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Filip Neriusz Walter
Filip Neriusz Walter or Philippe Walter (31 May 1810 – 9 April 1847) was a Polish chemist and pioneer of organic chemistry who worked in Paris. A pioneer of organic chemistry, he was extracted and characterized several compounds including toluene and octene. Life Walter was one of the youngest students of the Jagiellonian University in Kraków, where he studied history and chemistry in 1825–28. Subsequently, he studied at Berlin University, receiving a Ph.D. with his dissertation ''On Combination of Oxalic Acid and Alkali''. Simultaneously he served as assistant to Professor Eilhard Mitscherlich.Stefan Sękowski, Stefan Szostkiewicz, ''Serce i retorta'' (The Heart and the Retort), Warsaw, Wiedza Powszechna, 1957. On the outbreak of the November 1830 Uprising, he went to Warsaw and joined the Polish Army. He served as adjutant to Colonel Samuel Różycki, commander of the 7th infantry regiment. In 1831, aged 21, he was named professor of chemistry at the Jagiellonian Universit ...
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Chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe the properties they study in terms of quantities, with detail on the level of molecules and their component atoms. Chemists carefully measure substance proportions, chemical reaction rates, and other chemical properties. In Commonwealth English, pharmacists are often called chemists. Chemists use their knowledge to learn the composition and properties of unfamiliar substances, as well as to reproduce and synthesize large quantities of useful naturally occurring substances and create new artificial substances and useful processes. Chemists may specialize in any number of subdisciplines of chemistry. Materials scientists and metallurgists share much of the same education and skills with chemists. The work of chemists is often related to the ...
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Biphenyl
Biphenyl (also known as diphenyl, phenylbenzene, 1,1′-biphenyl, lemonene or BP) is an organic compound that forms colorless crystals. Particularly in older literature, compounds containing the functional group consisting of biphenyl less one hydrogen (the site at which it is attached) may use the prefixes xenyl or diphenylyl. It has a distinctively pleasant smell. Biphenyl is an aromatic hydrocarbon with a molecular formula (C6H5)2. It is notable as a starting material for the production of polychlorinated biphenyls (PCBs), which were once widely used as dielectric fluids and heat transfer agents. Biphenyl is also an intermediate for the production of a host of other organic compounds such as emulsifiers, optical brighteners, crop protection products, and plastics. Biphenyl is insoluble in water, but soluble in typical organic solvents. The biphenyl molecule consists of two connected phenyl rings. Properties and occurrence Biphenyl occurs naturally in coal tar, crude oil, a ...
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1847 Deaths
Events January–March * January 4 – Samuel Colt sells his first revolver pistol to the U.S. government. * January 13 – The Treaty of Cahuenga ends fighting in the Mexican–American War in California. * January 16 – John C. Frémont is appointed Governor of the new California Territory. * January 17 – St. Anthony Hall fraternity is founded at Columbia University, New York City. * January 30 – Yerba Buena, California, is renamed San Francisco. * February 5 – A rescue effort, called the First Relief, leaves Johnson's Ranch to save the ill-fated Donner Party (California-bound emigrants who became snowbound in the Sierra Nevada earlier this winter; some have resorted to survival by cannibalism). * February 22 – Mexican–American War: Battle of Buena Vista – 5,000 American troops under General Zachary Taylor use their superiority in artillery to drive off 15,000 Mexican troops under Antonio López de Santa Anna, defeating the Mexicans the next day. * ...
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1810 Births
Year 181 ( CLXXXI) was a common year starting on Sunday (link will display the full calendar) of the Julian calendar. At the time, it was known as the Year of the Consulship of Aurelius and Burrus (or, less frequently, year 934 ''Ab urbe condita''). The denomination 181 for this year has been used since the early medieval period, when the Anno Domini calendar era became the prevalent method in Europe for naming years. Events By place Roman Empire * Imperator Lucius Aurelius Commodus and Lucius Antistius Burrus become Roman Consuls. * The Antonine Wall is overrun by the Picts in Britannia (approximate date). Oceania * The volcano associated with Lake Taupō in New Zealand erupts, one of the largest on Earth in the last 5,000 years. The effects of this eruption are seen as far away as Rome and China. Births * April 2 – Xian of Han, Chinese emperor (d. 234) * Zhuge Liang, Chinese chancellor and regent (d. 234) Deaths * Aelius Aristides, Greek orator and w ...
