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H-stable
In statistical mechanics of continuous systems, a potential for a many-body system is called H-stable (or simply stable) if the potential energy per particle is bounded below by a constant that is independent of the total number of particles. In many circumstances, if a potential is not H-stable, it is not possible to define a grand canonical ensemble, grand canonical partition function in finite volume, because of ''catastrophic configurations'' with infinite particles located in a finite space. Classical statistical mechanics Definition Consider a system of particles in positions x_1, x_2,\ldots \in R^\nu; the ''interaction'' or ''potential'' between a particle in position x_i and a particle in position x_j is :\phi(x_i-x_j) \, where \phi(x) is a real, even (possibly unbounded) function. Then \phi(x) is H-stable if there exists B>0 such that, for any n\ge1 and any x_1, x_2,\ldots, x_n\in R^\nu, :V_n(x_1, x_2,\ldots x_n):=\sum_^n \phi(x_i-x_j)\ge-Bn\, Applications * If \p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Limit
In statistical mechanics, the thermodynamic limit or macroscopic limit, of a system is the limit for a large number of particles (e.g., atoms or molecules) where the volume is taken to grow in proportion with the number of particles.S.J. Blundell and K.M. Blundell, "Concepts in Thermal Physics", Oxford University Press (2009) The thermodynamic limit is defined as the limit of a system with a large volume, with the particle density held fixed. : N \to \infty,\, V \to \infty,\, \frac N V =\text In this limit, macroscopic thermodynamics is valid. There, thermal fluctuations in global quantities are negligible, and all thermodynamic quantities, such as pressure and energy, are simply functions of the thermodynamic variables, such as temperature and density. For example, for a large volume of gas, the fluctuations of the total internal energy are negligible and can be ignored, and the average internal energy can be predicted from knowledge of the pressure and temperature of the gas. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potential Energy
In physics, potential energy is the energy held by an object because of its position relative to other objects, stresses within itself, its electric charge, or other factors. Common types of potential energy include the gravitational potential energy of an object, the elastic potential energy of an extended spring, and the electric potential energy of an electric charge in an electric field. The unit for energy in the International System of Units (SI) is the joule, which has the symbol J. The term ''potential energy'' was introduced by the 19th-century Scottish engineer and physicist William Rankine, although it has links to Greek philosopher Aristotle's concept of potentiality. Potential energy is associated with forces that act on a body in a way that the total work done by these forces on the body depends only on the initial and final positions of the body in space. These forces, that are called ''conservative forces'', can be represented at every point in space by vec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Grand Canonical Ensemble
In statistical mechanics, the grand canonical ensemble (also known as the macrocanonical ensemble) is the statistical ensemble that is used to represent the possible states of a mechanical system of particles that are in thermodynamic equilibrium (thermal and chemical) with a reservoir. The system is said to be open in the sense that the system can exchange energy and particles with a reservoir, so that various possible states of the system can differ in both their total energy and total number of particles. The system's volume, shape, and other external coordinates are kept the same in all possible states of the system. The thermodynamic variables of the grand canonical ensemble are chemical potential (symbol: ) and absolute temperature (symbol: . The ensemble is also dependent on mechanical variables such as volume (symbol: which influence the nature of the system's internal states. This ensemble is therefore sometimes called the ensemble, as each of these three quantities ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Positive-definite Function
In mathematics, a positive-definite function is, depending on the context, either of two types of function. Most common usage A ''positive-definite function'' of a real variable ''x'' is a complex-valued function f: \mathbb \to \mathbb such that for any real numbers ''x''1, …, ''x''''n'' the ''n'' × ''n'' matrix : A = \left(a_\right)_^n~, \quad a_ = f(x_i - x_j) is positive ''semi-''definite (which requires ''A'' to be Hermitian; therefore ''f''(−''x'') is the complex conjugate of ''f''(''x'')). In particular, it is necessary (but not sufficient) that : f(0) \geq 0~, \quad , f(x), \leq f(0) (these inequalities follow from the condition for ''n'' = 1, 2.) A function is ''negative semi-definite'' if the inequality is reversed. A function is ''definite'' if the weak inequality is replaced with a strong ( 0). Examples If (X, \langle \cdot, \cdot \rangle) is a real inner product space, then g_y \colon X \to \mathbb, x \mapsto \exp(i \langle y, x \rangle ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coulomb System
The coulomb (symbol: C) is the unit of electric charge in the International System of Units (SI). In the present version of the SI it is equal to the electric charge delivered by a 1 ampere constant current in 1 second and to elementary charges, , (about ). Name and history By 1878, the British Association for the Advancement of Science had defined the volt, ohm, and farad, but not the coulomb. In 1881, the International Electrical Congress, now the International Electrotechnical Commission (IEC), approved the volt as the unit for electromotive force, the ampere as the unit for electric current, and the coulomb as the unit of electric charge. At that time, the volt was defined as the potential difference .e., what is nowadays called the "voltage (difference)"across a conductor when a current of one ampere dissipates one watt of power. The coulomb (later "absolute coulomb" or "abcoulomb" for disambiguation) was part of the EMU system of units. The "international coulomb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tempered Potential
Temper, tempered or tempering may refer to: Heat treatment * Tempering (metallurgy), a heat treatment technique to increase the toughness of iron-based alloys **Temper mill, a steel processing line * Tempering (spices), a cooking technique where spices are roasted briefly in oil or ghee * Tempered glass, a type of safety glass processed by controlled thermal or chemical treatments * Tempering chocolate, processing to ensure a uniform sheen and crisp bite * Temper (pottery), a non-plastic material added to clay to prevent shrinkage during drying and firing Arts and entertainment * ''Temper'' (film), a 2015 Telugu film ** ''Temper'' (soundtrack), or the title track, 2015 * Temper (band), a dance music group * ''Temper'', a 2008 album by Benoit Pioulard * "Temper", a song by Cyberaktif from the 1991 album ''Tenebrae Vision'' * "Temper", a 2021 song by Vera Blue * ''Temper, or, Domestic Scenes'', a novel by Amelia Opie, 1812–1813 * ''The Tempering'', a young-adult novel by G ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uncertainty Principle
In quantum mechanics, the uncertainty principle (also known as Heisenberg's uncertainty principle) is any of a variety of mathematical inequalities asserting a fundamental limit to the accuracy with which the values for certain pairs of physical quantities of a particle, such as position, ''x'', and momentum, ''p'', can be predicted from initial conditions. Such variable pairs are known as complementary variables or canonically conjugate variables; and, depending on interpretation, the uncertainty principle limits to what extent such conjugate properties maintain their approximate meaning, as the mathematical framework of quantum physics does not support the notion of simultaneously well-defined conjugate properties expressed by a single value. The uncertainty principle implies that it is in general not possible to predict the value of a quantity with arbitrary certainty, even if all initial conditions are specified. Introduced first in 1927 by the German physicist Werner ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ground State
The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum. If more than one ground state exists, they are said to be degenerate. Many systems have degenerate ground states. Degeneracy occurs whenever there exists a unitary operator that acts non-trivially on a ground state and commutes with the Hamiltonian of the system. According to the third law of thermodynamics, a system at absolute zero temperature exists in its ground state; thus, its entropy is determined by the degeneracy of the ground state. Many systems, such as a perfect crystal lattice, have a unique ground state and therefore have zero entropy at absolute zero. It is also possible for the highest excited state to have absolute zero temper ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
