Glass-filled Polymer
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Glass-filled Polymer
Glass-filled polymer (or glass-filled plastic), is a mouldable composite material. It comprises short glass fibers in a matrix of a polymer material. It is used to manufacture a wide range of structural components by injection or compression moulding. It is an ideal glass alternative that offers design flexibility, chemical, durability, and chemical and shatter resistance. Materials Either thermoplastic or thermosetting polymers may be used. One of the most widely used thermoplastics is a polyamide polymer nylon. The first mouldable composite was Bakelite. This used wood flour fibres in phenolic resin as the thermoset polymer matrix. As the fibres were only short this material had relatively low bulk strength, but still improved surface hardness and good mouldability. A wide range of polymers are now produced in glass-filled varieties, including polyamide (Nylon), acetal homopolymers and copolymers, polyester, polyphenylene oxide (PPO / Noryl), polycarbonate, polyethersulp ...
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Composite Material
A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a material with properties unlike the individual elements. Within the finished structure, the individual elements remain separate and distinct, distinguishing composites from mixtures and solid solutions. Typical engineered composite materials include: *Reinforced concrete and masonry *Composite wood such as plywood *Reinforced plastics, such as fibre-reinforced polymer or fiberglass *Ceramic matrix composites ( composite ceramic and metal matrices) *Metal matrix composites *and other advanced composite materials There are various reasons where new material can be favoured. Typical examples include materials which are less expensive, lighter, stronger or more durable when compared with commo ...
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Copolymer
In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are sometimes called ''bipolymers''. Those obtained from three and four monomers are called ''terpolymers'' and ''quaterpolymers'', respectively. Copolymers can be characterized by a variety of techniques such as NMR spectroscopy and size-exclusion chromatography to determine the molecular size, weight, properties, and composition of the material. Commercial copolymers include acrylonitrile butadiene styrene (ABS), styrene/butadiene co-polymer (SBR), nitrile rubber, styrene-acrylonitrile, styrene-isoprene-styrene (SIS) and ethylene-vinyl acetate, all of which are formed by chain-growth polymerization. Another production mechanism is step-growth polymerization, which is used to produce the nylon-12/6/66 copolymer of nylon 12, nylon 6 and nylon ...
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Composite Materials
A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a material with properties unlike the individual elements. Within the finished structure, the individual elements remain separate and distinct, distinguishing composites from mixtures and solid solutions. Typical engineered composite materials include: * Reinforced concrete and masonry *Composite wood such as plywood *Reinforced plastics, such as fibre-reinforced polymer or fiberglass *Ceramic matrix composites ( composite ceramic and metal matrices) *Metal matrix composites *and other advanced composite materials There are various reasons where new material can be favoured. Typical examples include materials which are less expensive, lighter, stronger or more durable when compared with com ...
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Fibre-reinforced Plastic
Fibre-reinforced plastic (FRP; also called fibre-reinforced polymer, or in American English ''fiber'') is a composite material made of a polymer matrix reinforced with fibres. The fibres are usually glass (in fibreglass), carbon (in carbon-fibre-reinforced polymer), aramid, or basalt. Rarely, other fibres such as paper, wood, or asbestos have been used. The polymer is usually an epoxy, vinyl ester, or polyester thermosetting plastic, though phenol formaldehyde resins are still in use. FRPs are commonly used in the aerospace, automotive, marine, and construction industries. They are commonly found in ballistic armour and cylinders for self-contained breathing apparatuses. Process definition A polymer is generally manufactured by step-growth polymerization or addition polymerization. When combined with various agents to enhance or in any way alter the material properties of polymers, the result is referred to as a plastic. Composite plastics refers to those types of plastic ...
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Fibreglass
Fiberglass (American English) or fibreglass (Commonwealth English) is a common type of fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth. The plastic matrix may be a thermoset polymer matrix—most often based on thermosetting polymers such as epoxy, polyester resin, or vinyl ester resin—or a thermoplastic. Cheaper and more flexible than carbon fiber, it is stronger than many metals by weight, non-magnetic, non-conductive, transparent to electromagnetic radiation, can be molded into complex shapes, and is chemically inert under many circumstances. Applications include aircraft, boats, automobiles, bath tubs and enclosures, swimming pools, hot tubs, septic tanks, water tanks, roofing, pipes, cladding, orthopedic casts, surfboards, and external door skins. Other common names for fiberglass are glass-reinforced plastic (GRP), glass-fiber reinforced plastic (GFRP) or ...
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Surface Hardness
In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard metals such as titanium and beryllium are harder than soft metals such as sodium and metallic tin, or wood and common plastics. Macroscopic hardness is generally characterized by strong intermolecular bonds, but the behavior of solid materials under force is complex; therefore, hardness can be measured in different ways, such as scratch hardness, indentation hardness, and rebound hardness. Hardness is dependent on ductility, elastic stiffness, plasticity, strain, strength, toughness, viscoelasticity, and viscosity. Common examples of hard matter are ceramics, concrete, certain metals, and superhard materials, which can be contrasted with soft matter. Measuring hardness There are three main types of hardness measurements: ''scratch'', ...
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Shear Strength
In engineering, shear strength is the strength of a material or component against the type of yield or structural failure when the material or component fails in shear. A shear load is a force that tends to produce a sliding failure on a material along a plane that is parallel to the direction of the force. When a paper is cut with scissors, the paper fails in shear. In structural and mechanical engineering, the shear strength of a component is important for designing the dimensions and materials to be used for the manufacture or construction of the component (e.g. beams, plates, or bolts). In a reinforced concrete beam, the main purpose of reinforcing bar (rebar) stirrups is to increase the shear strength. Equations For shear stress \tau applies :\tau = \frac , where :\sigma_1 is major principal stress and :\sigma_3 is minor principal stress. In general: ductile materials (e.g. aluminum) fail in shear, whereas brittle materials (e.g. cast iron) fail in tension. See ...
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Stiffness
Stiffness is the extent to which an object resists deformation in response to an applied force. The complementary concept is flexibility or pliability: the more flexible an object is, the less stiff it is. Calculations The stiffness, k, of a body is a measure of the resistance offered by an elastic body to deformation. For an elastic body with a single degree of freedom (DOF) (for example, stretching or compression of a rod), the stiffness is defined as k = \frac where, * F is the force on the body * \delta is the displacement produced by the force along the same degree of freedom (for instance, the change in length of a stretched spring) In the International System of Units, stiffness is typically measured in newtons per meter (N/m). In Imperial units, stiffness is typically measured in pounds (lbs) per inch. Generally speaking, deflections (or motions) of an infinitesimal element (which is viewed as a point) in an elastic body can occur along multiple DOF (maximum of s ...
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Bulk Moulding Compound
Bulk moulding compound (BMC), bulk moulding composite, or dough moulding compound (DMC), is a ready-to-mold, glass-fiber reinforced thermoset polymer material primarily used in compression moulding, as well as in injection moulding and transfer moulding. Typical applications include demanding electrical applications, corrosion resistant needs, appliance, automotive, and transit. Manufacturing BMC is manufactured by mixing strands (Greater than 1/8” and less than 2") of chopped glass fibers, styrene, an initiator, and filler in a mixer with an unsaturated thermoset resin (commonly polyester resin, vinyl ester resin or epoxy resin). The mixing is done at room temperature and stored at low temperatures to slow down curing prior to molding. The concentration of the mixture can vary depending on application, but is typically 30% glass fibers, 25% filler, and 45% resin, styrene, and initiator. The material is provided in bulk or in logs approximately 4" in diameter. The glass fiber ...
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Polyethersulphone
Polysulfones are a family of high performance thermoplastics. These polymers are known for their toughness and stability at high temperatures. Technically used polysulfones contain an aryl- SO2-aryl subunit. Due to the high cost of raw materials and processing, polysulfones are used in specialty applications and often are a superior replacement for polycarbonates. Three polysulfones are used industrially: polysulfone (PSU), polyethersulfone (PES/PESU) and polyphenylene sulfone (PPSU). They can be used in the temperature range from -100 to +200 °C and are used for electrical equipment, in vehicle construction and medical technology. They are composed of para-linked aromatics, sulfonyl groups and ether groups and partly also alkyl groups. Polysulfones have outstanding resistance to heat and oxidation, hydrolysis resistance to aqueous and alkaline media and good electrical properties. Nomenclature The term "polysulfone" is normally used for polyarylethersulfones (PAES), si ...
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Polycarbonate
Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code (RIC) and are identified as "Other", 7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A (BPA). Structure Carbonate esters have planar OC(OC)2 cores, which confers rigidity. The unique O=C bond is short (1.173 Å in the depicted example), while the C-O bonds are more ether-like (the bond distances of 1.326 Å for the example depicted). Polycarbonates received their name because they are polymers containing carbonate groups (−O−(C=O)−O−). A balance of useful features, including temperature resistance, impact resistance and o ...
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Noryl
The NORYL family of modified resins consists of amorphous blends of polyphenylene oxides (PPO) or polyphenylene ether (PPE) resins with polystyrene. They combine the inherent benefits of PPE resin (affordable high heat resistance, good electrical insulation properties, excellent hydrolytic stability and the ability to use non-halogen fire retardant packages), with excellent dimensional stability, good processability and low density. They were originally developed in 1966 by General Electric Plastics (now owned by SABIC). NORYL is a registered trademark of SABIC Innovative Plastics IP B.V. NORYL resins are a rare example of a homogeneous mixture of two polymers. Most polymers are incompatible with one another, so tend to produce separate phases when mixed. The two polymers compatibility in NORYL resins is due to the presence of a benzene ring in the repeat units of both chains. Properties The addition of polystyrene to PPE increases the glass transition temperature above 100 ...
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