Ginibre Inequality
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Ginibre Inequality
In statistical mechanics, the Griffiths inequality, sometimes also called Griffiths–Kelly–Sherman inequality or GKS inequality, named after Robert B. Griffiths, is a correlation inequality for ferromagnetic spin systems. Informally, it says that in ferromagnetic spin systems, if the 'a-priori distribution' of the spin is invariant under spin flipping, the correlation of any monomial of the spins is non-negative; and the two point correlation of two monomial of the spins is non-negative. The inequality was proved by Griffiths for Ising ferromagnets with two-body interactions, then generalised by Kelly and Sherman to interactions involving an arbitrary number of spins, and then by Griffiths to systems with arbitrary spins. A more general formulation was given by Ginibre, and is now called the Ginibre inequality. Definitions Let \textstyle \sigma=\_ be a configuration of (continuous or discrete) spins on a lattice ''Λ''. If ''A'' ⊂ ''Λ'' is a list of lattice sites, ...
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Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ...
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Haar Measure
In mathematical analysis, the Haar measure assigns an "invariant volume" to subsets of locally compact topological groups, consequently defining an integral for functions on those groups. This measure was introduced by Alfréd Haar in 1933, though its special case for Lie groups had been introduced by Adolf Hurwitz in 1897 under the name "invariant integral". Haar measures are used in many parts of analysis, number theory, group theory, representation theory, statistics, probability theory, and ergodic theory. Preliminaries Let (G, \cdot) be a locally compact Hausdorff topological group. The \sigma-algebra generated by all open subsets of G is called the Borel algebra. An element of the Borel algebra is called a Borel set. If g is an element of G and S is a subset of G, then we define the left and right translates of S by ''g'' as follows: * Left translate: g S = \. * Right translate: S g = \. Left and right translates map Borel sets onto Borel sets. A measure \mu on th ...
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Coulomb Gas
In statistical physics, a Coulomb gas is a many-body system of charged particles interacting under the electrostatic force. It is named after Charles-Augustin de Coulomb, as the force by which the particles interact is also known as the Coulomb force. The system can be defined in any number of dimensions. While the three-dimensional Coulomb gas is the most experimentally realistic, the best understood is the two-dimensional Coulomb gas. The two-dimensional Coulomb gas is known to be equivalent to the continuum XY model of magnets and the sine-Gordon model (upon taking certain limits) in a physical sense, in that physical observables (correlation functions) calculated in one model can be used to calculate physical observables in another model. This aided the understanding of the BKT transition, and the discoverers earned a Nobel prize in physics for their work on this phase transition. Formulation The setup starts with considering N charged particles in \mathbb^d with positions \ ...
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Ising Model
The Ising model () (or Lenz-Ising model or Ising-Lenz model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent magnetic dipole moments of atomic "spins" that can be in one of two states (+1 or −1). The spins are arranged in a graph, usually a lattice (where the local structure repeats periodically in all directions), allowing each spin to interact with its neighbors. Neighboring spins that agree have a lower energy than those that disagree; the system tends to the lowest energy but heat disturbs this tendency, thus creating the possibility of different structural phases. The model allows the identification of phase transitions as a simplified model of reality. The two-dimensional square-lattice Ising model is one of the simplest statistical models to show a phase transition. The Ising model was invented by the physicist , who gave it as a prob ...
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Classical XY Model
The classical XY model (sometimes also called classical rotor (rotator) model or O(2) model) is a lattice model of statistical mechanics. In general, the XY model can be seen as a specialization of Stanley's ''n''-vector model for . Definition Given a -dimensional lattice , per each lattice site there is a two-dimensional, unit-length vector The ''spin configuration'', is an assignment of the angle for each . Given a ''translation-invariant'' interaction and a point dependent external field \mathbf_=(h_j,0), the ''configuration energy'' is : H(\mathbf) = - \sum_ J_\; \mathbf_i\cdot\mathbf_j -\sum_j \mathbf_j\cdot \mathbf_j =- \sum_ J_\; \cos(\theta_i-\theta_j) -\sum_j h_j\cos\theta_j The case in which except for nearest neighbor is called ''nearest neighbor'' case. The ''configuration probability'' is given by the Boltzmann distribution with inverse temperature : :P(\mathbf)=\frac \qquad Z=\int_ \prod_ d\theta_j\;e^. where is the normalization, or partition fun ...
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Thermodynamic Free Energy
The thermodynamic free energy is a concept useful in the thermodynamics of chemical or thermal processes in engineering and science. The change in the free energy is the maximum amount of work that a thermodynamic system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point. Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is a thermodynamic state function, like the internal energy, enthalpy, and entropy. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, ''i.e.'', work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. Since first-law energy is always conserved, it is evident that free energy ...
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Thermodynamic Limit
In statistical mechanics, the thermodynamic limit or macroscopic limit, of a system is the limit for a large number of particles (e.g., atoms or molecules) where the volume is taken to grow in proportion with the number of particles.S.J. Blundell and K.M. Blundell, "Concepts in Thermal Physics", Oxford University Press (2009) The thermodynamic limit is defined as the limit of a system with a large volume, with the particle density held fixed. : N \to \infty,\, V \to \infty,\, \frac N V =\text In this limit, macroscopic thermodynamics is valid. There, thermal fluctuations in global quantities are negligible, and all thermodynamic quantities, such as pressure and energy, are simply functions of the thermodynamic variables, such as temperature and density. For example, for a large volume of gas, the fluctuations of the total internal energy are negligible and can be ignored, and the average internal energy can be predicted from knowledge of the pressure and temperature of the gas. ...
