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Ehrenfest Theorem
The Ehrenfest theorem, named after Paul Ehrenfest, an Austrian theoretical physicist at Leiden University, relates the time derivative of the expectation values of the position and momentum operators ''x'' and ''p'' to the expectation value of the force F=-V'(x) on a massive particle moving in a scalar potential V(x), The Ehrenfest theorem is a special case of a more general relation between the expectation of any quantum mechanical operator and the expectation of the commutator of that operator with the Hamiltonian of the system where is some quantum mechanical operator and is its expectation value. It is most apparent in the Heisenberg picture of quantum mechanics, where it amounts to just the expectation value of the Heisenberg equation of motion. It provides mathematical support to the correspondence principle. The reason is that Ehrenfest's theorem is closely related to Liouville's theorem of Hamiltonian mechanics, which involves the Poisson bracket instead of a com ...
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Paul Ehrenfest
Paul Ehrenfest (18 January 1880 – 25 September 1933) was an Austrian theoretical physicist, who made major contributions to the field of statistical mechanics and its relations with quantum mechanics, including the theory of phase transition and the Ehrenfest theorem. He bonded with Albert Einstein on a visit to Prague in 1912 and became a professor in Leiden, where he frequently hosted Einstein. Biography Paul Ehrenfest was born and grew up in Vienna to Jewish parents from Loštice in Moravia (now part of the Czech Republic). His parents, Sigmund Ehrenfest and Johanna Jellinek, ran a grocery store. Although the family was not overly religious, Paul studied Hebrew and the history of the Jewish people. Later, he always emphasized his Jewish roots. Ehrenfest excelled in grade school but did not do well at the Akademisches Gymnasium, his best subject being mathematics. After transferring to the Franz Josef Gymnasium, his marks improved. In 1899, he passed the final exams. He m ...
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Schrödinger Equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the subject. The equation is named after Erwin Schrödinger, who postulated the equation in 1925, and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics. Given a set of known initial conditions, Newton's second law makes a mathematical prediction as to what path a given physical system will take over time. The Schrödinger equation gives the evolution over time of a wave function, the quantum-mechanical characterization of an isolated physical system. The equation can be derived from the fact that the time-evolution operator must be unitary, and must therefore be generated by t ...
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Stone's Theorem On One-parameter Unitary Groups
In mathematics, Stone's theorem on one-parameter unitary groups is a basic theorem of functional analysis that establishes a one-to-one correspondence between self-adjoint operators on a Hilbert space \mathcal and one-parameter families :(U_)_ of unitary operators that are strongly continuous, i.e., :\forall t_0 \in \R, \psi \in \mathcal: \qquad \lim_ U_t(\psi) = U_(\psi), and are homomorphisms, i.e., :\forall s,t \in \R : \qquad U_ = U_t U_s. Such one-parameter families are ordinarily referred to as strongly continuous one-parameter unitary groups. The theorem was proved by , and showed that the requirement that (U_t)_ be strongly continuous can be relaxed to say that it is merely weakly measurable, at least when the Hilbert space is separable. This is an impressive result, as it allows one to define the derivative of the mapping t \mapsto U_t, which is only supposed to be continuous. It is also related to the theory of Lie groups and Lie algebras. Formal statem ...
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Newton's Second Law
Newton's laws of motion are three basic laws of classical mechanics that describe the relationship between the motion of an object and the forces acting on it. These laws can be paraphrased as follows: # A body remains at rest, or in motion at a constant speed in a straight line, unless acted upon by a force. # When a body is acted upon by a force, the time rate of change of its momentum equals the force. # If two bodies exert forces on each other, these forces have the same magnitude but opposite directions. The three laws of motion were first stated by Isaac Newton in his '' Philosophiæ Naturalis Principia Mathematica'' (''Mathematical Principles of Natural Philosophy''), originally published in 1687. Newton used them to investigate and explain the motion of many physical objects and systems, which laid the foundation for classical mechanics. In the time since Newton, the conceptual content of classical physics has been reformulated in alternative ways, involving differen ...
