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Fullerides
Fullerides are chemical compounds containing fullerene anions. Common fullerides are derivatives of the most common fullerenes, i.e. C60 and C70. The scope of the area is large because multiple charges are possible, i.e., 60sup>''n''− (''n'' = 1, 2...6), and all fullerenes can be converted to fullerides. The suffix "-ide" implies their negatively charged nature. Fullerides can be isolated as derivatives with a wide range of cations. Most heavily studied derivatives are those with alkali metals, but fullerides have been prepared with organic cations. Fullerides are typically dark colored solids that generally dissolve in polar organic solvents. Structure and bonding According to electronic structure calculations, the LUMO of C60 is a triply degenerate orbital of t1u symmetry. Using the technique cyclic voltammetry, C60 can be shown to undergo six reversible reductions starting at −1 V referenced to the Fc+/Fc couple. Reduction causes only subtle changes in the stru ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Buckminsterfullerene
Buckminsterfullerene is a type of fullerene with the formula C60. It has a cage-like fused-ring structure (truncated icosahedron) made of twenty hexagons and twelve pentagons, and resembles a soccer ball. Each of its 60 carbon atoms is bonded to its three neighbors. Buckminsterfullerene is a black solid that dissolves in hydrocarbon solvents to produce a violet solution. The compound was discovered in 1985 and has received intense study, although few real world applications have been found. Occurrence Buckminsterfullerene is the most common naturally occurring fullerene. Small quantities of it can be found in soot. It also exists in space. Neutral C60 has been observed in planetary nebulae and several types of star. The ionised form, C60+, has been identified in the interstellar medium, where it is the cause of several absorption features known as diffuse interstellar bands in the near-infrared. History Theoretical predictions of buckyball molecules appeared i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reviews Of Modern Physics
''Reviews of Modern Physics'' (abbreviated RMP) is a quarterly peer-reviewed scientific journal published by the American Physical Society. It was established in 1929 and the current editor-in-chief is Michael Thoennessen. The journal publishes review articles, usually by established researchers, on all aspects of physics Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which rel ... and related fields. The reviews are usually accessible to non-specialists and serve as introductory material to graduate students, which survey recent work, discuss key problems to be solved and provide perspectives toward the end. References External links * Publications established in 1929 Physics review journals Quarterly journals English-language journals American Physical Society academic jour ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Condensed Matter
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with "condensed" phases of matter: systems of many constituents with strong interactions between them. More exotic condensed phases include the superconductivity, superconducting phase exhibited by certain materials at low temperature, the ferromagnetic and antiferromagnetic phases of spin (physics), spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other theoretical physics, theories to develop mathematical models. The diversity of systems and p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
