Gaston Charlot
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Gaston Charlot
Gaston Charlot (11 June 1904 – 17 April 1994) was a French chemist, founder of modern analytical chemistry in France. Charlot graduated from the École supérieure de physique et de chimie industrielles de la ville de Paris; he worked on the catalytic oxidation of organic substances in the gas phase. In 1945, he became professor of analytical chemistry at the École supérieure, and also lectured at the Faculté des sciences de Paris and at the Institut national des sciences et techniques nucléaires. Charlot generalized the Brønsted–Lowry theory of acid-base chemistry to complex chemistry. In 1943, he published ''Théories et méthodes nouvelles d'analyse qualitative'' (New theories and methods of qualitative analysis), which eliminated traditional methods such as hydrogen sulfide tests by replacing them with electrochemical or colorimetric tests, complex chemistry, and non-aqueous chemical reactions. After some reluctance from part of the chemistry community, the Charlot m ...
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École Supérieure De Physique Et De Chimie Industrielles De La Ville De Paris
ESPCI Paris (officially the École supérieure de physique et de chimie industrielles de la Ville de Paris; ''The City of Paris Industrial Physics and Chemistry Higher Educational Institution'') is a prestigious grande école founded in 1882 by the city of Paris, France. It educates undergraduate and graduate students in physics, chemistry and biology and conducts high-level research in those fields. It is ranked as the first French ''École d'Ingénieurs'' in the 2017 Shanghai Ranking. ESPCI Paris is a constituent college of Université PSL and a founding member of the ParisTech (Paris Institute of Technology) alliance. 5 researchers and alumni from ESPCI Paris have been awarded the Nobel Prize: * Pierre and Marie Curie (Physics, 1903), * Marie Curie - second Nobel Prize (Chemistry, 1911), * Frédéric Joliot-Curie (Chemistry, 1935), * Pierre-Gilles de Gennes (Physics, 1991), * Georges Charpak (Physics, 1992). Two thirds of the students enter the School following a competi ...
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Institut National Des Sciences Et Techniques Nucléaires
Th(National Institute for Nuclear Science and Technology), in French: ''L' Institut national des sciences et techniques nucléaires,'' is a public higher education institution administered by the CEA (French Alternative Energies and Atomic Energy Commission) under the joint authority of the Ministry of National Education, Higher Education and Research, the Ministry of the Economy, Industry and the Digital Sector and the Ministry of the Environment, Energy and Marine Affairs. It is the main center of education for nuclear energy in France. History The establishment of INSTN goes back to 1956 with the purpose to train engineers, researchers and technicians who were tasked with implementing the French civil nuclear development programme introduced in the 1950s. Since its creation, the mission of INSTN has been to support the transfer of knowledge and know-how developed by the CEA and its industrial partners in order to support the growth of the nuclear industry worldwide. One of its ...
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Brønsted–Lowry Acid–base Theory
The Brønsted–Lowry theory (also called proton theory of acids and bases) is an acid–base reaction theory which was proposed independently by Johannes Nicolaus Brønsted and Thomas Martin Lowry in 1923. The fundamental concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate base, and the base forms its conjugate acid by exchange of a proton (the hydrogen cation, or H+). This theory is a generalization of the Arrhenius theory. Definitions of acids and bases In the Arrhenius theory, acids are defined as substances that dissociate in aqueous solution to give H+ (hydrogen ions), while bases are defined as substances that dissociate in aqueous solution to give OH− (hydroxide ions). In 1923 physical chemists Johannes Nicolaus Brønsted in Denmark and Thomas Martin Lowry in England both independently proposed the theory that carries their names. In the Brønsted–Lowry theory acids and bases are defined by the way they react ...
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The underground mine gas term for foul-smelling hydrogen sulfide-rich gas mixtures is ''stinkdamp''. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, a spelling no longer recommended by the Royal Society of Chemistry or the International Union of Pure and Applied Chemistry. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or it or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the ...
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Electrochemical
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outcome of a particular chemical change, or vice versa. These reactions involve electrons moving via an electronically-conducting phase (typically an external electrical circuit, but not necessarily, as in electroless plating) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic species in a solution). When a chemical reaction is driven by an electrical potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an ''electrochemical'' reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the af ...
