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Girdler Sulfide Process
The Girdler sulfide (GS) process, also known as the GeibSpevack (GS) process, is an industrial production method for filtering out of natural water the heavy water (deuterium oxide = D2O) which is used in particle research, in deuterium NMR spectroscopy, deuterated solvents for proton NMR spectroscopy, in heavy water nuclear reactors (as a coolant and moderator) and in deuterated drugs. Karl-Hermann Geib and Jerome S. Spevack independently, and in parallel, invented the process in 1943 and its name derives from the Girdler company, which built the first American plant using the process. The method is an isotopic exchange process between H2S and H2O ("light" water), that produces heavy water over several steps. It is a highly energy intensive process. Until its closure in 1997, the Bruce Heavy Water Plant in Ontario (located on the same site as Douglas Point and the Bruce Nuclear Generating Station) was the world's largest heavy water production plant, with a peak capa ...
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Girdler
Girdler is a surname of professional origin. Girdlers or belt makers were people who made metal belts worn around the waist and other small metal objects. It may refer to: People with the surname Girdler * Chris Girdler, American politician in Kentucky *Eddie Girdler, American politician and mayor of Somerset, Kentucky *Nick Girdler, freelance radio broadcaster who worked for BBC Radio Solent for 35 years from 1972 to 2006 * Rick Girdler, American politician in Kentucky *Ryan Girdler (born 1972), Australian former rugby league footballer of the 1990s and 2000s *William Girdler (1947–1978), American filmmaker People with the given name Girdler *George Girdler Smith, American engraver in 19th-century Boston Other uses * Girdler, Kentucky * Girdler Island See also *Girdler sulfide process, industrial production method for making heavy water (deuterium oxide) *Worshipful Company of Girdlers The Worshipful Company of Girdlers is one of the Livery Companies of the City of Lo ...
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Bruce Nuclear Generating Station
Bruce Nuclear Generating Station is a nuclear power station located on the eastern shore of Lake Huron in Ontario, Canada. It occupies 932 ha (2300 acres) of land. The facility derives its name from Bruce Township, the local municipality when the plant was constructed, now Kincardine due to amalgamation. With eight CANDU pressurized heavy-water reactors, it was the world's largest fully operational nuclear generating station by total reactor count and the number of currently operational reactors until 2016, when it was exceeded in nameplate capacity by South Korea's Kori Nuclear Power Plant. The station is the largest employer in Bruce County, with over 4000 workers. Formerly known as the Bruce Nuclear Power Development (BNPD), the facility was constructed in stages between 1970 and 1987 by the provincial Crown corporation, Ontario Hydro. In April 1999 Ontario Hydro was split into 5 component Crown corporations with Ontario Power Generation (OPG) taking over all electrical ge ...
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Name Reactions
A name reaction is a chemical reaction named after its discoverers or developers. Among the tens of thousands of organic reactions that are known, hundreds of such reactions are well-known enough to be named after people. Well-known examples include the Grignard reaction, the Sabatier reaction, the Wittig reaction, the Claisen condensation, the Friedel-Crafts acylation, and the Diels-Alder reaction. Books have been published devoted exclusively to name reactions;Alfred Hassner, C. Stumer. ''Organic syntheses based on name reactions''. Elsevier, 2002. Li, Jie Jack. ''Name Reactions: A Collection of Detailed Reaction Mechanisms''. Springer, 2003. the Merck Index, a chemical encyclopedia, also includes an appendix on name reactions. As organic chemistry developed during the 20th century, chemists started associating synthetically useful reactions with the names of the discoverers or developers; in many cases, the name is merely a mnemonic. Some cases of reactions that were not reall ...
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Isotope Separation
Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is varied. The largest variety is used in research (e.g. in chemistry where atoms of "marker" nuclide are used to figure out reaction mechanisms). By tonnage, separating natural uranium into enriched uranium and depleted uranium is the largest application. In the following text, mainly the uranium enrichment is considered. This process is crucial in the manufacture of uranium fuel for nuclear power plants, and is also required for the creation of uranium-based nuclear weapons. Plutonium-based weapons use plutonium produced in a nuclear reactor, which must be operated in such a way as to produce plutonium already of suitable isotopic mix or ''grade''. While different chemical elements can be purified through chemical reaction, chemical processes, isotopes of the same element have nearly identical chemical properties, which makes this ...
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Industrial Processes
Industrial processes are procedures involving chemical, physical, electrical or mechanical steps to aid in the manufacturing of an item or items, usually carried out on a very large scale. Industrial processes are the key components of heavy industry. Chemical processes by main basic material Certain chemical process yield important basic materials for society, e.g., (cement, steel, aluminum, and fertilizer). However, these chemical reactions contribute to climate change by emitting carbon dioxide, a greenhouse gas, through chemical reactions, as well as through the combustion of fossil fuels to generate the high temperatures needed to reach the activation energies of the chemical reactions. Cement (the paste within concrete) * Calcination – Limestone, which is largely composed of fossilized calcium carbonate (CaCO3), breaks down at high temperatures into useable calcium oxide (CaO) and carbon dioxide gas (), which gets released as a by-product. This chemical reaction, call ...
