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Embrittlement
Embrittlement is a significant decrease of ductility of a material, which makes the material brittle. Embrittlement is used to describe any phenomena where the environment compromises a stressed material's mechanical performance, such as temperature or environmental composition. This is oftentimes undesirable as brittle fracture occurs quicker and can much more easily propagate than ductile fracture, leading to complete failure of the equipment. Various materials have different mechanisms of embrittlement, therefore it can manifest in a variety of ways, from slow crack growth to a reduction of tensile ductility and toughness. Mechanisms Embrittlement is a series complex mechanism that is not completely understood. The mechanisms can be driven by temperature, stresses, grain boundaries, or material composition. However, by studying the embrittlement process, preventative measures can be put in place to mitigate the effects. There are several ways to study the mechanisms. During me ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Metal-induced Embrittlement
Metal-induced embrittlement (MIE) is the embrittlement caused by diffusion of metal, either solid or liquid, into the base material. Metal induced embrittlement occurs when metals are in contact with low-melting point metals while under tensile stress. The embrittler can be either solid ( SMIE) or liquid (liquid metal embrittlement). Under sufficient tensile stress, MIE failure occurs instantaneously at temperatures just above melting point. For temperatures below the melting temperature of the embrittler, solid-state diffusion is the main transport mechanism.P. Gordon, "Metal-Induced embrittlement of metals—an evaluation of embrittler transport mechanisms" Metallurgical Transactions A, 9, p. 267 (1978). https://doi.org/10.1007/BF02646710 This occurs in the following ways: * Diffusion through grain boundaries near the crack of matrix * Diffusion of first monolayer heterogeneous surface embrittler atoms * Second monolayer heterogenous surface diffusion of embrittler * Surface di ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Liquid Metal Embrittlement
Liquid metal embrittlement (LME), also known as liquid metal induced embrittlement, is a phenomenon of practical importance, where certain ductile metals experience drastic loss in tensile ductility or undergo brittle fracture when exposed to specific liquid metals. Generally, a tensile stress, either externally applied or internally present, is needed to induce embrittlement. Exceptions to this rule have been observed, as in the case of aluminium in the presence of liquid gallium.J. Huntington, ''Inst. Metals'', 11 (1914), 108 This phenomenon has been studied since the beginning of the 20th century. Many of its phenomenological characteristics are known and several mechanisms have been proposed to explain it.B. Joseph, M. Picat, and F. Barbier, ''Eur. Phys. J. AP'', 5 (1999), 19D.G. Kolman, "Environmentally Induced Cracking, Liquid Metal Embrittlement" in "ASM Handbook, Volume 13A, Corrosion: Fundamentals, Testing and Protection", ASM International, Materials Park, OH, pp. 381-392 ( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Neutron Embrittlement
Neutron embrittlement, sometimes more broadly radiation embrittlement, is the embrittlement of various materials due to the action of neutrons. This is primarily seen in nuclear reactors, where the release of high-energy neutrons causes the long-term degradation of the reactor materials. The embrittlement is caused by the microscopic movement of atoms that are hit by the neutrons; this same action also gives rise to neutron-induced swelling causing materials to grow in size, and the Wigner effect causing energy buildup in certain materials that can lead to sudden releases of energy. Neutron embrittlement mechanisms include: * Hardening and dislocation pinning due to nanometer features created by irradiation * Generation of lattice defects in collision cascades via the high-energy recoil atoms produced in the process of neutron scattering. * Diffusion of major defects, which leads to higher amounts of solute diffusion, as well as formation of nanoscale defect-solute cluster comple ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Sulfide Stress Cracking
Sulfide stress cracking (SSC) is a form of hydrogen embrittlement which is a cathodic cracking mechanism. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Susceptible alloys, especially steels, react with hydrogen sulfide (), forming metal sulfides (MeS) and atomic hydrogen (H•) as corrosion byproducts. Atomic hydrogen either combines to form H2 at the metal surface or diffuses into the metal matrix. Since sulfur is a hydrogen recombination poison, the amount of atomic hydrogen which recombines to form H2 on the surface is greatly reduced, thereby increasing the amount of diffusion of atomic hydrogen into the metal matrix. This aspect is what makes wet H2S environments so severe.Foroulis Z.A ed., High-Temperature Metallic Corrosion by Sulfur and Its Compounds, The Electrochemical Society, Princeton, NJ. (1970) Conference proceedings Since SSC is a form of hydrogen embrittlement, it is most susceptibile to cracking at or sl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Stress Corrosion Cracking
Stress corrosion cracking (SCC) is the growth of crack formation in a corrosive environment. It can lead to unexpected and sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. SCC is highly chemically specific in that certain alloys are likely to undergo SCC only when exposed to a small number of chemical environments. The chemical environment that causes SCC for a given alloy is often one which is only mildly corrosive to the metal. Hence, metal parts with severe SCC can appear bright and shiny, while being filled with microscopic cracks. This factor makes it common for SCC to go undetected prior to failure. SCC often progresses rapidly, and is more common among alloys than pure metals. The specific environment is of crucial importance, and only very small concentrations of certain highly active chemicals are needed to produce catastrophic cracking, often leading to devastating and unexpected failure.ASM Internatio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Ductility
