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ExoMol
ExoMol is a database of molecular line lists that can be used for spectral characterisation and simulation of astrophysical environments such as exoplanets, brown dwarfs, cool stars and sunspots. The project is run by the theoretical molecular physics group of University College London , mottoeng = Let all come who by merit deserve the most reward , established = , type = Public research university , endowment = £143 million (2020) , budget = ... and is led by Jonathan Tennyson. New line lists for about 30 small molecules of astrophysical interest that currently lack a complete spectroscopic coverage are being generated. The list includes diatomics (e.g., C2, O2, AlO, MgH, CaH, FeH), triatomics (e.g., H2O, H2S, C3, SO2), tetratomics (e.g., PH3, HOOH, H2CO) and a few larger molecules (most notably CH4 and HNO3). Full details on the ExoMol web site (www.exomol.com). References {{ ...
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Jonathan Tennyson (physicist)
Charles Jonathan Penrose Tennyson (born 11 May 1955) is a British physicist. He is the Massey Professor of Physics (since 2005) and Head of department at the Department of Physics and Astronomy, University College London (2004–11). Chief Scientist Quantemol Ltd and chair, Blue Skies Space Ltd. Education He was educated at Bootham School, York. He continued his studies at King's College, Cambridge and the University of Sussex. Research and career Tennyson is an author of over 700 scientific papers focusing on applications of molecular spectroscopy to problems in astrophysics, atmospheric science, plasma physics and other fields. He has written a number of popular science articles. He wrote the undergraduate textbook ''Astronomical Spectroscopy: An Introduction to the Atomic and Molecular Physics of Astronomical Spectra'' (2005). Leader of the ExoMol project. Awards and honours Tennyson was elected a Fellow of the Royal Society (FRS) in 2009. One or more of the prec ...
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Exoplanet
An exoplanet or extrasolar planet is a planet outside the Solar System. The first possible evidence of an exoplanet was noted in 1917 but was not recognized as such. The first confirmation of detection occurred in 1992. A different planet, initially detected in 1988, was confirmed in 2003. There are many methods of detecting exoplanets. Transit photometry and Doppler spectroscopy have found the most, but these methods suffer from a clear observational bias favoring the detection of planets near the star; thus, 85% of the exoplanets detected are inside the tidal locking zone. In several cases, multiple planets have been observed around a star. About 1 in 5 Sun-like starsFor the purpose of this 1 in 5 statistic, "Sun-like" means G-type star. Data for Sun-like stars was not available so this statistic is an extrapolation from data about K-type stars. have an "Earth-sized"For the purpose of this 1 in 5 statistic, Earth-sized means 1–2 Earth radii. planet in the habitable zone. ...
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Brown Dwarf
Brown dwarfs (also called failed stars) are substellar objects that are not massive enough to sustain nuclear fusion of ordinary hydrogen ( 1H) into helium in their cores, unlike a main-sequence star. Instead, they have a mass between the most massive gas giant planets and the least massive stars, approximately 13 to 80 times that of Jupiter (). However, they can fuse deuterium ( 2H), and the most massive ones (> ) can fuse lithium ( 7Li). Astronomers classify self-luminous objects by spectral class, a distinction intimately tied to the surface temperature, and brown dwarfs occupy types M, L, T, and Y. As brown dwarfs do not undergo stable hydrogen fusion, they cool down over time, progressively passing through later spectral types as they age. Despite their name, to the naked eye, brown dwarfs would appear in different colors depending on their temperature. The warmest ones are possibly orange or red, while cooler brown dwarfs would likely appear magenta or black to th ...
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Sunspot
Sunspots are phenomena on the Sun's photosphere that appear as temporary spots that are darker than the surrounding areas. They are regions of reduced surface temperature caused by concentrations of magnetic flux that inhibit convection. Sunspots appear within active regions, usually in pairs of opposite magnetic polarity. Their number varies according to the approximately 11-year solar cycle. Individual sunspots or groups of sunspots may last anywhere from a few days to a few months, but eventually decay. Sunspots expand and contract as they move across the surface of the Sun, with diameters ranging from to . Larger sunspots can be visible from Earth without the aid of a telescope. They may travel at relative speeds, or proper motions, of a few hundred meters per second when they first emerge. Indicating intense magnetic activity, sunspots accompany other active region phenomena such as coronal loops, prominences, and reconnection events. Most solar flares and coronal mas ...
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University College London
, mottoeng = Let all come who by merit deserve the most reward , established = , type = Public research university , endowment = £143 million (2020) , budget = £1.544 billion (2019/20) , chancellor = Anne, Princess Royal(as Chancellor of the University of London) , provost = Michael Spence , head_label = Chair of the council , head = Victor L. L. Chu , free_label = Visitor , free = Sir Geoffrey Vos , academic_staff = 9,100 (2020/21) , administrative_staff = 5,855 (2020/21) , students = () , undergrad = () , postgrad = () , coordinates = , campus = Urban , city = London, England , affiliations = , colours = Purple and blue celeste , nickname ...
