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Ewald Sphere
The Ewald sphere is a geometric construction used in electron, neutron, and X-ray crystallography which demonstrates the relationship between: :* the wavevector of the incident and diffracted x-ray beams, :* the diffraction angle for a given reflection, :* the reciprocal lattice of the crystal It was conceived by Paul Peter Ewald, a German physicist and crystallographer. Ewald himself spoke of the sphere of reflection. Ewald's sphere can be used to find the maximum resolution available for a given x-ray wavelength and the unit cell dimensions. It is often simplified to the two-dimensional "Ewald's circle" model or may be referred to as the Ewald sphere. Ewald construction 250px, Ewald construction A crystal can be described as a lattice of points of equal symmetry. The requirement for constructive interference in a diffraction experiment means that in momentum or reciprocal space the values of momentum transfer where constructive interference occurs also form a lattice ...
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Electron Crystallography
Electron crystallography is a method to determine the arrangement of atoms in solids using a transmission electron microscope (TEM). Comparison with X-ray crystallography It can complement X-ray crystallography for studies of very small crystals ( 1 micrometer) crystals impervious to electrons, which only penetrate short distances. One of the main difficulties in X-ray crystallography is determining phases in the diffraction pattern. Because of the complexity of X-ray lenses, it is difficult to form an image of the crystal being diffracted, and hence phase information is lost. Fortunately, electron microscopes can resolve atomic structure in real space and the crystallographic structure factor phase information can be experimentally determined from an image's Fourier transform. The Fourier transform of an atomic resolution image is similar, but different, to a diffraction pattern—with reciprocal lattice spots reflecting the symmetry and spacing of a crystal. Aaron Klug was the ...
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Bragg Diffraction
In physics and chemistry , Bragg's law, Wulff–Bragg's condition or Laue–Bragg interference, a special case of Laue diffraction, gives the angles for coherent scattering of waves from a crystal lattice. It encompasses the superposition of wave fronts scattered by lattice planes, leading to a strict relation between wavelength and scattering angle, or else to the wavevector transfer with respect to the crystal lattice. Such law had initially been formulated for X-rays upon crystals. However, It applies to all sorts of quantum beams, including neutron and electron waves at atomic distances, as well as visible light at artificial periodic microscale lattices. History Bragg diffraction (also referred to as the Bragg formulation of X-ray diffraction) was first proposed by Lawrence Bragg and his father, William Henry Bragg, in 1913 in response to their discovery that crystalline solids produced surprising patterns of reflected X-rays (in contrast to that of, say, a liquid). They ...
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Kikuchi Line (solid State Physics)
Kikuchi lines are patterns of electrons formed by scattering. They pair up to form bands in electron diffraction from single crystal specimens, there to serve as "roads in orientation-space" for microscopists uncertain of what they are looking at. In transmission electron microscopes, they are easily seen in diffraction from regions of the specimen thick enough for multiple scattering. Unlike diffraction spots, which blink on and off as one tilts the crystal, Kikuchi bands mark orientation space with well-defined intersections (called zones or poles) as well as paths connecting one intersection to the next. Experimental and theoretical maps of Kikuchi band geometry, as well as their direct-space analogs e.g. bend contours, electron channeling patterns, and fringe visibility maps are increasingly useful tools in electron microscopy of crystalline and nanocrystalline materials. Because each Kikuchi line is associated with Bragg diffraction from one side of a single set of lattice pl ...
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Laue Equations
In crystallography and solid state physics, the Laue equations relate incoming waves to outgoing waves in the process of elastic scattering, where the photon energy or light temporal frequency does not change by scattering, by a crystal lattice. They are named after physicist Max von Laue (1879–1960). The Laue equations can be written as \mathbf= \mathbf_ - \mathbf_ = \mathbf as the condition of elastic wave scattering by a crystal lattice, where \mathbf_, \mathbf k_, and \mathbf are an incoming (to the crystal) wavevector, an outgoing (from the crystal by scattering) wavevector, and a reciprocal lattice vector for the crystal respectively. Due to elastic scattering , \mathbf_, ^2=, \mathbf_, ^2, three vectors. \mathbf, \mathbf_, and -\mathbf_ , form a rhombus if the equation is satisfied. If the scattering satisfies this equation, all the crystal lattice points scatter the incoming wave toward the scattering direction (the direction along \mathbf k_). If the equation is not sati ...
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Bragg's Law
In physics and chemistry , Bragg's law, Wulff–Bragg's condition or Laue–Bragg interference, a special case of Laue diffraction, gives the angles for coherent scattering of waves from a crystal lattice. It encompasses the superposition of wave fronts scattered by lattice planes, leading to a strict relation between wavelength and scattering angle, or else to the wavevector transfer with respect to the crystal lattice. Such law had initially been formulated for X-rays upon crystals. However, It applies to all sorts of quantum beams, including neutron and electron waves at atomic distances, as well as visible light at artificial periodic microscale lattices. History Bragg diffraction (also referred to as the Bragg formulation of X-ray diffraction) was first proposed by Lawrence Bragg and his father, William Henry Bragg, in 1913 in response to their discovery that crystalline solids produced surprising patterns of reflected X-rays (in contrast to that of, say, a liquid). They ...
