Grandreefite
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Grandreefite
Grandreefite is a rare secondary lead sulfate-fluoride mineral with a general chemical formula, Pb2SO4F2. It is named for the location in which it was discovered in 1989, the Grand Reef Mine in Graham County, Arizona. Grandreefite is monoclinic, falling in the 2/m symmetry group. Crystallographically this means, grandreefite has three axes of unequal length, with two angles at 90° to one another and a third, obtuse angle. The 2/m symmetry group indicates a two-fold axis with a perpendicular mirror plane. Grandreefite was originally classified as an orthorhombic mineral but was determined monoclinic instead upon further analysis. Pseudograndreefite, one of three other newly discovered minerals in 1989 at the Grand Reef Mine site, has orthorhombic crystallography. Optically, grandreefite is an anisotropic mineral, meaning the velocity of light varies depending on the direction through which it is passing through the mineral. Its calculated relief, i.e. its relative difference in in ...
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Sulfate Minerals
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal Vein (geology), veins and as secondary minerals in the Redox, oxidizing zone of sulfide mineral deposits. The Chromate ion, chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 **Anglesite PbSO4 **Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O **Kieserite MgSO4·H2O **Starkeyite MgSO4·4H2O **Hexahydrite MgSO4·6H2O **Epsomite MgSO4·7H2O **Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O **Antlerite ...
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Intrusion
In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and compositions, illustrated by examples like the Palisades Sill of New York and New Jersey; the Henry Mountains of Utah; the Bushveld Igneous Complex of South Africa; Shiprock in New Mexico; the Ardnamurchan intrusion in Scotland; and the Sierra Nevada Batholith of California. Because the solid country rock into which magma intrudes is an excellent insulator, cooling of the magma is extremely slow, and intrusive igneous rock is coarse-grained (phaneritic). Intrusive igneous rocks are classified separately from extrusive igneous rocks, generally on the basis of their mineral content. The relative amounts of quartz, alkali feldspar, plagioclase, and feldspathoid is particularly important in classifying intrusive igneous rocks. Intrusions ...
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Lead Minerals
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the group, le ...
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Breccia
Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix. The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of different origins, as indicated by the named types including sedimentary breccia, tectonic breccia, igneous breccia, impact breccia, and hydrothermal breccia. A megabreccia is a breccia composed of very large rock fragments, sometimes kilometers across, which can be formed by landslides, impact events, or caldera collapse. Types Breccia is composed of coarse rock fragments held together by cement or a fine-grained matrix. Like conglomerate, breccia contains at least 30 percent of gravel-sized particles (particles over 2mm in size), but it is distinguished from conglomerate because the rock fragments have sharp edges that have not been worn down. These indicate that the gravel was deposited very close to its source area, since otherwise th ...
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Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ...
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Lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the ...
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Silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earth's crust in the pure, free elemental form ("native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc Refining (metallurgy), refining. Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes bimetallism, alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of th ...
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Copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form ( native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create ...
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Hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie.'' Oxford: Clarendon Press. and θέρμη, ''heat'' ). Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the shallow to mid crust along deeply penetrating fault irregularities or in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Seafloor hydrothermal circulation Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems. The term includes both the circulation of the well-known, high-temperature vent waters near the ridge crests, and the much-lower-temperature, diffuse flow of water through sedim ...
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Vein (geology)
In geology, a vein is a distinct sheetlike body of crystallized minerals within a rock. Veins form when mineral constituents carried by an aqueous solution within the rock mass are deposited through precipitation. The hydraulic flow involved is usually due to hydrothermal circulation. Veins are classically thought of as being the ones in the body not the rock veins and arteries planar fractures in rocks, with the crystal growth occurring normal to the walls of the cavity, and the crystal protruding into open space. This certainly is the method for the formation of some veins. However, it is rare in geology for significant open space to remain open in large volumes of rock, especially several kilometers below the surface. Thus, there are two main mechanisms considered likely for the formation of veins: ''open-space filling'' and ''crack-seal growth''. Open space filling Open space filling is the hallmark of epithermal vein systems, such as a stockwork, in greisens or in cert ...
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Granite
Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies underground. It is common in the continental crust of Earth, where it is found in igneous intrusions. These range in size from dikes only a few centimeters across to batholiths exposed over hundreds of square kilometers. Granite is typical of a larger family of ''granitic rocks'', or ''granitoids'', that are composed mostly of coarse-grained quartz and feldspars in varying proportions. These rocks are classified by the relative percentages of quartz, alkali feldspar, and plagioclase (the QAPF classification), with true granite representing granitic rocks rich in quartz and alkali feldspar. Most granitic rocks also contain mica or amphibole minerals, though a few (known as leucogranites) contain almost no dark minerals. Granite is nearly alway ...
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Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below org ...
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