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Freeze-casting
Freeze-casting, also frequently referred to as ''ice-templating'', or ''freeze alignment'', is a technique that exploits the highly anisotropic solidification behavior of a solvent (generally water) in a well-dispersed slurry to controllably template a directionally porous ceramic. By subjecting an aqueous slurry to a directional temperature gradient, ice crystals will nucleate on one side of the slurry and grow along the temperature gradient. The ice crystals will redistribute the suspended ceramic particles as they grow within the slurry, effectively templating the ceramic. Once solidification has ended, the frozen, templated ceramic is placed into a freeze-dryer to remove the ice crystals. The resulting green body contains anisotropic macropores in a replica of the sublimated ice crystals and micropores found between the ceramic particles in the walls. This structure is often sintered to consolidate the particulate walls and provide strength to the porous material. The porosit ...
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Brownian Motion
Brownian motion, or pedesis (from grc, πήδησις "leaping"), is the random motion of particles suspended in a medium (a liquid or a gas). This pattern of motion typically consists of random fluctuations in a particle's position inside a fluid sub-domain, followed by a relocation to another sub-domain. Each relocation is followed by more fluctuations within the new closed volume. This pattern describes a fluid at thermal equilibrium, defined by a given temperature. Within such a fluid, there exists no preferential direction of flow (as in transport phenomena). More specifically, the fluid's overall linear and angular momenta remain null over time. The kinetic energies of the molecular Brownian motions, together with those of molecular rotations and vibrations, sum up to the caloric component of a fluid's internal energy (the equipartition theorem). This motion is named after the botanist Robert Brown, who first described the phenomenon in 1827, while looking throu ...
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Dendrite (crystal)
A crystal dendrite is a crystal that develops with a typical multi-branching form. The name comes from the Greek word dendron (δενδρον) which means "tree", since the crystal's structure resembles that of a tree. These crystals can be synthesised by using a supercooled pure liquid, however they are also quite common in nature. The most common crystals in nature exhibit dendritic growth are snowflakes and frost on windows, but many minerals and metals can also be found in dendritic structures. History Maximum velocity principle The first dendritic patterns were discovered in palaeontology and are often mistaken for fossils because of their appearance. The first theory for the creation of these patterns was published by Nash and Glicksman in 1974, they used a very mathematical method and derived a non-linear integro-differential equation for a classical needle growth. However they only found an inaccurate numerical solution close to the tip of the needle and they f ...
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Lamella (materials)
A ''lamella'' (plural ''lamellae'') is a small plate or flake, from the Latin, and may also be used to refer to collections of fine sheets of material held adjacent to one another, in a gill-shaped structure, often with fluid in between though sometimes simply a set of 'welded' plates. The term is used in biological contexts to describe thin membranes of plates of tissue. In context of materials science, the microscopic structures in bone and nacre are called lamellae. Moreover, the term lamella is often used as a way to describe crystal structure of some materials. Uses of the term In surface chemistry (especially mineralogy and materials science), lamellar structures are fine layers, alternating between different materials. They can be produced by chemical effects (as in eutectic solidification), biological means, or a deliberate process of lamination, such as pattern welding. Lamellae can also describe the layers of atoms in the crystal lattices of materials such as me ...
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Temperature Gradient
A temperature gradient is a physical quantity that describes in which direction and at what rate the temperature changes the most rapidly around a particular location. The temperature gradient is a dimensional quantity expressed in units of degrees (on a particular temperature scale) per unit length. The SI unit is kelvin per meter (K/m). Temperature gradients in the atmosphere are important in the atmospheric sciences (meteorology, climatology and related fields). Mathematical description Assuming that the temperature ''T'' is an intensive quantity, i.e., a single-valued, continuous and differentiable function of three-dimensional space (often called a scalar field), i.e., that :T=T(x,y,z) where ''x'', ''y'' and ''z'' are the coordinates of the location of interest, then the temperature gradient is the vector quantity defined as :\nabla T = \begin , , \end Physical processes Climatology On a global and annual basis, the dynamics of the atmosphere (and the oceans) ...
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Crystal Structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of Three-dimensional space (mathematics), three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive Translation (geometry), translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of the crystal are described by the con ...
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Ice Nucleus
An ice nucleus, also known as an ice nucleating particle (INP), is a particle which acts as the nucleus for the formation of an ice crystal in the atmosphere. Ice Nucleation Mechanisms There are a number of mechanisms of ice nucleation in the atmosphere through which ice nuclei can catalyse the formation of ice particles. In the upper troposphere, water vapor can deposit directly onto solid particles. In clouds warmer than about −37 °C where liquid water can persist in a supercooled state, ice nuclei can trigger droplets to freeze. Contact nucleation can occur if an ice nucleus collides with a supercooled droplet, but the more important mechanism of freezing is when an ice nucleus becomes immersed in a supercooled water droplet and then triggers freezing. In the absence of an ice nucleating particle, pure water droplets can persist in a supercooled state to temperatures approaching −37 °C where they freeze homogeneously. As per Web of Science, the key wor ...
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Particle Entrapment
In the physical sciences, a particle (or corpuscule in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from subatomic particles like the electron, to microscopic particles like atoms and molecules, to macroscopic particles like powders and other granular materials. Particles can also be used to create scientific models of even larger objects depending on their density, such as humans moving in a crowd or celestial bodies in motion. The term ''particle'' is rather general in meaning, and is refined as needed by various scientific fields. Anything that is composed of particles may be referred to as being particulate. However, the noun ''particulate'' is most frequently used to refer to pollutants in the Earth's atmosphere, which are a suspension of unconnected particles, rather than a connected particle aggregation. Conceptual properties The co ...
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Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ...
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Kinetics (physics)
In physics and engineering, kinetics is the branch of classical mechanics that is concerned with the relationship between the motion and its causes, specifically, forces and torques. Since the mid-20th century, the term " dynamics" (or "analytical dynamics") has largely superseded "kinetics" in physics textbooks, though the term is still used in engineering. In plasma physics, kinetics refers to the study of continua in velocity space. This is usually in the context of non-thermal ( non-Maxwellian) velocity distributions, or processes that perturb thermal distributions. These " kinetic plasmas" cannot be adequately described with fluid equations. The term ''kinetics'' is also used to refer to chemical kinetics, particularly in chemical physics and physical chemistry Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, ...
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Surface Potential
Surface charge is a two-dimensional surface with non-zero electric charge. These electric charges are constrained on this 2-D surface, and surface charge density, measured in coulombs per square meter (C•m−2), is used to describe the charge distribution on the surface. The electric potential is continuous across a surface charge and the electric field is discontinuous, but not infinite; this is unless the surface charge consists of a dipole layer. In comparison, the potential and electric field both diverge at any point charge or linear charge. In physics, at equilibrium, an ideal conductor has no charge on its interior; instead, the entirety of the charge of the conductor resides on the surface. However, this only applies to the ideal case of infinite electrical conductivity; The majority of the charge of an actual conductor resides within the skin depth of the conductor's surface. For dielectric materials, upon the application of an external electric field, the positive cha ...
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