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Aleksander Jełowicki
Aleksander Jełowicki (18 December 1804 in Hubnyk - 15 April 1877 in Rome) was a Polish writer, poet, translator and publisher. He was a veteran of the November Uprising, deputy to the Sejm of Congress Poland for the Haisyn powiat and political exile in France, where he was a social activist, superior of the Polish Catholic Mission in Paris and monk. Among the works he published are the first editions of Adam Mickiewicz's '' Part III of Dziady'' (1832) and ''Pan Tadeusz'' (1834). Between 1835 and 1838 he was leading partner of the publishing house and printing works, ''Jełowicki i S-ka'' in Paris. His list of authors constitutes a major part of Poland's 19th-century literary canon and includes: Juliusz Słowacki, Zygmunt Krasiński, Julian Ursyn Niemcewicz, Kazimierz Brodziński, Stefan Witwicki, Wincenty Pol, Antoni Gorecki, Maurycy Mochnacki, Joachim Lelewel, Henryk Rzewuski, Michał Czajkowski, Klementyna Hoffmanowa, Ignacy Krasicki. In 1844 he arrived in Paris, where he ...
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List Of Poles
This is a partial list of notable Polish or Polish-speaking or -writing people. People of partial Polish heritage have their respective ancestries credited. Science Physics * Czesław Białobrzeski * Andrzej Buras * Georges Charpak, 1995 Nobel Prize * Jan Kazimierz Danysz * Marian Danysz * Tomasz Dietl * Maria Dworzecka * Artur Ekert, one of the independent inventors (in 1991) of quantum cryptography * Marek Gazdzicki * Ryszard Horodecki * Leopold Infeld * Aleksander Jabłoński * Jerzy Stanisław Janicki * Sylwester Kaliski * Elżbieta Kossecka * Jan Eugeniusz Krysiński * Stanislas Leibler * Maciej Lewenstein * Olga Malinkiewicz * Albert A. Michelson, 1907 Nobel Prize * Lidia Morawska * Stanisław Mrozowski * Władysław Natanson * Witold Nazarewicz * Henryk Niewodniczański * Georges Nomarski * Karol Olszewski * Jerzy Plebański * Jerzy Pniewski * Nikodem Popławski * Sylwester Porowski, blue laser * Józef Rotblat, 1995 Nobel Peace Prize * Stefan Rozent ...
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Legion Of Honour
The National Order of the Legion of Honour (french: Ordre national de la Légion d'honneur), formerly the Royal Order of the Legion of Honour ('), is the highest French order of merit, both military and civil. Established in 1802 by Napoleon, Napoleon Bonaparte, it has been retained (with occasional slight alterations) by all later French governments and regimes. The order's motto is ' ("Honour and Fatherland"); its Seat (legal entity), seat is the Palais de la Légion d'Honneur next to the Musée d'Orsay, on the left bank of the Seine in Paris. The order is divided into five degrees of increasing distinction: ' (Knight), ' (Officer), ' (Commander (order), Commander), ' (Grand Officer) and ' (Grand Cross). History Consulate During the French Revolution, all of the French Order of chivalry, orders of chivalry were abolished and replaced with Weapons of Honour. It was the wish of Napoleon, Napoleon Bonaparte, the French Consulate, First Consul, to create a reward to commend c ...
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Menthol
Menthol is an organic compound, more specifically a monoterpenoid, made synthetically or obtained from the oils of corn mint, peppermint, or other mints. It is a waxy, clear or white crystalline substance, which is solid at room temperature and melts slightly above. The main form of menthol occurring in nature is (−)-menthol, which is assigned the (1''R'',2''S'',5''R'') configuration. Menthol has local anesthetic and counterirritant qualities, and it is widely used to relieve minor throat irritation. Menthol also acts as a weak κ-opioid receptor agonist. Structure Natural menthol exists as one pure stereoisomer, nearly always the (1''R'',2''S'',5''R'') form (bottom left corner of the diagram below). The eight possible stereoisomers are: : In the natural compound, the isopropyl group is in the ''trans'' orientation to both the methyl and hydroxyl groups. Thus, it can be drawn in any of the ways shown: : The (+)- and (−)-enantiomers of menthol are the most stable among ...
