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Gay-Lussac's Law
Gay-Lussac's law usually refers to Joseph-Louis Gay-Lussac's law of combining volumes of gases, discovered in 1808 and published in 1809. It sometimes refers to the proportionality of the volume of a gas to its absolute temperature at constant pressure. This law was published by Gay-Lussac in 1802, and in the article in which he described his work he cited earlier unpublished work from the 1780s by Jacques Charles. Consequently, the volume-temperature proportionality is usually known as Charles's Law. Law of combining volumes The law of combining volumes states that, when gases react together they do so in volume which bears simple whole number ratio provided that the temperature and pressure of the reacting gases and their products remain constant The ratio between the volumes of the reactant gases and the gaseous products can be expressed in simple whole numbers. For example, Gay-Lussac found that two volumes of hydrogen and one volume of oxygen would react to form two vo ...
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Joseph-Louis Gay-Lussac
Joseph Louis Gay-Lussac (, , ; 6 December 1778 – 9 May 1850) was a French chemist and physicist. He is known mostly for his discovery that water is made of two parts hydrogen and one part oxygen (with Alexander von Humboldt), for two laws related to gases, and for his work on alcohol–water mixtures, which led to the degrees Gay-Lussac used to measure alcoholic beverages in many countries. Biography Gay-Lussac was born at Saint-Léonard-de-Noblat in the present-day department of Haute-Vienne. The father of Joseph Louis Gay, Anthony Gay, son of a doctor, was a lawyer and prosecutor and worked as a judge in Noblat Bridge. Father of two sons and three daughters, he owned much of the Lussac village and usually added the name of this hamlet of the Haute-Vienne to his name, following a custom of the Ancien Régime. Towards the year 1803, father and son finally adopted the name Gay-Lussac. During the Revolution, on behalf of the Law of Suspects, his father, former king's att ...
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Guillaume Amontons
Guillaume Amontons (31 August 1663 – 11 October 1705) was a French scientific instrument inventor and physicist. He was one of the pioneers in studying the problem of friction, which is the resistance to motion when bodies make contact. He is also known for his work on thermodynamics, the concept of absolute zero, and early engine design. Life Guillaume was born in Paris, France. His father was a lawyer from Normandy who had moved to the French capital. While still young, Guillaume lost his hearing and became mostly deaf. According to one biographer, Fontenelle, while studying perpetual motion, he became convinced of the importance of studying machines from a mathematical perspective. He never attended a university, but was able to study mathematics, the physical sciences, and celestial mechanics. He also spent time studying the skills of drawing, surveying, and architecture. He died in Paris, France. Work He was supported in his research career by the government, and was e ...
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Gas Laws
The gas laws were developed at the end of the 18th century, when scientists began to realize that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases. Boyle's law In 1662 Robert Boyle studied the relationship between volume and pressure of a gas of fixed amount at constant temperature. He observed that volume of a given mass of a gas is inversely proportional to its pressure at a constant temperature. Boyle's law, published in 1662, states that, at constant temperature, the product of the pressure and volume of a given mass of an ideal gas in a closed system is always constant. It can be verified experimentally using a pressure gauge and a variable volume container. It can also be derived from the kinetic theory of gases: if a container, with a fixed number of molecules inside, is reduced in volume, more molecules will strike a given area of the sides of the container per unit time, causing ...
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Absolute Zero
Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical, zero-point energy-induced particle motion. The theoretical temperature is determined by extrapolating the ideal gas law; by international agreement, absolute zero is taken as −273.15 degrees on the Celsius scale (International System of Units), Note: The triple point of water is 0.01 °C, not 0 °C; thus 0 K is −2890.15 °C, not −273.16 °C. which equals −459.67 degrees on the Fahrenheit scale ( United States customary units or Imperial units). The corresponding Kelvin and Rankine temperature scales set their zero points at absolute zero by definition. It is commonly thought of as the lowest temperature possible, but it is not the lowest ''enthalpy'' state poss ...
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Ideal Gas Law
The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stated by Benoît Paul Émile Clapeyron in 1834 as a combination of the empirical Boyle's law, Charles's law, Avogadro's law, and Gay-Lussac's law. The ideal gas law is often written in an empirical form: pV = nRT where p, V and T are the pressure, volume and temperature; n is the amount of substance; and R is the ideal gas constant. It can also be derived from the microscopic kinetic theory, as was achieved (apparently independently) by August Krönig in 1856 and Rudolf Clausius in 1857. Equation The state of an amount of gas is determined by its pressure, volume, and temperature. The modern form of the equation relates these simply in two main forms. The temperature used in the equation of state is an absolute temperature: the appropria ...
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Combined Gas Law
The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stated by Benoît Paul Émile Clapeyron in 1834 as a combination of the empirical Boyle's law, Charles's law, Avogadro's law, and Gay-Lussac's law. The ideal gas law is often written in an empirical form: pV = nRT where p, V and T are the pressure, volume and temperature; n is the amount of substance; and R is the ideal gas constant. It can also be derived from the microscopic kinetic theory, as was achieved (apparently independently) by August Krönig in 1856 and Rudolf Clausius in 1857. Equation The state of an amount of gas is determined by its pressure, volume, and temperature. The modern form of the equation relates these simply in two main forms. The temperature used in the equation of state is an absolute temperature: the appropriat ...
