Ferrimagnetic
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Ferrimagnetic
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when the populations consist of different atoms or ions (such as Fe2+ and Fe3+). Ferrimagnetism has often been confused with ferromagnetism. The oldest known magnetic substance, magnetite (Fe3O4), was classified as a ferromagnet before Louis Néel discovered ferrimagnetism in 1948. Since the discovery, numerous uses have been found for ferrimagnetic materials, such as hard drive platters and biomedical applications. History Until the twentieth century, all naturally occurring magnetic substances were called ferromagnets. In 1936, Louis Néel published a paper proposing the existence of a new form of cooperative magnetism he called antiferromagnetism. While working with Mn2Sb, French physicist Charles Guillaud discovered that the current theo ...
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Ferrimagnetic Ordering
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when the populations consist of different atoms or ions (such as Fe2+ and Fe3+). Ferrimagnetism has often been confused with ferromagnetism. The oldest known magnetic substance, magnetite (Fe3O4), was classified as a ferromagnet before Louis Néel discovered ferrimagnetism in 1948. Since the discovery, numerous uses have been found for ferrimagnetic materials, such as hard drive platters and biomedical applications. History Until the twentieth century, all naturally occurring magnetic substances were called ferromagnets. In 1936, Louis Néel published a paper proposing the existence of a new form of cooperative magnetism he called antiferromagnetism. While working with Mn2Sb, French physicist Charles Guillaud discovered that the current theo ...
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Ferrimagnetism - Magnetic Moment As A Function Of Temperature
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when the populations consist of different atoms or ions (such as Fe2+ and Fe3+). Ferrimagnetism has often been confused with ferromagnetism. The oldest known magnetic substance, magnetite (Fe3O4), was classified as a ferromagnet before Louis Néel discovered ferrimagnetism in 1948. Since the discovery, numerous uses have been found for ferrimagnetic materials, such as hard drive platters and biomedical applications. History Until the twentieth century, all naturally occurring magnetic substances were called ferromagnets. In 1936, Louis Néel published a paper proposing the existence of a new form of cooperative magnetism he called antiferromagnetism. While working with Mn2Sb, French physicist Charles Guillaud discovered that the current theo ...
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Curie Temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Curie temperature is named after Pierre Curie, who showed that magnetism was lost at a critical temperature. The force of magnetism is determined by the magnetic moment, a dipole moment within an atom which originates from the angular momentum and spin of electrons. Materials have different structures of intrinsic magnetic moments that depend on temperature; the Curie temperature is the critical point at which a material's intrinsic magnetic moments change direction. Permanent magnetism is caused by the alignment of magnetic moments and induced magnetism is created when disordered magnetic moments are forced to align in an applied magnetic field. For example, the ordered magnetic moments (ferromagnetic, Figure 1) change and become disorder ...
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Ferromagnetism
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials are the familiar metals noticeably attracted to a magnet, a consequence of their large magnetic permeability. Magnetic permeability describes the induced magnetization of a material due to the presence of an ''external'' magnetic field, and it is this temporarily induced magnetization inside a steel plate, for instance, which accounts for its attraction to the permanent magnet. Whether or not that steel plate acquires a permanent magnetization itself, depends not only on the strength of the applied field, but on the so-called coercivity of that material, which varies greatly among ferromagnetic materials. In physics, several different types of material magnetism are distinguished. Ferromagnetism (along with the similar effect ferrimagnetis ...
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Magnetic Orders
Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particles give rise to a magnetic field, which acts on other currents and magnetic moments. Magnetism is one aspect of the combined phenomena of electromagnetism. The most familiar effects occur in ferromagnetic materials, which are strongly attracted by magnetic fields and can be magnetized to become permanent magnets, producing magnetic fields themselves. Demagnetizing a magnet is also possible. Only a few substances are ferromagnetic; the most common ones are iron, cobalt, and nickel and their alloys. The rare-earth metals neodymium and samarium are less common examples. The prefix ' refers to iron because permanent magnetism was first observed in lodestone, a form of natural iron ore called magnetite, Fe3O4. All substances exhibit some type of m ...