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Laue Zone
Max Theodor Felix von Laue (; 9 October 1879 – 24 April 1960) was a German physicist who received the Nobel Prize in Physics in 1914 for his discovery of the diffraction of X-rays by crystals. In addition to his scientific endeavors with contributions in optics, crystallography, quantum theory, superconductivity, and the theory of relativity, Laue had a number of administrative positions which advanced and guided German scientific research and development during four decades. A strong objector to Nazism, he was instrumental in re-establishing and organizing German science after World War II. Biography Early years Laue was born in Pfaffendorf, now part of Koblenz, Germany, to Julius Laue and Minna Zerrenner. In 1898, after passing his ''Abitur'' in Strassburg, he began his compulsory year of military service, after which in 1899 he started to study mathematics, physics, and chemistry at the University of Strassburg, the University of Göttingen, and the Ludwig Maximilian Uni ...
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Transmission Electron Microscopy
Transmission electron microscopy (TEM) is a microscopy technique in which a beam of electrons is transmitted through a specimen to form an image. The specimen is most often an ultrathin section less than 100 nm thick or a suspension on a grid. An image is formed from the interaction of the electrons with the sample as the beam is transmitted through the specimen. The image is then magnified and focused onto an imaging device, such as a fluorescent screen, a layer of photographic film, or a sensor such as a scintillator attached to a charge-coupled device. Transmission electron microscopes are capable of imaging at a significantly higher resolution than light microscopes, owing to the smaller de Broglie wavelength of electrons. This enables the instrument to capture fine detail—even as small as a single column of atoms, which is thousands of times smaller than a resolvable object seen in a light microscope. Transmission electron microscopy is a major analytical method i ...
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Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the Crystal_structure#Unit_cell, unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc, and alternatively called Close-packing_of_equal_spheres, ''cubic close-packed'' or ccp) Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive_cell, primitive unit cells often are not. Bravais lattices The three Bravais lattices in the cubic crystal system are: The primitive cubic lattice (cP) consists of one Lattice_(group), lattice point on each corner of the cube; this means each simple cubic unit cell has in total one latt ...
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Reciprocal Space
In physics, the reciprocal lattice represents the Fourier transform of another lattice (usually a Bravais lattice). In normal usage, the initial lattice (whose transform is represented by the reciprocal lattice) is usually a periodic spatial function in real-space and is also known as the ''direct lattice''. While the direct lattice exists in real-space and is what one would commonly understand as a physical lattice (e.g., a lattice of a crystal), the reciprocal lattice exists in reciprocal space (also known as ''momentum space'' or less commonly as ''K-space'', due to the relationship between the Pontryagin duals momentum and position). The reciprocal lattice of a reciprocal lattice is equivalent to the original direct lattice, because the defining equations are symmetrical with respect to the vectors in real and reciprocal space. Mathematically, direct and reciprocal lattice vectors represent covariant and contravariant vectors, respectively. The reciprocal lattice is the se ...
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Lattice (group)
In geometry and group theory, a lattice in the real coordinate space \mathbb^n is an infinite set of points in this space with the properties that coordinate wise addition or subtraction of two points in the lattice produces another lattice point, that the lattice points are all separated by some minimum distance, and that every point in the space is within some maximum distance of a lattice point. Closure under addition and subtraction means that a lattice must be a subgroup of the additive group of the points in the space, and the requirements of minimum and maximum distance can be summarized by saying that a lattice is a Delone set. More abstractly, a lattice can be described as a free abelian group of dimension n which spans the vector space \mathbb^n. For any basis of \mathbb^n, the subgroup of all linear combinations with integer coefficients of the basis vectors forms a lattice, and every lattice can be formed from a basis in this way. A lattice may be viewed as a regula ...
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Neutron Diffraction
Neutron diffraction or elastic neutron scattering is the application of neutron scattering to the determination of the atomic and/or magnetic structure of a material. A sample to be examined is placed in a beam of thermal or cold neutrons to obtain a diffraction pattern that provides information of the structure of the material. The technique is similar to X-ray diffraction but due to their different scattering properties, neutrons and X-rays provide complementary information: X-Rays are suited for superficial analysis, strong x-rays from synchrotron radiation are suited for shallow depths or thin specimens, while neutrons having high penetration depth are suited for bulk samples.Measurement of residual stress in materials using neutrons


Ewald Sphere
The Ewald sphere is a geometric construction used in electron, neutron, and X-ray crystallography which demonstrates the relationship between: :* the wavevector of the incident and diffracted x-ray beams, :* the diffraction angle for a given reflection, :* the reciprocal lattice of the crystal It was conceived by Paul Peter Ewald, a German physicist and crystallographer. Ewald himself spoke of the sphere of reflection. Ewald's sphere can be used to find the maximum resolution available for a given x-ray wavelength and the unit cell dimensions. It is often simplified to the two-dimensional "Ewald's circle" model or may be referred to as the Ewald sphere. Ewald construction 250px, Ewald construction A crystal can be described as a lattice of points of equal symmetry. The requirement for constructive interference in a diffraction experiment means that in momentum or reciprocal space the values of momentum transfer where constructive interference occurs also form a lattice ...
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