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Boyle's Law
Boyle's law, also referred to as the Boyle–Mariotte law, or Mariotte's law (especially in France), is an experimental gas law that describes the relationship between pressure and volume of a confined gas. Boyle's law has been stated as: The absolute pressure exerted by a given mass of an ideal gas is inversely proportional to the volume it occupies if the temperature and amount of gas remain unchanged within a closed system.Levine, Ira. N. (1978), p. 12 gives the original definition. Mathematically, Boyle's law can be stated as: or where is the pressure of the gas, is the volume of the gas, and is a constant. Boyle's Law states that when the temperature of a given mass of confined gas is constant, the product of its pressure and volume is also constant. When comparing the same substance under two different sets of conditions, the law can be expressed as: :P_1 V_1 = P_2 V_2. showing that as volume increases, the pressure of a gas decreases proportionally, and vic ...
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Charles's Law
Charles's law (also known as the law of volumes) is an experimental gas law that describes how gases tend to expand when heated. A modern statement of Charles's law is: When the pressure on a sample of a dry gas is held constant, the Kelvin temperature and the volume will be in direct proportion. This relationship of direct proportion can be written as: :V \propto T So this means: :\frac = k, \quad \text \quad V=k T where: * is the volume of the gas, * is the temperature of the gas (measured in kelvins), and * is a non-zero constant. This law describes how a gas expands as the temperature increases; conversely, a decrease in temperature will lead to a decrease in volume. For comparing the same substance under two different sets of conditions, the law can be written as: \frac=\frac The equation shows that, as absolute temperature increases, the volume of the gas also increases in proportion. History The law was named after scientist Jacques Charles, who formulated ...
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Karlsruhe Congress
The Karlsruhe Congress was an international meeting of chemists held in Karlsruhe, Germany from 3 to 5 September 1860. It was the first international conference of chemistry worldwide. The meeting The Karlsruhe Congress was called so that European chemists could discuss matters of chemical nomenclature, notation, and atomic weights. The organization, invitation, and sponsorship of the conference were handled by August Kekulé, Adolphe Wurtz, and Karl Weltzien. As an example of the problems facing the delegates, Kekulé's ''Lehrbuch der Organischen Chemie'' gave nineteen different formulas used by chemists for acetic acid, as shown in the figure on this page. An understanding was reached on the time and place of the meeting, and printing of a circular addressed to European chemists listed below, which explained the objectives and goals of an international congress was agreed upon. The circular concluded: "...with the aim of avoiding any unfortunate omissions, the undersigned ...
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Jacques Charles
Jacques Alexandre César Charles (November 12, 1746 – April 7, 1823) was a French inventor, scientist, mathematician, and balloonist. Charles wrote almost nothing about mathematics, and most of what has been credited to him was due to mistaking him with another Jacques Charles, also a member of the Paris Academy of Sciences, entering on May 12, 1785. He was sometimes called Charles the Geometer. Charles and the Robert brothers launched the world's first unmanned hydrogen-filled gas balloon in August 1783; then in December 1783, Charles and his co-pilot Nicolas-Louis Robert ascended to a height of about 1,800 feet (550 m) in a manned gas balloon. Their pioneering use of hydrogen for lift led to this type of balloon being named a ''Charlière'' (as opposed to a Montgolfière which used hot air). Charles's law, describing how gases tend to expand when heated, was formulated by Joseph Louis Gay-Lussac in 1802, but he credited it to unpublished work by Jacques Charles. Charles ...
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Stanislao Cannizzaro
Stanislao Cannizzaro ( , also , ; 13 July 1826 – 10 May 1910) was an Italian chemist. He is famous for the Cannizzaro reaction and for his influential role in the atomic-weight deliberations of the Karlsruhe Congress in 1860. Biography Cannizzaro was born in Palermo in 1826. He entered the university there with the intention of making medicine his profession, but he soon turned to the study of chemistry. In 1845 and 1846, he acted as assistant to Raffaele Piria (1815–1865), known for his work on salicin, and who was then professor of chemistry at Pisa and subsequently occupied the same position at Turin. During the Sicilian revolution of independence of 1848, Cannizzaro served as an artillery officer at Messina and was also chosen deputy for Francavilla in the Sicilian parliament; and, after the fall of Messina in September 1848, he was stationed at Taormina. On the collapse of the insurgents, Cannizzaro escaped to Marseille in May 1849, and, after visiting various ...
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Joseph Louis Gay-Lussac
Joseph Louis Gay-Lussac (, , ; 6 December 1778 – 9 May 1850) was a French chemist and physicist. He is known mostly for his discovery that water is made of two parts hydrogen and one part oxygen (with Alexander von Humboldt), for two laws related to gases, and for his work on alcohol–water mixtures, which led to the degrees Gay-Lussac used to measure alcoholic beverages in many countries. Biography Gay-Lussac was born at Saint-Léonard-de-Noblat in the present-day department of Haute-Vienne. The father of Joseph Louis Gay, Anthony Gay, son of a doctor, was a lawyer and prosecutor and worked as a judge in Noblat Bridge. Father of two sons and three daughters, he owned much of the Lussac village and usually added the name of this hamlet of the Haute-Vienne to his name, following a custom of the Ancien Régime. Towards the year 1803, father and son finally adopted the name Gay-Lussac. During the Revolution, on behalf of the Law of Suspects, his father, former king's atto ...
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