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FKG Inequality
In mathematics, the Fortuin–Kasteleyn–Ginibre (FKG) inequality is a correlation inequality, a fundamental tool in statistical mechanics and probabilistic combinatorics (especially random graphs and the probabilistic method), due to . Informally, it says that in many random systems, increasing events are positively correlated, while an increasing and a decreasing event are negatively correlated. It was obtained by studying the random cluster model. An earlier version, for the special case of i.i.d. variables, called Harris inequality, is due to , see below. One generalization of the FKG inequality is the Holley inequality (1974) below, and an even further generalization is the Ahlswede–Daykin "four functions" theorem (1978). Furthermore, it has the same conclusion as the Griffiths inequalities, but the hypotheses are different. The inequality Let X be a finite distributive lattice, and ''μ'' a nonnegative function on it, that is assumed to satisfy the (FKG) lattice condit ...
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Chebyshev's Sum Inequality
In mathematics, Chebyshev's sum inequality, named after Pafnuty Chebyshev, states that if :a_1 \geq a_2 \geq \cdots \geq a_n \quad and \quad b_1 \geq b_2 \geq \cdots \geq b_n, then : \sum_^n a_k b_k \geq \left(\sum_^n a_k\right)\!\!\left(\sum_^n b_k\right)\!. Similarly, if :a_1 \leq a_2 \leq \cdots \leq a_n \quad and \quad b_1 \geq b_2 \geq \cdots \geq b_n, then : \sum_^n a_k b_k \leq \left(\sum_^n a_k\right)\!\!\left(\sum_^n b_k\right)\!. Proof Consider the sum :S = \sum_^n \sum_^n (a_j - a_k) (b_j - b_k). The two sequences are non-increasing, therefore and have the same sign for any . Hence . Opening the brackets, we deduce: :0 \leq 2 n \sum_^n a_j b_j - 2 \sum_^n a_j \, \sum_^n b_j, hence :\frac \sum_^n a_j b_j \geq \left( \frac \sum_^n a_j\right)\!\!\left(\frac \sum_^n b_j\right)\!. An alternative proof is simply obtained with the rearrangement inequality, writing that :\sum_^ a_i \sum_^ b_j = \sum_^ \sum_^ a_i b_j =\sum_^\sum_^ a_i b_ = \sum_^ \sum_^ a_i b_ \leq \s ...
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Totally Ordered Set
In mathematics, a total or linear order is a partial order in which any two elements are comparable. That is, a total order is a binary relation \leq on some set X, which satisfies the following for all a, b and c in X: # a \leq a ( reflexive). # If a \leq b and b \leq c then a \leq c ( transitive). # If a \leq b and b \leq a then a = b ( antisymmetric). # a \leq b or b \leq a (strongly connected, formerly called total). Total orders are sometimes also called simple, connex, or full orders. A set equipped with a total order is a totally ordered set; the terms simply ordered set, linearly ordered set, and loset are also used. The term ''chain'' is sometimes defined as a synonym of ''totally ordered set'', but refers generally to some sort of totally ordered subsets of a given partially ordered set. An extension of a given partial order to a total order is called a linear extension of that partial order. Strict and non-strict total orders A on a set X is a strict partial ord ...
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Positive-definite Function
In mathematics, a positive-definite function is, depending on the context, either of two types of function. Most common usage A ''positive-definite function'' of a real variable ''x'' is a complex-valued function f: \mathbb \to \mathbb such that for any real numbers ''x''1, …, ''x''''n'' the ''n'' × ''n'' matrix : A = \left(a_\right)_^n~, \quad a_ = f(x_i - x_j) is positive ''semi-''definite (which requires ''A'' to be Hermitian; therefore ''f''(−''x'') is the complex conjugate of ''f''(''x'')). In particular, it is necessary (but not sufficient) that : f(0) \geq 0~, \quad , f(x), \leq f(0) (these inequalities follow from the condition for ''n'' = 1, 2.) A function is ''negative semi-definite'' if the inequality is reversed. A function is ''definite'' if the weak inequality is replaced with a strong ( 0). Examples If (X, \langle \cdot, \cdot \rangle) is a real inner product space, then g_y \colon X \to \mathbb, x \mapsto \exp(i \langle y, x \rangle ...
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Compact Group
In mathematics, a compact (topological) group is a topological group whose topology realizes it as a compact topological space (when an element of the group is operated on, the result is also within the group). Compact groups are a natural generalization of finite groups with the discrete topology and have properties that carry over in significant fashion. Compact groups have a well-understood theory, in relation to group actions and representation theory. In the following we will assume all groups are Hausdorff spaces. Compact Lie groups Lie groups form a class of topological groups, and the compact Lie groups have a particularly well-developed theory. Basic examples of compact Lie groups include * the circle group T and the torus groups T''n'', * the orthogonal group O(''n''), the special orthogonal group SO(''n'') and its covering spin group Spin(''n''), * the unitary group U(''n'') and the special unitary group SU(''n''), * the compact forms of the exceptional Lie gr ...
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