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Fourier Transform Spectrometer
Fourier-transform spectroscopy is a measurement technique whereby spectra are collected based on measurements of the coherence of a radiative source, using time-domain or space-domain measurements of the radiation, electromagnetic or not. It can be applied to a variety of types of ''spectroscopy'' including optical spectroscopy, infrared spectroscopy ( FTIR, FT-NIRS), nuclear magnetic resonance (NMR) and magnetic resonance spectroscopic imaging (MRSI), mass spectrometry and electron spin resonance spectroscopy. There are several methods for measuring the temporal coherence of the light (see: field-autocorrelation), including the continuous-wave and the pulsed Fourier-transform spectrometer or Fourier-transform spectrograph. The term "Fourier-transform spectroscopy" reflects the fact that in all these techniques, a Fourier transform is required to turn the raw data into the actual spectrum, and in many of the cases in optics involving interferometers, is based on the Wiener–K ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectrum (physics)
A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a Continuum (measurement), continuum. The word was first used scientifically in optics to describe the rainbow of colors in visible light after passing through a triangular prism (optics), prism. As scientific understanding of light advanced, it came to apply to the entire electromagnetic spectrum. It thereby became a mapping of a range of magnitudes (wavelengths) to a range of qualities, which are the perceived "colors of the rainbow" and other properties which correspond to wavelengths that lie outside of the visible light spectrum. Spectrum has since been applied by analogy to topics outside optics. Thus, one might talk about the "political spectrum, spectrum of political opinion", or the "spectrum of activity" of a drug, or the "autism spectrum". In these uses, values within a spectrum may not be associated with precisely quantifi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wiener–Khinchin Theorem
In applied mathematics, the Wiener–Khinchin theorem or Wiener–Khintchine theorem, also known as the Wiener–Khinchin–Einstein theorem or the Khinchin–Kolmogorov theorem, states that the autocorrelation function of a wide-sense-stationary random process has a spectral decomposition given by the power spectrum of that process. History Norbert Wiener proved this theorem for the case of a deterministic function in 1930; Aleksandr Khinchin later formulated an analogous result for stationary stochastic processes and published that probabilistic analogue in 1934. Albert Einstein explained, without proofs, the idea in a brief two-page memo in 1914. The case of a continuous-time process For continuous time, the Wiener–Khinchin theorem says that if x is a wide-sense stochastic process whose autocorrelation function (sometimes called autocovariance) defined in terms of statistical expected value, r_(\tau) = \mathbb\big (t)^*x(t - \tau)\big/math> (the asterisk denotes complex co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Paramagnetic Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the fie ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sine And Cosine Transforms
In mathematics, the Fourier sine and cosine transforms are forms of the Fourier transform that do not use complex numbers or require negative frequency. They are the forms originally used by Joseph Fourier and are still preferred in some applications, such as signal processing or statistics. Definition The Fourier sine transform of , sometimes denoted by either ^s or _s (f) , is ^s(\xi) = \int_^\infty f(t)\sin(2\pi \xi t) \,dt. If means time, then is frequency in cycles per unit time, but in the abstract, they can be any pair of variables which are dual to each other. This transform is necessarily an odd function of frequency, i.e. for all : ^s(-\xi) = - ^s(\xi). The numerical factors in the Fourier transforms are defined uniquely only by their product. Here, in order that the Fourier inversion formula not have any numerical factor, the factor of 2 appears because the sine function has norm of \tfrac. The Fourier cosine transform of , sometimes denoted by either ^c o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wavenumber
In the physical sciences, the wavenumber (also wave number or repetency) is the ''spatial frequency'' of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber). It is analogous to temporal frequency, which is defined as the number of wave cycles per unit time (''ordinary frequency'') or radians per unit time (''angular frequency''). In multidimensional systems, the wavenumber is the magnitude of the ''wave vector''. The space of wave vectors is called ''reciprocal space''. Wave numbers and wave vectors play an essential role in optics and the physics of wave scattering, such as X-ray diffraction, neutron diffraction, electron diffraction, and elementary particle physics. For quantum mechanical waves, the wavenumber multiplied by the reduced Planck's constant is the ''canonical momentum''. Wavenumber can be used to specify quantities other than spatial frequency. For example, in optical spectroscopy, it is often used ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Michelson Interferometer
