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Glauberite
Glauberite is a monoclinic sodium calcium sulfate mineral with the formula Na2 Ca( S O4)2. It was first described in 1808 for material from the El Castellar Mine, Villarrubia de Santiago, Toledo, Castile-La Mancha, Spain. It was named for the extracted Glauber's salts after the German alchemist Johann Rudolf Glauber (1604–1668). Glauberite often forms in continental and marine evaporite deposits, but may also form from hydrothermal deposits, as mineral sublimates deposited near fumaroles, in amygdules in basalt, and in nitrate deposits in arid climates. It occurs associated with halite, polyhalite, anhydrite, gypsum, thenardite, mirabilite, sassolite and blodite. Because of its solubility, glauberite is often dissolved away from the crystal matrix leaving a distinctly shaped hollow cast. Its mineral composition is readily altered into other minerals as pseudomorphs. Gypsum pseudomorphs are common due to increased humidity. Glauberite, its cast impressions, and its pseud ...
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Sulfate Minerals
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 ** Anglesite PbSO4 ** Anhydrite CaSO4 ** Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O ** Kieserite MgSO4·H2O ** Starkeyite MgSO4·4H2O ** Hexahydrite MgSO4·6H2O ** Epsomite MgSO4·7H2O ** Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O ** Antlerite Cu3SO4(OH)4 **Brochant ...
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Mirabilite
Mirabilite, also known as Glauber's salt, is a hydrous sodium sulfate mineral with the chemical formula Na2SO4·10H2O. It is a vitreous, colorless to white monoclinic mineral that forms as an evaporite from sodium sulfate-bearing brines. It is found around saline springs and along saline playa lakes. Associated minerals include gypsum, halite, thenardite, trona, glauberite, and epsomite. Mirabilite is unstable and quickly dehydrates in dry air, the prismatic crystals turning into a white powder, thenardite (Na2SO4). In turn, thenardite can also absorb water and converts to mirabilite. Mirabilite is used as a purgative and anti-inflammatory remedy in the Traditional Chinese medicine; in Mandarin, it is called máng xiāo. The name 'mirabilite' is based on the phrase ''"Sal mirabilis"'' (Latin for "wonderful salt") used by Johann Rudolph Glauber when he inadvertently synthesized mirabilite. Mirabilite is found in several areas within the Mammoth Cave system, where it appears t ...
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Sulfate Mineral
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 **Anglesite PbSO4 ** Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O ** Kieserite MgSO4·H2O ** Starkeyite MgSO4·4H2O ** Hexahydrite MgSO4·6H2O ** Epsomite MgSO4·7H2O ** Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O ** Antlerite Cu3SO4(OH)4 **Brochantit ...
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Glauber's Salt
Sodium sulfate (also known as sodium sulphate or sulfate of soda) is the inorganic compound with formula Na2SO4 as well as several related hydrates. All forms are white solids that are highly soluble in water. With an annual production of 6 million tonnes, the decahydrate is a major commodity chemical product. It is mainly used as a filler in the manufacture of powdered home laundry detergents and in the Kraft process of paper pulping for making highly alkaline sulfides. Forms *Anhydrous sodium sulfate, known as the rare mineral thenardite, used as a drying agent in organic synthesis. *Heptahydrate sodium sulfate, a very rare form. *Decahydrate sodium sulfate, known as the mineral mirabilite, widely used by chemical industry. It is also known as Glauber's salt. History The decahydrate of sodium sulfate is known as Glauber's salt after the Dutch/German chemist and apothecary Johann Rudolf Glauber (1604–1670), who discovered it in Austrian spring water in 1625. He named it (m ...
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Fumarole
A fumarole (or fumerole) is a vent in the surface of the Earth or other rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcanic activity, but fumarole activity can also precede a volcanic eruption and has been used for eruption prediction. Most fumaroles die down within a few days or weeks of the end of an eruption, but a few are persistent, lasting for decades or longer. An area containing fumaroles is known as a fumarole field. The predominant vapor emitted by fumaroles is steam, formed by the circulation of groundwater through heated rock. This is typically accompanied by volcanic gases given off by magma cooling deep below the surface. These volcanic gases include sulfur compounds, such as various sulfur oxides and hydrogen sulfide, and sometimes hydrogen chloride, hydrogen fluoride, and other gases. A fumarole that emits significant sulfur compounds is som ...
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Solubility
In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubility of a substance in a specific solvent is generally measured as the concentration of the solute in a saturated solution, one in which no more solute can be dissolved. At this point, the two substances are said to be at the solubility equilibrium. For some solutes and solvents, there may be no such limit, in which case the two substances are said to be " miscible in all proportions" (or just "miscible"). The solute can be a solid, a liquid, or a gas, while the solvent is usually solid or liquid. Both may be pure substances, or may themselves be solutions. Gases are always miscible in all proportions, except in very extreme situations,J. de Swaan Arons and G. A. M. Diepen (1966): "Gas—Gas Equilibria". ''Journal of Chemical Physics' ...
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Sassolite
Sassolite is a borate mineral, specifically the mineral form of boric acid. It is usually white to gray, and colourless in transmitted light. It can also take on a yellow colour from sulfur impurities, or brown from iron oxides. History and occurrence Its mineral form was first described in 1800, and was named after Sasso Pisano, Castelnuovo Val di Cecina, Pisa Province, Tuscany, Italy where it was found. The mineral may be found in lagoons throughout Tuscany and Sasso. It is also found in the Lipari Islands and the US state of Nevada. It occurs in volcanic fumaroles and hot springs, deposited from steam, as well as in bedded sedimentary evaporite deposits. See also * List of minerals * Borax Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form ... References External links ...
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Gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. Alabaster, a fine-grained white or lightly tinted variety of gypsum, has been used for sculpture by many cultures including Ancient Egypt, Mesopotamia, Ancient Rome, the Byzantine Empire, and the Nottingham alabasters of Medieval England. Gypsum also crystallizes as translucent crystals of selenite. It forms as an evaporite mineral and as a hydration product of anhydrite. The Mohs scale of mineral hardness defines gypsum as hardness value 2 based on scratch hardness comparison. Etymology and history The word '' gypsum'' is derived from the Greek word (), "plaster". Because the quarries of the Montmartre district of Paris have long furnished burnt gypsum ( calcined gypsum) used for various purposes, this dehydrated gypsum be ...
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Anhydrite
Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium ( celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The Mohs hardness is 3.5, and the specific gravity is 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is glassy. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to around under normal atmospheric conditions. Anhydrite is common ...
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Polyhalite
Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: . Polyhalite crystallizes in the triclinic system, although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it may be brick red due to iron oxide inclusions. It has a Mohs hardness of 3.5 and a specific gravity of 2.8. It occurs in sedimentary marine evaporites and is a major potassium ore mineral in the Carlsbad deposits of New Mexico. It is also present as a 2–3% contaminant of Himalayan salt. Polyhalite was first described in 1818 for specimens from its type locality in Salzburg, Austria. The name comes from the German ''Polyhalit'', which comes from the Ancient Greek words (''polys'') and ' (''hals''), which mean "many" and "salt", and the German ending ''-it'' (which comes from the Latin ending -ites, which originally also came from Greek), which is used like the English ending ''-ite'' to form the ...
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