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Diatomic Carbon
Diatomic carbon (systematically named dicarbon and 1λ2,2λ2-ethene), is a green, gaseous inorganic chemical with the chemical formula C=C (also written 2or C2). It is kinetically unstable at ambient temperature and pressure, being removed through autopolymerisation. It occurs in carbon vapor, for example in electric arcs; in comets, stellar atmospheres, and the interstellar medium; and in blue hydrocarbon flames. Diatomic carbon is the second simplest form of carbon after atomic carbon, and is an intermediate participator in the genesis of fullerenes. Properties C2 is a component of carbon vapor. One paper estimates that carbon vapor is around 28% diatomic, but theoretically this depends on the temperature and pressure. Electromagnetic properties The electrons in diatomic carbon are distributed among the molecular orbitals according to the Aufbau principle to produce unique quantum states, with corresponding energy levels. The state with the lowest energy level, or ground s ...
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Dioxygen
There are several known allotropes of oxygen. The most familiar is molecular oxygen (O2), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (O3). Others are: *Atomic oxygen (O1), a free radical. *Singlet oxygen (O2*), one of two metastable states of molecular oxygen. *Tetraoxygen (O4), another metastable form. *Solid oxygen, existing in six variously colored phases, of which one is and another one metallic. Atomic oxygen Atomic oxygen, denoted O(3P) or O(3P), is very reactive, as the single atoms of oxygen tend to quickly bond with nearby molecules. On Earth's surface, it exists naturally for a very short time. In outer space, the presence of ample ultraviolet radiation results in a low Earth orbit atmosphere in which 96% of the oxygen occurs in atomic form. Ryan D. McCulla, Saint Louis University (2010). /acswebcontent.acs.org/prfar/2010/reports/P11141.html "Atomic Oxygen O(3P): Photog ...
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Water Vapor
(99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous phase of water. It is one state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the sublimation of ice. Water vapor is transparent, like most constituents of the atmosphere. Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed by condensation. It is less dense than most of the other constituents of air and triggers convection currents that can lead to clouds. Being a component of Earth's hydrosphere and hydrologic cycle, it is particularly abundant in Earth's atmosphere, where it acts as a greenhouse gas and warming feedback, contributing more to total greenhouse effect than non-condensable gases such as carbon dioxide an ...
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The underground mine gas term for foul-smelling hydrogen sulfide-rich gas mixtures is ''stinkdamp''. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, a spelling no longer recommended by the Royal Society of Chemistry or the International Union of Pure and Applied Chemistry. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or it or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the ...
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Tricarbon
Tricarbon (systematically named 1λ2,3λ2-propadiene and ''catena''-tricarbon) is an inorganic compound with the chemical formula (also written (μ-C)Cor ). It is a colourless gas that only persists in dilution or solution as an adduct. It is one of the simplest unsaturated carbenes. Tricarbon can be found in interstellar space and can be produced in the laboratory by a process called laser ablation. Natural occurrence Tricarbon is a small carbon cluster first spectroscopically observed in the early 20th century in the tail of a comet by William Huggins and subsequently identified in stellar atmospheres. Small carbon clusters like tricarbon and dicarbon are regarded as soot precursors and are implicated in the formation of certain industrial diamonds and in the formation of fullerenes. C3 has also been identified as a transient species in various combustion reactions. Properties Chemical properties The chemical properties of C3 was investigated in the 1960s by Prof ...
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Sulfur Dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur- bearing fossil fuels. Structure and bonding SO2 is a bent molecule with ''C''2v symmetry point group. A valence bond theory approach considering just ''s'' and ''p'' orbitals would describe the bonding in terms of resonance between two resonance structures. The sulfur–oxygen bond has a bond order of 1.5. There is support for this simple approach that does not invoke ''d'' orbital participation. In terms of electron-counting formalism, the sulfur atom has an oxidation state of +4 and a formal charge of +1. Occurrence Sulfur dioxide is found on Earth and exists in very small concentrations and in the atmosphere at about 1 ppm. On other planets, ...
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Phosphine
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula , classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (). With traces of present, is spontaneously flammable in air ( pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure. Phosphines are compounds that include and the organophosphines, which are derived from by substituting one or more hydrogen atoms with organic groups. They have the general formula . Phosphanes are saturated phosphorus hydrides of the form , such as triphosphane. Phosphine, PH3, is the smallest of the phosphines and the smallest of the phosphanes. History Philippe Gengembre (1764–1838), a student of Lavois ...
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