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stress before failure. Ductility is an important consideration in engineering and manufacturing. It defines a material's suitability for certain manufacturing operations (such as cold working) and its capacity to absorb mechanical overload.. Some metals that are generally described as ductile include gold and copper. However, not all metals experience ductile failure as some can be characterized with brittle failure like cast iron. Polymers generally can be viewed as ductile materials as they typically allow for plastic deformation. Malleability, a similar mechanical property, is characterized by a material's ability to deform plastically without failure under compressive stress. Historically, materials were considered malleable if they wer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Liberty Ships
Liberty ships were a class of cargo ship built in the United States during World War II under the Emergency Shipbuilding Program. Though British in concept, the design was adopted by the United States for its simple, low-cost construction. Mass-produced on an unprecedented scale, the Liberty ship came to symbolize U.S. wartime industrial output. The class was developed to meet British orders for transports to replace ships that had been lost. Eighteen American shipyards built 2,710 Liberty ships between 1941 and 1945 (an average of three ships every two days), easily the largest number of ships ever produced to a single design. Their production mirrored (albeit on a much larger scale) the manufacture of "Hog Islander" and similar standardized ship types during World War I. The immensity of the effort, the number of ships built, the role of female workers in their construction, and the survival of some far longer than their original five-year design life combine to make them th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Ductility
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stress before failure. Ductility is an important consideration in engineering and manufacturing. It defines a material's suitability for certain manufacturing operations (such as cold working) and its capacity to absorb mechanical overload.. Some metals that are generally described as ductile include gold and copper. However, not all metals experience ductile failure as some can be characterized with brittle failure like cast iron. Polymers generally can be viewed as ductile materials as they typically allow for plastic deformation. Malleability, a similar mechanical property, is characterized by a material's ability to deform plastically without failure under compressive stress. Historically, materials were considered malleable if they wer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Rehbinder Effect
The Rehbinder effect in physics is the reduction in the hardness and ductility of a material, particularly metals, by a surfactant film. A proposed explanation for this effect is the disruption of surface oxide films, and the reduction of surface energy by surfactants. The effect is of particular importance in machining, as lubricants A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, t ... reduce cutting forces. References Further reading * * * Condensed matter physics Surface science {{CMP-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The underground mine gas term for foul-smelling hydrogen sulfide-rich gas mixtures is ''stinkdamp''. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, a spelling no longer recommended by the Royal Society of Chemistry or the International Union of Pure and Applied Chemistry. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or it or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Natural Rubber
Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, and Indonesia are three of the leading rubber producers. Types of polyisoprene that are used as natural rubbers are classified as elastomers. Currently, rubber is harvested mainly in the form of the latex from the rubber tree (''Hevea brasiliensis'') or others. The latex is a sticky, milky and white colloid drawn off by making incisions in the bark and collecting the fluid in vessels in a process called "tapping". The latex then is refined into the rubber that is ready for commercial processing. In major areas, latex is allowed to coagulate in the collection cup. The coagulated lumps are collected and processed into dry forms for sale. Natural rubber is used extensively in many applications and products, either alone or in combination ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant typically need an additional 11% chromium. Because of its high tensile strength and low cost, steel is used in buildings, infrastructure, tools, ships, trains, cars, machines, electrical appliances, weapons, and rockets. Iron is the base metal of steel. Depending on the temperature, it can take two crystalline forms (allotropic forms): body-centred cubic and face-centred cubic. The interaction of the allotropes of iron with the alloying elements, primarily carbon, gives steel and cast iron their range of unique properties. In pure iron, the crystal structure has relatively little resistance to the iron atoms slipping past one another, and so pure iron is quite ductile, or soft and easily formed. In steel, small amounts of carb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |