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Electrocapillarity
Electrocapillarity or electrocapillary phenomena are the phenomena related to changes in the surface energy (or interfacial tension) of the dropping mercury electrode (DME), or in principle, any electrode, as the electrode potential changes or the electrolytic solution composition and concentration change. The term "electro-capillary" is used to describe the change in mercury (Hg) electrode potential as a function of the change in the surface or interfacial tension of the Hg determined by the capillary rise method. The phenomena are the historic main contributions for understanding and validating the models of the structure of the electrical double layer. The phenomena are related to the electrokinetic phenomena and consequently to the colloid chemistry. Interfacial tension The interfacial (surface) tension, St, (dyne cm−1), can be calculated by applying the equation of capillary rise method (when the contact angle Ө → 0): St = \frac where: * h (cm) is the height of Hg co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Interfacial Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Double Layer
A double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object. The first layer, the surface charge (either positive or negative), consists of ions adsorbed onto the object due to chemical interactions. The second layer is composed of ions attracted to the surface charge via the Coulomb force, electrically screening the first layer. This second layer is loosely associated with the object. It is made of free ions that move in the fluid under the influence of electric attraction and thermal motion rather than being firmly anchored. It is thus called the "diffuse layer". Interfacial DLs are most apparent in systems with a large surface area to volume ratio, such as a colloid or porous bodies with particles or pores (respectively) on the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Energy
In surface science, surface free energy (also interfacial free energy or surface energy) quantifies the disruption of intermolecular bonds that occurs when a surface is created. In solid-state physics, surfaces must be intrinsically less energetically favorable than the bulk of the material (the atoms on the surface have more energy compared with the atoms in the bulk), otherwise there would be a driving force for surfaces to be created, removing the bulk of the material (see sublimation). The surface energy may therefore be defined as the excess energy at the surface of a material compared to the bulk, or it is the work required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cut a bulk sample, creating two surfaces. There is "excess energy" as a result of the now-incomplete, unrealized bonding at the two surfaces. Cutting a solid body into pieces disrupts its bonds and increases the surface area, and th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Liquid Metal Electrode
A liquid metal electrode is an electrode that uses a liquid metal, such as mercury, Galinstan, and NaK. They can be used in electrocapillarity, voltammetry, and impedance measurements. Dropping mercury electrode The dropping mercury electrode (DME) is a working electrode made of mercury and used in polarography. Experiments run with mercury electrodes are referred to as forms of polarography even if the experiments are identical or very similar to a corresponding voltammetry experiment which uses solid working electrodes. Like other working electrodes these electrodes are used in electrochemical studies using three electrode systems when investigating reaction mechanisms related to redox chemistry among other chemical phenomena. Structure A flow of mercury passes through an insulating capillary producing a droplet which grows from the end of the capillary in a reproducible way. Each droplet grows until it reaches a diameter of about a millimeter and releases. The released dro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrokinetic Phenomena
Electrokinetic phenomena are a family of several different effects that occur in heterogeneous fluids, or in porous bodies filled with fluid, or in a fast flow over a flat surface. The term heterogeneous here means a fluid containing particles. Particles can be solid, liquid or gas bubbles with sizes on the scale of a micrometer or nanometer.Dukhin, A. S. and Goetz, P. J. ''Characterization of liquids, nano- and micro- particulates and porous bodies using Ultrasound'', Elsevier, 2017 There is a common source of all these effects—the so-called interfacial 'double layer' of charges. Influence of an external force on the diffuse layer generates tangential motion of a fluid with respect to an adjacent charged surface. This force might be electric, pressure gradient, concentration gradient, or gravity. In addition, the moving phase might be either continuous fluid or dispersed phase. Family Various combinations of the driving force and moving phase determine various electrokinetic ef ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Colloid Chemistry
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word ''suspension'' is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be opaque or have a slight color. Colloidal suspensions are the subject of interface and colloid science. This field of study was introduced in 1845 by Ital ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluid Interface