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Colorimetric
Colorimetry is "the science and technology used to quantify and describe physically the human color perception". It is similar to spectrophotometry, but is distinguished by its interest in reducing spectra to the physical correlates of color perception, most often the CIE 1931 XYZ color space tristimulus values and related quantities. History The Duboscq colorimeter was invented by Jules Duboscq in 1870. Instruments Colorimetric equipment is similar to that used in spectrophotometry. Some related equipment is also mentioned for completeness. * A tristimulus colorimeter measures the tristimulus values of a color. * A spectroradiometer measures the absolute spectral radiance (intensity) or irradiance of a light source. * A spectrophotometer measures the spectral reflectance, transmittance, or relative irradiance of a color sample. * A ''spectrocolorimeter'' is a spectrophotometer that can ''calculate'' tristimulus values. * A densitometer measures the degree of light ...
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Utrecht (city)
Utrecht ( , , ) is the fourth-largest city and a municipality of the Netherlands, capital and most populous city of the province of Utrecht. It is located in the eastern corner of the Randstad conurbation, in the very centre of mainland Netherlands, about 35 km south east of the capital Amsterdam and 45 km north east of Rotterdam. It has a population of 361,966 as of 1 December 2021. Utrecht's ancient city centre features many buildings and structures, several dating as far back as the High Middle Ages. It has been the religious centre of the Netherlands since the 8th century. It was the most important city in the Netherlands until the Dutch Golden Age, when it was surpassed by Amsterdam as the country's cultural centre and most populous city. Utrecht is home to Utrecht University, the largest university in the Netherlands, as well as several other institutions of higher education. Due to its central position within the country, it is an important hub for both rail and road ...
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French Academy Of Science
The French Academy of Sciences (French: ''Académie des sciences'') is a learned society, founded in 1666 by Louis XIV at the suggestion of Jean-Baptiste Colbert, to encourage and protect the spirit of French scientific research. It was at the forefront of scientific developments in Europe in the 17th and 18th centuries, and is one of the earliest Academies of Sciences. Currently headed by Patrick Flandrin (President of the Academy), it is one of the five Academies of the Institut de France. History The Academy of Sciences traces its origin to Colbert's plan to create a general academy. He chose a small group of scholars who met on 22 December 1666 in the King's library, near the present-day Bibliothèque Nationals, and thereafter held twice-weekly working meetings there in the two rooms assigned to the group. The first 30 years of the Academy's existence were relatively informal, since no statutes had as yet been laid down for the institution. In contrast to its Britis ...
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Légion D'honneur
The National Order of the Legion of Honour (french: Ordre national de la Légion d'honneur), formerly the Royal Order of the Legion of Honour ('), is the highest French order of merit, both military and civil. Established in 1802 by Napoleon Bonaparte, it has been retained (with occasional slight alterations) by all later French governments and regimes. The order's motto is ' ("Honour and Fatherland"); its seat is the Palais de la Légion d'Honneur next to the Musée d'Orsay, on the left bank of the Seine in Paris. The order is divided into five degrees of increasing distinction: ' (Knight), ' (Officer), ' (Commander), ' (Grand Officer) and ' (Grand Cross). History Consulate During the French Revolution, all of the French orders of chivalry were abolished and replaced with Weapons of Honour. It was the wish of Napoleon Bonaparte, the First Consul, to create a reward to commend civilians and soldiers. From this wish was instituted a , a body of men that was not an order of ...
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Charlot Equation
The Charlot equation, named after Gaston Charlot, is used in analytical chemistry to relate the hydrogen ion concentration, and therefore the pH, with the formal analytical concentration of an acid and its conjugate base. It can be used for computing the pH of buffer solutions when the approximations of the Henderson–Hasselbalch equation break down. The Henderson–Hasselbalch equation assumes that the autoionization of water is negligible and that the dissociation or hydrolysis of the acid and the base in solution are negligible (in other words, that the formal concentration is the same as the equilibrium concentration). For an acid-base equilibrium such as HA H+ + A−, the Charlot equation may be written as :\mathrm = K_a \frac where +is the equilibrium concentration of H+, ''K''a is the acid dissociation constant, ''C''a and ''C''b are the analytical concentrations of the acid and its conjugate base, respectively, and Δ = +− H− The equation can be solved for +by ...
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Members Of The French Academy Of Sciences
Member may refer to: * Military jury, referred to as "Members" in military jargon * Element (mathematics), an object that belongs to a mathematical set * In object-oriented programming, a member of a class ** Field (computer science), entries in a database ** Member variable, a variable that is associated with a specific object * Limb (anatomy), an appendage of the human or animal body ** Euphemism for penis * Structural component of a truss, connected by nodes * User (computing), a person making use of a computing service, especially on the Internet * Member (geology), a component of a geological formation * Member of parliament * The Members, a British punk rock band * Meronymy, a semantic relationship in linguistics * Church membership, belonging to a local Christian congregation, a Christian denomination and the universal Church * Member, a participant in a club or learned society A learned society (; also learned academy, scholarly society, or academic association) is an ...
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