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Freundlich Equation
The Freundlich equation or Freundlich adsorption isotherm, an adsorption isotherm, is an empirical relationship between the quantity of a gas adsorbed into a solid surface and the gas pressure. The same relationship is also applicable for the concentration of a solute adsorbed onto the surface of a solid and the concentration of the solute in the liquid phase. In 1909, Herbert Freundlich Herbert Max Finlay Freundlich (28 January 1880 in Charlottenburg – 30 March 1941 in Minneapolis) was a German chemist. His father was of German Jewish descent, and his mother ( Finlay) was from Scotland. His younger brother was Erw ... gave an expression representing the isothermal variation of adsorption of a quantity of gas adsorbed by unit mass of solid adsorbent with gas pressure. This equation is known as Freundlich adsorption isotherm or Freundlich adsorption equation. As this relationship is entirely empirical, in the case where adsorption behavior can be properly fit by is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adsorption Isotherm
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). Adsorption is a ''surface phenomenon'', while absorption involves the whole volume of the material, although adsorption does often precede absorption. The term ''sorption'' encompasses both processes, while ''desorption'' is the reverse of it. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in the material. However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent atoms and therefore can attract adsorbates. The exact nature of the bond ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Concentration
In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', '' molar concentration'', '' number concentration'', and '' volume concentration''. The concentration can refer to any kind of chemical mixture, but most frequently refers to solutes and solvents in solutions. The molar (amount) concentration has variants, such as normal concentration and osmotic concentration. Etymology The term concentration comes from the word concentrate, from the French , from con– + center, meaning “to put at the center”. Qualitative description Often in informal, non-technical language, concentration is described in a qualitative way, through the use of adjectives such as "dilute" for solutions of relatively low concentration and "concentrated" for solutions of relatively high concentration. To concentrate a solution, one must add more solute (for examp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solute
In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term " aqueous solution" is use ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Herbert Freundlich
Herbert Max Finlay Freundlich (28 January 1880 in Charlottenburg – 30 March 1941 in Minneapolis) was a German chemist. His father was of German Jewish descent, and his mother ( Finlay) was from Scotland. His younger brother was Erwin Finlay Freundlich (1885–1964). He was a department head at the Kaiser Wilhelm Institute for Physical Chemistry and Electrochemistry (now the Fritz Haber Institute) from 1919 until 1933, when the racial policies of the Nazi party demanded the dismissal of non-Aryans from senior posts. In 1934 he became a foreign member of the Royal Netherlands Academy of Arts and Sciences. Emigrating to England, Freundlich accepted a guest professorship at University College London. Five years later, he accepted a professorship at the University of Minnesota. He died in Minneapolis two years later. Freundlich's main works dealt with the coagulation and stability of colloidal solutions. His most prominent student was Robert Havemann who became a w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Akademische Verlagsgesellschaft
The (AVG, AVg, Aka, AV; English: Academic publishing company) in Leipzig was an important German academic publisher, which was founded in 1906. The original Jewish owners of the publishing house and key employees were expropriated during the time of the Nazi regime, emigrated and founded new scientific publishing houses in other countries. The publishing house was then named . After World War II, in the German Democratic Republic (GDR/DDR) the Leipzig branch of the publishing house was transformed into in 1947 and 1951. This was dissolved in 1991 as a consequence of the German reunification. Between 1953 and 1983, another seeing itself as the legal successor of the original company existed in the Federal Republic of Germany (FRG/BRD) in Frankfurt am Main and Wiesbaden. Today, there are two German publishing houses claiming to stand in the tradition of the , AULA-Verlag and AKA-Verlag, although legally they are new and independent foundations. History founded an antiquar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Langmuir Adsorption Isotherm