In the physical sciences, an interface is the boundary between two spatial regions occupied by different matter, or by matter in different physical states. The interface between matter and air, or matter and vacuum, is called a surface, and studied in surface science. In thermal equilibrium, the regions in contact are called phases, and the interface is called a phase boundary. An example for an interface out of equilibrium is the grain boundary in polycrystalline matter. The importance of the interface depends on the type of system: the bigger the quotient area/volume, the greater the effect the interface will have. Consequently, interfaces are very important in systems with large interface area-to-volume ratios, such as colloids. Interfaces can be flat or curved. For example, oil droplets in a salad dressing are spherical but the interface between water and air in a glass of water is mostly flat. Surface tension is the physical property which rules interface processes involving ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reference Electrode
A reference electrode is an electrode which has a stable and well-known electrode potential. The high stability of the electrode potential is usually reached by employing a redox system with constant (buffered or saturated) concentrations of each participant of the redox reaction. There are many ways reference electrodes are used. The simplest is when the reference electrode is used as a half-cell to build an electrochemical cell. This allows the reduction potential, potential of the other half cell to be determined. An accurate and practical method to measure an electrode's potential in isolation (absolute electrode potential) has yet to be developed. Aqueous reference electrodes Common reference electrodes and potential with respect to the standard hydrogen electrode (SHE): * Standard hydrogen electrode (SHE) (E = 0.000 V) activity of H+ = 1 Molar * Normal hydrogen electrode (NHE) (E ≈ 0.000 V) concentration H+ = 1 Molar * Reversible hydrogen electrode (RHE) (E = 0.000 V ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ideal Electrode
In electrochemistry, there are two types of ideal electrode, the ideal polarizable electrode and the ideal non-polarizable electrode. Simply put, the ideal polarizable electrode is characterized by charge separation at the electrode-electrolyte boundary and is electrically equivalent to a capacitor, while the ideal non-polarizable electrode is characterized by no charge separation and is electrically equivalent to a short. Ideal polarizable electrode An ideal polarizable electrode (also ideally polarizable electrode or ideally polarized electrode or IPE) is a hypothetical electrode characterized by an absence of net DC current between the two sides of the electrical double layer, i.e., no faradic current exists between the electrode surface and the electrolyte. Any transient current that may be flowing is considered non-faradaic.Vladimir Sergeevich Bagot'skiĭ, "Fundamentals Of Electrochemistry",John Wiley & Sons, 2006, p. 178. The reason for this behavior is that the electrode ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematically, density is defined as mass divided by volume: : \rho = \frac where ''ρ'' is the density, ''m'' is the mass, and ''V'' is the volume. In some cases (for instance, in the United States oil and gas industry), density is loosely defined as its weight per unit volume, although this is scientifically inaccurate – this quantity is more specifically called specific weight. For a pure substance the density has the same numerical value as its mass concentration. Different materials usually have different densities, and density may be relevant to buoyancy, purity and packaging. Osmium and iridium are the densest known elements at standard conditions for temperature and pressure. To simplify comparisons of density across different s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Standard Gravity
The standard acceleration due to gravity (or standard acceleration of free fall), sometimes abbreviated as standard gravity, usually denoted by or , is the nominal gravitational acceleration of an object in a vacuum near the surface of the Earth. It is defined by standard as . This value was established by the 3rd CGPM (1901, CR 70) and used to define the standard weight of an object as the product of its mass and this nominal acceleration. The acceleration of a body near the surface of the Earth is due to the combined effects of gravity and centrifugal acceleration from the rotation of the Earth (but the latter is small enough to be negligible for most purposes); the total (the apparent gravity) is about 0.5% greater at the poles than at the Equator. Although the symbol is sometimes used for standard gravity, (without a suffix) can also mean the local acceleration due to local gravity and centrifugal acceleration, which varies depending on one's position on Earth (see Earth's ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acceleration
In mechanics, acceleration is the rate of change of the velocity of an object with respect to time. Accelerations are vector quantities (in that they have magnitude and direction). The orientation of an object's acceleration is given by the orientation of the ''net'' force acting on that object. The magnitude of an object's acceleration, as described by Newton's Second Law, is the combined effect of two causes: * the net balance of all external forces acting onto that object — magnitude is directly proportional to this net resulting force; * that object's mass, depending on the materials out of which it is made — magnitude is inversely proportional to the object's mass. The SI unit for acceleration is metre per second squared (, \mathrm). For example, when a vehicle starts from a standstill (zero velocity, in an inertial frame of reference) and travels in a straight line at increasing speeds, it is accelerating in the direction of travel. If the vehicle turns, an acc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