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Distillation
Distillation, or classical distillation, is the process of separation process, separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heating of solid materials to produce gaseous products (which may condense into liquids or solids); this may involve chemical changes such as destructive distillation or Cracking (chemistry), cracking. Distillation may result in essentially complete separation (resulting in nearly pure components), or it may be a partial separation that increases the concentration of selected components; in either case, the process exploits differences in the relative volatility of the mixture's components. In Chemical industry, industrial applications, distillation is a unit operation of practically universal importance, but is a physical separation process, not a chemical reaction. An installation used for distillation, especially of distilled ...
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Cascade (chemical Engineering)
In chemical engineering, a cascade is a plant consisting of several similar stages with each processing the output from the previous stage. Cascades are most commonly used in isotope separation, distillation, flotation and other separation or purification processes. Cascade process Cascade process is any process that takes place in a number of steps, usually because the single step is too inefficient to produce the desired result. For example, in some uranium-enrichment processes the separation of the desired isotope is only poorly achieved in a single stage; to achieve better separation the process has to be repeated a number of times, in a series, with the enriched fraction of one stage being fed to the succeeding stage for further enrichment. Another example of cascade process is that operating in a cascade liquefier.oxford dictionary of science, 4th edition, 1999. Examples If a still A still is an apparatus used to distill liquid mixtures by heating to selectively ...
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Degasification
Degassing, also known as degasification, is the removal of dissolved gases from liquids, especially water or aqueous solutions. There are numerous methods for removing gases from liquids. Gases are removed for various reasons. Chemists remove gases from solvents when the compounds they are working on are possibly air- or oxygen-sensitive (air-free technique), or when bubble formation at solid-liquid interfaces becomes a problem. The formation of gas bubbles when a liquid is frozen can also be undesirable, necessitating degassing beforehand. Pressure reduction The solubility of gas obeys Henry's law, that is, the amount of a dissolved gas in a liquid is proportional to its partial pressure. Therefore, placing a solution under reduced pressure makes the dissolved gas less soluble. Sonication and stirring under reduced pressure can usually enhance the efficiency. This technique is often referred to as ''vacuum degasification''. Specialized vacuum chambers, called vacuum degassers, ar ...
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Water Purification
Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for human consumption (drinking water), but water purification may also be carried out for a variety of other purposes, including medical, pharmacological, chemical, and industrial applications. The history of water purification includes a wide variety of methods. The methods used include physical processes such as filtration, sedimentation, and distillation; biological processes such as slow sand filters or biologically active carbon; chemical processes such as flocculation and chlorination; and the use of electromagnetic radiation such as ultraviolet light. Water purification can reduce the concentration of particulate matter including suspended particles, parasites, bacteria, algae, viruses, and fungi as well as reduce the concentration of ...
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CANDU
The CANDU (Canada Deuterium Uranium) is a Canadian pressurized heavy-water reactor design used to generate electric power. The acronym refers to its deuterium oxide ( heavy water) moderator and its use of (originally, natural) uranium fuel. CANDU reactors were first developed in the late 1950s and 1960s by a partnership between Atomic Energy of Canada Limited (AECL), the Hydro-Electric Power Commission of Ontario, Canadian General Electric, and other companies. There have been two major types of CANDU reactors, the original design of around 500  MWe that was intended to be used in multi-reactor installations in large plants, and the rationalized CANDU 6 in the 600 MWe class that is designed to be used in single stand-alone units or in small multi-unit plants. CANDU 6 units were built in Quebec and New Brunswick, as well as Pakistan, Argentina, South Korea, Romania, and China. A single example of a non-CANDU 6 design was sold to India. The multi-unit design was used o ...
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IPHWR
The IPHWR (Indian Pressurized Heavy Water Reactor) is a class of Indian pressurized heavy-water reactors designed by the Bhabha Atomic Research Centre. The baseline 220 MWe design was developed from the CANDU based RAPS-1 and RAPS-2 reactors built at Rawatbhata, Rajasthan. The design was later expanded into 540 MW and 700 MW designs. Currently there are 17 units of various types operational at various locations in India. IPHWR-220 The first PHWR units built in India (RAPS-1 and RAPS-2) are of Canadian CANDU design similar to the first full-scale Canadian reactor built at Douglas point, Ontario. The reactors were set up in collaboration with Government of Canada. Starting in 1963, 100 MWe RAPS-1 was mostly built with equipment and technology supplied by AECL, Canada. RAPS-1 was commissioned in 1973 but the cessation of Canadian cooperation in light of successful development of nuclear weapons by India as part of Operation Smiling Buddha the RAPS-2 commissioning c ...
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