The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes. This model even explains the effect of pressure i.e at these conditions the adsorbate's partial pressure, p_A, is related to the volume of it, , adsorbed onto a solid adsorbent. The adsorbent, as indicated in the figure, is assumed to be an ideal solid surface composed of a series of distinct sites capable of binding the adsorbate. The adsorbate binding is treated as a chemical reaction between the adsorbate gaseous molecule A_\text and an empty sorption site, . This reaction yields an adsorbed species A_\text with an associated equilibrium constant K_\text: : A_ + S A_ From these basic hypotheses the mathematical formulation of the Langmuir adsorption isotherm can be derived in various independent and complementary ways: by the kinetics, the thermodynamics, and the statistical m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
BET Theory
Brunauer–Emmett–Teller (BET) theory aims to explain the physical adsorption Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which ... of gas molecules on a solid Surface science, surface and serves as the basis for an important analysis technique for the measurement of the specific surface area of materials. The observations are very often referred to as physical adsorption or physisorption. In 1938, Stephen Brunauer, Paul H. Emmett, Paul Hugh Emmett, and Edward Teller presented their theory in the ''Journal of the American Chemical Society''. BET theory applies to systems of multilayer adsorption that usually utilizes a probing gas (called the adsorbate) that do not react chemically with the adsorptive (the material upon which the gas attaches to and the gas phase is called the adsorp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Freundlich Acetic Acid
Freundlich is a surname which may refer to: *Bart Freundlich (born 1970), American film director, screenwriter and producer *Herbert Freundlich (1880–1941), German chemist *Irwin Freundlich (1908-1977), US music teacher and academician *Jeff Lindsay (writer), pen name of Jeffry Freundlich (born 1952), American author *Otto Freundlich (1878-1943), German artist See also * Freindlich *Erwin Finlay-Freundlich (1885–1964), German astronomer **Freundlich (crater), a crater on the far side of the Moon named in his honor *Freundlich equation The Freundlich equation or Freundlich adsorption isotherm, an adsorption isotherm, is an empirical relationship between the quantity of a gas adsorbed into a solid surface and the gas pressure. The same relationship is also applicable for the conc ..., an adsorption (adhesion of gas or liquid on solid) equation {{surname German-language surnames Jewish surnames Yiddish-language surnames ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adsorbate
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). Adsorption is a ''surface phenomenon'', while absorption involves the whole volume of the material, although adsorption does often precede absorption. The term ''sorption'' encompasses both processes, while ''desorption'' is the reverse of it. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in the material. However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent atoms and therefore can attract adsorbates. The exact nature of the bo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adsorbent
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). Adsorption is a ''surface phenomenon'', while absorption involves the whole volume of the material, although adsorption does often precede absorption. The term '' sorption'' encompasses both processes, while '' desorption'' is the reverse of it. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in the material. However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent atoms and therefore can attract adsorbates. The exact nature of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and even by industry. Further, both spellings are often used ''within'' a particular industry or country. Industries in British English-speaking countries typically use the "gauge" spelling. is the pressure relative to the ambient pressure. Various units are used to express pressure. Some of these derive from a unit of force divided by a unit of area; the SI unit of pressure, the pascal (Pa), for example, is one newton per square metre (N/m2); similarly, the pound-force per square inch ( psi) is the traditional unit of pressure in the imperial and U.S. customary systems. Pressure may also be expressed in terms of standard atmospheric pressure; the atmosphere (atm) is equal to this pressure, and the torr is defined as of this. Manome ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Distribution Coefficient
In the physical sciences, a partition coefficient (''P'') or distribution coefficient (''D'') is the ratio of concentrations of a compound in a mixture of two immiscible solvents at equilibrium. This ratio is therefore a comparison of the solubilities of the solute in these two liquids. The partition coefficient generally refers to the concentration ratio of un-ionized species of compound, whereas the distribution coefficient refers to the concentration ratio of all species of the compound (ionized plus un-ionized). In the chemical and pharmaceutical sciences, both phases usually are solvents. Most commonly, one of the solvents is water, while the second is hydrophobic, such as 1-octanol. Hence the partition coefficient measures how hydrophilic ("water-loving") or hydrophobic ("water-fearing") a chemical substance is. Partition coefficients are useful in estimating the distribution of drugs within the body. Hydrophobic drugs with high octanol-water partition coefficients are m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
