Ferdinand Münz
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Ferdinand Münz
Ferdinand Münz (1888-1969) was an Austrian chemist who first synthesized EDTA (ethylenediaminetetraacetic acid) at the IG Farben in 1935, patented both in Germany (anonymously) and in the USA (with his name), with the aim of producing a citric acid substitute, in order to reduce the German government's dependence on imports of chemical products from abroad. Münz noted that an aminocarboxylic acid worked much better as a chelating agent than citric acid and therefore thought that a polyaminopolycarboxylic acid would have worked even better. In 1945 he worked closely with the future Nobel laureate Kurt Alder (1902-1958). In 1949 they published a paper together on diene synthesis and additions. See also * EDTA Ethylenediaminetetraacetic acid (EDTA) is an aminopolycarboxylic acid with the formula H2N(CH2CO2H)2sub>2. This white, water-soluble solid is widely used to bind to iron (Fe2+/Fe3+) and calcium ions (Ca2+), forming water-soluble complexes ev ... References {{ ...
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EDTA
Ethylenediaminetetraacetic acid (EDTA) is an aminopolycarboxylic acid with the formula H2N(CH2CO2H)2sub>2. This white, water-soluble solid is widely used to bind to iron (Fe2+/Fe3+) and calcium ions (Ca2+), forming water-soluble complexes even at neutral pH. It is thus used to dissolve Fe- and Ca-containing scale as well as to deliver iron ions under conditions where its oxides are insoluble. EDTA is available as several salts, notably disodium EDTA, sodium calcium edetate, and tetrasodium EDTA, but these all function similarly. Uses Textile industry In industry, EDTA is mainly used to sequester (bind or confine) metal ions in aqueous solution. In the textile industry, it prevents metal ion impurities from modifying colours of dyed products. In the pulp and paper industry, EDTA inhibits the ability of metal ions, especially Mn2+, from catalysing the disproportionation of hydrogen peroxide, which is used in chlorine-free bleaching. In a similar manner, EDTA is added ...
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Austria
Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous city and state. A landlocked country, Austria is bordered by Germany to the northwest, the Czech Republic to the north, Slovakia to the northeast, Hungary to the east, Slovenia and Italy to the south, and Switzerland and Liechtenstein to the west. The country occupies an area of and has a population of 9 million. Austria emerged from the remnants of the Eastern and Hungarian March at the end of the first millennium. Originally a margraviate of Bavaria, it developed into a duchy of the Holy Roman Empire in 1156 and was later made an archduchy in 1453. In the 16th century, Vienna began serving as the empire's administrative capital and Austria thus became the heartland of the Habsburg monarchy. After the dissolution of the H ...
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Glashütten (Taunus)
Glashütten is a small municipality in the Hochtaunuskreis. This community in the Taunus, which is made up of the three formerly independent communities of Glashütten, Schloßborn and Oberems, lies in the Hochtaunus Nature Park, not far from Königstein im Taunus, Germany. Geography Neighbouring communities Glashütten borders in the north on the communities of Waldems (Rheingau-Taunus-Kreis) and Schmitten, in the east on the town of Königstein, in the south on the towns of Kelkheim and Eppstein Eppstein is a town in the Main-Taunus-Kreis, in Hesse, Germany. Eppstein lies west of Frankfurt am Main, around 12 km north east of the state capital Wiesbaden, and is at the edge of the Taunus mountains. The ruins of the Eppstein castle is ..., and in the west on the town of Idstein (Rheingau-Taunus-Kreis). Constituent communities Glashütten consists of the three centres of Glashütten, Oberems and Schloßborn. Schloßborn This is arguably the first verifiable settleme ...
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Organic Chemistry
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; Greeves, N. and Warren, S. (2012) ''Organic Chemistry''. Oxford University Press. pp. 1–15. . Study of structure determines their structural formula. Study of properties includes physical and chemical properties, and evaluation of chemical reactivity to understand their behavior. The study of organic reactions includes the chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical ( in silico) study. The range of chemicals studied in organic chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but also containing other elements, especially oxygen, nitrogen, sulfur, phosphorus (included in ...
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Technische Universität Wien
TU Wien (TUW; german: Technische Universität Wien; still known in English as the Vienna University of Technology from 1975–2014) is one of the major universities in Vienna, Austria. The university finds high international and domestic recognition in teaching as well as in research, and it is a highly esteemed partner of innovation-oriented enterprises. It currently has about 28,100 students (29% women), eight faculties and about 5,000 staff members (3,800 academics). The university's teaching and research is focused on engineering, computer science, and natural sciences. History The institution was founded in 1815 by Emperor Francis I of Austria as the '' k.k. Polytechnische Institut'' (Imperial-Royal Polytechnic Institute). The first rector was Johann Joseph von Prechtl. It was renamed the ''Technische Hochschule'' (College of Technology) in 1872. When it began granting doctoral and higher degrees in 1975, it was renamed the ''Technische Universität Wien'' (Vienna Univer ...