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Antiferromagnetism
In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. This is, like ferromagnetism and ferrimagnetism, a manifestation of ordered magnetism. The phenomenon of antiferromagnetism was first introduced by Lev Landau in 1933. Generally, antiferromagnetic order may exist at sufficiently low temperatures, but vanishes at and above the Néel temperature – named after Louis Néel, who had first identified this type of magnetic ordering. Above the Néel temperature, the material is typically paramagnetic. Measurement When no external field is applied, the antiferromagnetic structure corresponds to a vanishing total magnetization. In an external magnetic field, a kind of ferrimagnetic behavior may be displayed in the antiferromagnetic phase, with the absolute value of one of the sublattice magneti ...
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Applied Magnetic Field
A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, and are created by electric currents such as those used in electromagnets, and by electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function assigning a vector to each point of space, cal ...
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Magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the exception of extremely rare native iron deposits, it is the most magnetic of all the naturally occurring minerals on Earth. Naturally magnetized pieces of magnetite, called lodestone, will attract small pieces of iron, which is how ancient peoples first discovered the property of magnetism. Magnetite is black or brownish-black with a metallic luster, has a Mohs hardness of 5–6 and leaves a black streak. Small grains of magnetite are very common in igneous and metamorphic rocks. The chemical IUPAC name is iron(II,III) oxide and the common chemical name is ''ferrous-ferric oxide''. Properties In addition to igneous rocks, magnetite also occurs in sedimentary rocks, including banded iron formations and in lake and marine sediments ...
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Spontaneous Magnetization
Spontaneous magnetization is the appearance of an ordered spin state (magnetization) at zero applied magnetic field in a ferromagnetic or ferrimagnetic material below a critical point called the Curie temperature or . Overview Heated to temperatures above , ferromagnetic materials become paramagnetic and their magnetic behavior is dominated by spin waves or magnons, which are boson collective excitations with energies in the meV range. The magnetization that occurs below is an example of the "spontaneous" breaking of a global symmetry, a phenomenon that is described by Goldstone's theorem. The term "symmetry breaking" refers to the choice of a magnetization direction by the spins, which have spherical symmetry above , but a preferred axis (the magnetization direction) below . Temperature dependence To a first order approximation, the temperature dependence of spontaneous magnetization at low temperatures is given by the Bloch T3/2 law: :M(T) = M(0)\left(1-(T/T_c\right)^), ...
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Paramagnetism
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, diamagnetic materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field. Paramagnetic materials include most chemical elements and some compounds; they have a relative magnetic permeability slightly greater than 1 (i.e., a small positive magnetic susceptibility) and hence are attracted to magnetic fields. The magnetic moment induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a SQUID magnetometer. Paramagnetism is due to the presence of unpaired electrons in the material, so most atoms ...
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Resistivity
Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows electric current. Resistivity is commonly represented by the Greek letter  (rho). The SI unit of electrical resistivity is the ohm-meter (Ω⋅m). For example, if a solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is , then the resistivity of the material is . Electrical conductivity or specific conductance is the reciprocal of electrical resistivity. It represents a material's ability to conduct electric current. It is commonly signified by the Greek letter  ( sigma), but  (kappa) (especially in electrical engineering) and  (gamma) are sometimes used. The SI unit of electrical conductivity is siemens per metre (S/m). Resistivity and conductivity are intensi ...
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Magnetic Hysteresis
Magnetic hysteresis occurs when an external magnetic field is applied to a ferromagnet such as iron and the atomic dipoles align themselves with it. Even when the field is removed, part of the alignment will be retained: the material has become ''magnetized''. Once magnetized, the magnet will stay magnetized indefinitely. To demagnetize it requires heat or a magnetic field in the opposite direction. This is the effect that provides the element of memory in a hard disk drive. The relationship between field strength and magnetization is not linear in such materials. If a magnet is demagnetized () and the relationship between and is plotted for increasing levels of field strength, follows the ''initial magnetization curve''. This curve increases rapidly at first and then approaches an asymptote called magnetic saturation. If the magnetic field is now reduced monotonically, follows a different curve. At zero field strength, the magnetization is offset from the origin by an am ...
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