The Michelson interferometer is a common configuration for optical interferometry and was invented by the 19/20th-century American physicist Albert Abraham Michelson. Using a beam splitter, a light source is split into two arms. Each of those light beams is reflected back toward the beamsplitter which then combines their amplitudes using the superposition principle. The resulting interference pattern that is not directed back toward the source is typically directed to some type of photoelectric detector or camera. For different applications of the interferometer, the two light paths can be with different lengths or incorporate optical elements or even materials under test. The Michelson interferometer (among other interferometer configurations) is employed in many scientific experiments and became well known for its use by Michelson and Edward Morley in the famous Michelson–Morley experiment (1887) in a configuration which would have detected the Earth's motion through the sup ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Michelson–Morley Experiment
The Michelson–Morley experiment was an attempt to detect the existence of the luminiferous aether, a supposed medium permeating space that was thought to be the carrier of light waves. The experiment was performed between April and July 1887 by American physicists Albert A. Michelson and Edward W. Morley at what is now Case Western Reserve University in Cleveland, Ohio, and published in November of the same year. The experiment compared the speed of light in perpendicular directions in an attempt to detect the relative motion of matter through the stationary luminiferous aether ("aether wind"). The result was negative, in that Michelson and Morley found no significant difference between the speed of light in the direction of movement through the presumed aether, and the speed at right angles. This result is generally considered to be the first strong evidence against the then-prevalent aether theory, as well as initiating a line of research that eventually led to special r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fourier Transform Spectrometer
Fourier-transform spectroscopy is a measurement technique whereby spectra are collected based on measurements of the coherence of a radiative source, using time-domain or space-domain measurements of the radiation, electromagnetic or not. It can be applied to a variety of types of ''spectroscopy'' including optical spectroscopy, infrared spectroscopy ( FTIR, FT-NIRS), nuclear magnetic resonance (NMR) and magnetic resonance spectroscopic imaging (MRSI), mass spectrometry and electron spin resonance spectroscopy. There are several methods for measuring the temporal coherence of the light (see: field-autocorrelation), including the continuous-wave and the pulsed Fourier-transform spectrometer or Fourier-transform spectrograph. The term "Fourier-transform spectroscopy" reflects the fact that in all these techniques, a Fourier transform is required to turn the raw data into the actual spectrum, and in many of the cases in optics involving interferometers, is based on the Wiener–K ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absorption Spectroscopy
Absorption spectroscopy refers to spectroscopic techniques that measure the absorption of radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum. Absorption spectroscopy is employed as an analytical chemistry tool to determine the presence of a particular substance in a sample and, in many cases, to quantify the amount of the substance present. Infrared and ultraviolet–visible spectroscopy are particularly common in analytical applications. Absorption spectroscopy is also employed in studies of molecular and atomic physics, astronomical spectroscopy and remote sensing. There is a wide range of experimental approaches for measuring absorption spectra. The most common arrangement is to direct ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wave Interference
In physics, interference is a phenomenon in which two waves combine by adding their displacement together at every single point in space and time, to form a resultant wave of greater, lower, or the same amplitude. Constructive and destructive interference result from the interaction of waves that are correlated or coherent with each other, either because they come from the same source or because they have the same or nearly the same frequency. Interference effects can be observed with all types of waves, for example, light, radio, acoustic, surface water waves, gravity waves, or matter waves. Etymology The word ''interference'' is derived from the Latin words ''inter'' which means "between" and ''fere'' which means "hit or strike", and was coined by Thomas Young in 1801. Mechanisms The principle of superposition of waves states that when two or more propagating waves of the same type are incident on the same point, the resultant amplitude at that point is equal to t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