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Benzyl Bromide
Benzyl bromide is an organic compound with the formula . The molecule consists of a benzene ring substituted with a bromomethyl group. It is a colorless liquid with lachrymatory properties. The compound is a reagent for introducing benzyl groups. Synthesis and structure Benzyl bromide can be synthesized by the bromination of toluene under conditions suitable for a free radical halogenation: : The structure has been examined by electron diffraction. Applications Benzyl bromide is used in organic synthesis for the introduction of the benzyl groups when the less expensive benzyl chloride is insufficiently reactive. Benzylations are often achieved in the presence of catalytic amounts of sodium iodide, which generates the more reactive benzyl iodide in situ. In some cases, benzyl serves as protecting group for alcohols and carboxylic acids. Safety Benzyl bromide is a strong lachrymator and is also intensely irritating to skin and mucous membranes. Because of these properties, it ...
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Benzyl Chloride
Benzyl chloride, or α-chlorotoluene, is an organic compound with the formula C6H5CH2Cl. This colorless liquid is a reactive organochlorine compound that is a widely used chemical building block. Preparation Benzyl chloride is prepared industrially by the gas-phase photochemical reaction of toluene with chlorine: :C6H5CH3 + Cl2 → C6H5CH2Cl + HCl In this way, approximately 100,000 tonnes are produced annually. The reaction proceeds by the free radical process, involving the intermediacy of free chlorine atoms. Side products of the reaction include benzal chloride and benzotrichloride. Other methods of production exist, such as the Blanc chloromethylation of benzene. Benzyl chloride was first prepared from treatment of benzyl alcohol with hydrochloric acid. Uses and reactions Industrially, benzyl chloride is the precursor to benzyl esters, which are used as plasticizers, flavorants, and perfumes. Phenylacetic acid, a precursor to pharmaceuticals, is produced from benzyl cyan ...
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Cumene
Cumene (isopropylbenzene) is an organic compound that contains a benzene ring with an isopropyl substituent. It is a constituent of crude oil and refined fuels. It is a flammable colorless liquid that has a boiling point of 152 °C. Nearly all the cumene that is produced as a pure compound on an industrial scale is converted to cumene hydroperoxide, which is an intermediate in the synthesis of other industrially important chemicals, primarily phenol and acetone (known as the cumene process). Production Commercial production of cumene is by Friedel–Crafts alkylation of benzene with propylene. Cumene producers account for approximately 20% of the global demand for benzene. The original route for manufacturing of cumene was by alkylation of benzene in the liquid phase using sulfuric acid as a catalyst, but because of the complicated neutralization and recycling steps required, together with corrosion problems, this process has been largely replaced. As an alternative, sol ...
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Chromyl Chloride
Chromyl chloride is the inorganic compound with the formula CrO2Cl2. It is a reddish brown compound that is a volatile liquid at room temperature, which is unusual for transition metal complexes. Preparation Chromyl chloride can be prepared by the reaction of potassium chromate or potassium dichromate with hydrogen chloride in the presence of sulfuric acid, followed by distillation. :K2Cr2O7 + 6 HCl → 2 CrO2Cl2 + 2 KCl + 3 H2O The sulfuric acid serves as the dehydration agent. It can also be prepared directly by exposing chromium trioxide to anhydrous hydrogen chloride gas. :CrO3 + 2 HCl ⇌ CrO2Cl2 + H2O The method used to prepare chromyl chloride is the basis for a qualitative test for chloride: a sample suspected of containing chloride is heated with a mixture of potassium dichromate and concentrated sulfuric acid. If chloride is present, chromyl chloride forms as evidenced by red fumes of CrO2Cl2. Analogous compounds are not formed with fluorides, bromides, iodides and cy ...
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