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Citric Acid
Citric acid is an organic compound with the chemical formula HOC(CO2H)(CH2CO2H)2. It is a colorless weak organic acid. It occurs naturally in citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, which occurs in the metabolism of all aerobic organisms. More than two million tons of citric acid are manufactured every year. It is used widely as an acidifier, as a flavoring, and a chelating agent. A citrate is a derivative of citric acid; that is, the salts, esters, and the polyatomic anion found in solution. An example of the former, a salt is trisodium citrate; an ester is triethyl citrate. When part of a salt, the formula of the citrate anion is written as or . Natural occurrence and industrial production Citric acid occurs in a variety of fruits and vegetables, most notably citrus fruits. Lemons and limes have particularly high concentrations of the acid; it can constitute as much as 8% of the dry weight of these fruits (about 47 g/L in ...
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Kurt Alder
Kurt Alder (; 10 July 1902 – 20 June 1958) was a German chemist and Nobel laureate. Biography Alder was born in the industrial area of Königshütte, Silesia (modern day Chorzów, Upper Silesia, Poland), where he received his early schooling. Alder left the area when Königshütte became part of Poland in 1922. He studied chemistry at the University of Berlin from 1922, and later at the University of Kiel where his PhD was awarded in 1926 for work supervised by Otto Paul Hermann Diels. In 1930 Alder was appointed reader for chemistry at Kiel, and promoted to lecturer in 1934. In 1936 he left Kiel to join I G Farben Industrie at Leverkusen, where he worked on synthetic rubber. Then in 1940 he was appointed Professor of Experimental Chemistry and Chemical Technology at the University of Cologne and Director of the Institute of Chemistry there. Throughout this time and despite the many obstacles to original research in Europe at the time, he continued a systematic prog ...
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Diene
In organic chemistry a diene ( ) (diolefin ( ) or alkadiene) is a covalent compound that contains two double bonds, usually among carbon atoms. They thus contain two alk''ene'' units, with the standard prefix ''di'' of systematic nomenclature. As a subunit of more complex molecules, dienes occur in naturally occurring and synthetic chemicals and are used in organic synthesis. Conjugated dienes are widely used as monomers in the polymer industry. Polyunsaturated fats are of interest to nutrition. Classes Dienes can be divided into three classes, depending on the relative location of the double bonds: #Cumulated dienes have the double bonds sharing a common atom. The result is more specifically called an allene. #Conjugated dienes have conjugated double bonds separated by one single bond. Conjugated dienes are more stable than other dienes because of resonance. #Unconjugated dienes have the double bonds separated by two or more single bonds. They are usually less stable tha ...
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1888 Births
In Germany, 1888 is known as the Year of the Three Emperors. Currently, it is the year that, when written in Roman numerals, has the most digits (13). The next year that also has 13 digits is the year 2388. The record will be surpassed as late as 2888, which has 14 digits. Events January–March * January 3 – The 91-centimeter telescope at Lick Observatory in California is first used. * January 12 – The Schoolhouse Blizzard hits Dakota Territory, the states of Montana, Minnesota, Nebraska, Kansas, and Texas, leaving 235 dead, many of them children on their way home from school. * January 13 – The National Geographic Society is founded in Washington, D.C. * January 21 – The Amateur Athletic Union is founded by William Buckingham Curtis in the United States. * January 26 – The Lawn Tennis Association is founded in England. * February 6 – Gillis Bildt becomes Prime Minister of Sweden (1888–1889). * February 27 – In West O ...
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1969 Deaths
This year is notable for Apollo 11's first landing on the moon. Events January * January 4 – The Government of Spain hands over Ifni to Morocco. * January 5 **Ariana Afghan Airlines Flight 701 crashes into a house on its approach to London's Gatwick Airport, killing 50 of the 62 people on board and two of the home's occupants. * January 14 – An explosion aboard the aircraft carrier USS ''Enterprise'' near Hawaii kills 27 and injures 314. * January 19 – End of the siege of the University of Tokyo, marking the beginning of the end for the 1968–69 Japanese university protests. * January 20 – Richard Nixon is sworn in as the 37th President of the United States. * January 22 – An assassination attempt is carried out on Soviet leader Leonid Brezhnev by deserter Viktor Ilyin. One person is killed, several are injured. Brezhnev escaped unharmed. * January 27 ** Fourteen men, 9 of them Jews, are executed in Baghdad for spying for Israel. ...
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