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Gold Telluride
Gold chalcogenides are compounds formed between gold and one of the chalcogens, elements from group 16 of the periodic table: oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ..., sulfur, selenium, or tellurium. * Gold(III) oxide, Au2O3. Decomposes into gold and oxygen above 160 °C, and dissolves in concentrated alkalis to form solutions which probably contain the u(OH)4sup>− ion * Gold(I) sulfide, Au2S. Formed by passing hydrogen sulfide through solutions of gold(I) compounds. * Gold(III) sulfide, Au2S3, unstable in the presence of water. *Gold tellurides: Au2Te3, Au3Te5, and AuTe2 (approximate formulæ) are known as non-stoichiometric compounds. They show metallic conductivity. One telluride of gold is a superconductor at very low temperatures: Au3Te5 (1. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile metal in a pure form. Chemically, gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements and is solid under standard conditions. Gold often occurs in free elemental ( native state), as nuggets or grains, in rocks, veins, and alluvial deposits. It occurs in a solid solution series with the native element silver (as electrum), naturally alloyed with other metals like copper and palladium, and mineral inclusions such as within pyrite. Less commonly, it occurs in minerals as gold compounds, often with tellurium ( gold tellurides). Gold is resistant to most acids, though it does dissolve in aqua regia (a mixture of nitric acid and hydrochloric acid), forming a soluble tetrachloroaurate an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Resistivity And Conductivity
Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows electric current. Resistivity is commonly represented by the Greek letter (rho). The SI unit of electrical resistivity is the ohm- meter (Ω⋅m). For example, if a solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is , then the resistivity of the material is . Electrical conductivity or specific conductance is the reciprocal of electrical resistivity. It represents a material's ability to conduct electric current. It is commonly signified by the Greek letter (sigma), but (kappa) (especially in electrical engineering) and (gamma) are sometimes used. The SI unit of electrical conductivity is siemens per metre (S/m). Resistivity and conductivity are intens ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfides
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH−) are the conjugate acids of sulfide. Chemical properties The sulfide ion, S2−, does not exist in aqueous alkaline solutions of Na2S. Instead sulfide converts to hydrosulfide: :S2− + H2O → SH− + OH− Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: :S2− + H+ → SH− :SH− + H+ → H2S Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. :8 MgS + 8 I2 → S8 + 8& ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Non-stoichiometric Compounds
In chemistry, non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogeneous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometric examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula , whereas the more common material is nonstoi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gold Compounds
Gold compounds are compounds by the element gold (Au). Although gold is the most noble of the noble metals, it still forms many diverse compounds. The oxidation state of gold in its compounds ranges from −1 to +5, but Au(I) and Au(III) dominate its chemistry. Au(I), referred to as the aurous ion, is the most common oxidation state with soft ligands such as thioethers, thiolates, and organophosphines. Au(I) compounds are typically linear. A good example is , which is the soluble form of gold encountered in mining. The binary gold halides, such as AuCl, form zigzag polymeric chains, again featuring linear coordination at Au. Most drugs based on gold are Au(I) derivatives. Au(III) (referred to as the auric) is a common oxidation state, and is illustrated by gold(III) chloride, . The gold atom centers in Au(III) complexes, like other d8 compounds, are typically square planar, with chemical bonds that have both covalent and ionic character. Gold(I,III) chloride is also known, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Telluride Mineral
A telluride mineral is a mineral that has the telluride anion as a main component. Tellurides are similar to sulfides and are grouped with them in both the Dana and Strunz mineral classification systems.http://webmineral.com/strunz/II.shtml Webmineral Strunz Examples include: * altaite * calaverite * coloradoite * empressite * hessite * kostovite * krennerite * melonite * merenskyite * petzite * rickardite * stützite * sylvanite * tellurobismuthite * temagamite * tetradymite * vulcanite See also * Cripple Creek & Victor Gold Mine The Cripple Creek & Victor Gold Mine, formerly and historically the Cresson Mine, is an active gold mine located near the town of Victor, in the Cripple Creek mining district in the US state of Colorado. The richest gold mine in Colorado histor ... References * {{Mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sylvanite
Sylvanite or silver gold telluride, chemical formula , is the most common telluride of gold. Properties The gold:silver ratio varies from 3:1 to 1:1. It is a metallic mineral with a color that ranges from a steely gray to almost white. It is closely related to calaverite, which is more purely gold telluride with 3% silver. Sylvanite crystallizes in the monoclinic 2/m system. Crystals are rare and it is usually bladed or granular. It is very soft with a hardness of 1.5–2. It has a high relative density of 8–8.2. Sylvanite is photosensitive and can accumulate a dark tarnish if it is exposed to bright light for too long. Occurrence Sylvanite is found in Transylvania, from which its name is partially derived. It is also found and mined in Australia in the East Kalgoorlie district. In Canada it is found in the Kirkland Lake Gold District, Ontario and the Rouyn District, Quebec. In the United States it occurs in California and in Colorado where it was mined as part of the Cr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Petzite
The mineral petzite, Ag3 Au Te2, is a soft, steel-gray telluride mineral generally deposited by hydrothermal activity. It forms isometric crystals, and is usually associated with rare tellurium and gold minerals, often with silver, mercury, and copper. The name comes from chemist W. Petz, who first analyzed the mineral from the type locality in Săcărâmb, Transylvania, Romania in 1845. It was described by Wilhelm Karl Ritter von Haidinger in 1845 and dedicated to W. Petz who had carried out the first analyses. It occurs with other tellurides in vein gold deposits. It is commonly associated with native gold, hessite, sylvanite, krennerite, calaverite, altaite, montbrayite, melonite, frohbergite, tetradymite, rickardite, vulcanite and pyrite. Petzite forms together with uytenbogaardtite The mineral uytenbogaardtite, Ag3AuS2, is a soft, greyish white sulfide mineral, occurring in hydrothermal Au-Ag-quartz veins. It occurs as tiny crystals, visible only with a mic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Krennerite
Krennerite is an orthorhombic gold telluride mineral which can contain variable amounts of silver in the structure. The formula is AuTe2, but specimen with gold substituted by up to 24% with silver have been found ( u0.77Ag0.24e2). Both of the chemically similar gold-silver tellurides, calaverite and sylvanite, are in the monoclinic crystal system, whereas krennerite is orthorhombic. The color varies from silver-white to brass-yellow. It has a specific gravity of 8.62 and a hardness of 2.5. It occurs in high temperature, hydrothermal environments. Krennerite was discovered in 1878 near the village of Săcărâmb, Romania, and first described by the Hungarian mineralogist Joseph Krenner (1839–1920). See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A * Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–2004)alfred *Abswurmbachite: Cu2+Mn3+6O ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calaverite
Calaverite, or gold telluride, is an uncommon telluride of gold, a metallic mineral with the chemical formula AuTe2, with approximately 3% of the gold replaced by silver. It was first discovered in Calaveras County, California in 1861, and was named for the county in 1868. The mineral often has a metallic luster, and its color may range from a silvery white to a brassy yellow. It is closely related to the gold-silver telluride mineral sylvanite, which, however, contains significantly more silver. Another AuTe2 mineral (but with a quite different crystal structure) is krennerite. Calaverite and sylvanite represent the major telluride ores of gold, although such ores are minor sources of gold in general. As a major gold mineral found in Western Australia, calaverite played a major role in the 1890s gold rushes in that area. Physical and chemical properties Calaverite occurs as monoclinic crystals, which do not possess cleavage planes. It has a specific gravity of 9.35 and a hard ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Non-stoichiometric Compound
In chemistry, non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogeneous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometric examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula , whereas the more common material is nonst ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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