 1905 and 1914 by Ciamician and Silber, who obtained 5,5-dimethylhydantoin from a mixture of acetone and hydrocyanic acid after it had been exposed to sunlight for five to seven months. In 1929, Bergs issued a patent that described his own synthesis of a ...
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University Of Munich
The Ludwig Maximilian University of Munich (simply University of Munich or LMU; german: Ludwig-Maximilians-Universität München) is a public research university in Munich, Germany. It is Germany's List of universities in Germany, sixth-oldest university in continuous operation. Originally University of Ingolstadt, established in Ingolstadt in 1472 by Louis IX, Duke of Bavaria, Duke Ludwig IX of Bavaria-Landshut, the university was moved in 1800 to Landshut by Maximilian I Joseph of Bavaria, King Maximilian I of Bavaria when the city was threatened by the French, before being relocated to its present-day location in Munich in 1826 by Ludwig I of Bavaria, King Ludwig I of Bavaria. In 1802, the university was officially named Ludwig-Maximilians-Universität by King Maximilian I of Bavaria in honor of himself and Ludwig IX. LMU is currently the second-largest university in Germany in terms of student population; in the 2018/19 winter semester, the university had a total of 51,606 m ...
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University Of Karlsruhe
The Karlsruhe Institute of Technology (KIT; german: Karlsruher Institut für Technologie) is a public research university in Karlsruhe, Germany. The institute is a national research center of the Helmholtz Association. KIT was created in 2009 when the University of Karlsruhe (), founded in 1825 as a public research university and also known as the "Fridericiana", merged with the Karlsruhe Research Center (), which had originally been established in 1956 as a national nuclear research center (, or KfK). KIT is a member of the TU9, an incorporated society of the largest and most notable German institutes of technology.TU9 As part of the German Universities Excellence Initiative KIT was one of three universities which were awarded excellence status in 2006. In the following "German Excellence Strategy" KIT was awarded as one of eleven "Excellence Universities" in 2019. KIT is among the leading technical universities in Germany and Europe. According to different bibliometric ranking ...
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