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Product Rule
In calculus, the product rule (or Leibniz rule or Leibniz product rule) is a formula used to find the derivatives of products of two or more functions. For two functions, it may be stated in Lagrange's notation as (u \cdot v)' = u ' \cdot v + u \cdot v' or in Leibniz's notation as \frac (u\cdot v) = \frac \cdot v + u \cdot \frac. The rule may be extended or generalized to products of three or more functions, to a rule for higher-order derivatives of a product, and to other contexts. Discovery Discovery of this rule is credited to Gottfried Leibniz, who demonstrated it using differentials. (However, J. M. Child, a translator of Leibniz's papers, argues that it is due to Isaac Barrow.) Here is Leibniz's argument: Let ''u''(''x'') and ''v''(''x'') be two differentiable functions of ''x''. Then the differential of ''uv'' is : \begin d(u\cdot v) & = (u + du)\cdot (v + dv) - u\cdot v \\ & = u\cdot dv + v\cdot du + du\cdot dv. \end Since the term ''du''·''dv'' is "negligi ...
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Ad Hoc
Ad hoc is a Latin phrase meaning literally 'to this'. In English, it typically signifies a solution for a specific purpose, problem, or task rather than a generalized solution adaptable to collateral instances. (Compare with ''a priori''.) Common examples are ad hoc committees and commissions created at the national or international level for a specific task. In other fields, the term could refer to, for example, a military unit created under special circumstances (see '' task force''), a handcrafted network protocol (e.g., ad hoc network), a temporary banding together of geographically-linked franchise locations (of a given national brand) to issue advertising coupons, or a purpose-specific equation. Ad hoc can also be an adjective describing the temporary, provisional, or improvised methods to deal with a particular problem, the tendency of which has given rise to the noun ''adhocism''. Styling Style guides disagree on whether Latin phrases like ad hoc should be italicized. ...
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Time Evolution
Time evolution is the change of state brought about by the passage of time, applicable to systems with internal state (also called ''stateful systems''). In this formulation, ''time'' is not required to be a continuous parameter, but may be discrete or even finite. In classical physics, time evolution of a collection of rigid bodies is governed by the principles of classical mechanics. In their most rudimentary form, these principles express the relationship between forces acting on the bodies and their acceleration given by Newton's laws of motion. These principles can also be equivalently expressed more abstractly by Hamiltonian mechanics or Lagrangian mechanics. The concept of time evolution may be applicable to other stateful systems as well. For instance, the operation of a Turing machine can be regarded as the time evolution of the machine's control state together with the state of the tape (or possibly multiple tapes) including the position of the machine's read-write h ...
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Hilbert Space
In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise naturally and frequently in mathematics and physics, typically as function spaces. Formally, a Hilbert space is a vector space equipped with an inner product that defines a distance function for which the space is a complete metric space. The earliest Hilbert spaces were studied from this point of view in the first decade of the 20th century by David Hilbert, Erhard Schmidt, and Frigyes Riesz. They are indispensable tools in the theories of partial differential equations, quantum mechanics, Fourier analysis (which includes applications to signal processing and heat transfer), and ergodic theory (which forms the mathematical underpinning of thermodynamics). John von Neumann coined the term ''Hilbert space'' for the abstract concept that under ...
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Linear Operator
In mathematics, and more specifically in linear algebra, a linear map (also called a linear mapping, linear transformation, vector space homomorphism, or in some contexts linear function) is a mapping V \to W between two vector spaces that preserves the operations of vector addition and scalar multiplication. The same names and the same definition are also used for the more general case of modules over a ring; see Module homomorphism. If a linear map is a bijection then it is called a . In the case where V = W, a linear map is called a (linear) ''endomorphism''. Sometimes the term refers to this case, but the term "linear operator" can have different meanings for different conventions: for example, it can be used to emphasize that V and W are real vector spaces (not necessarily with V = W), or it can be used to emphasize that V is a function space, which is a common convention in functional analysis. Sometimes the term ''linear function'' has the same meaning as ''linear map' ...
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Real Number
In mathematics, a real number is a number that can be used to measure a ''continuous'' one-dimensional quantity such as a distance, duration or temperature. Here, ''continuous'' means that values can have arbitrarily small variations. Every real number can be almost uniquely represented by an infinite decimal expansion. The real numbers are fundamental in calculus (and more generally in all mathematics), in particular by their role in the classical definitions of limits, continuity and derivatives. The set of real numbers is denoted or \mathbb and is sometimes called "the reals". The adjective ''real'' in this context was introduced in the 17th century by René Descartes to distinguish real numbers, associated with physical reality, from imaginary numbers (such as the square roots of ), which seemed like a theoretical contrivance unrelated to physical reality. The real numbers include the rational numbers, such as the integer and the fraction . The rest of the real number ...
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Potential
Potential generally refers to a currently unrealized ability. The term is used in a wide variety of fields, from physics to the social sciences to indicate things that are in a state where they are able to change in ways ranging from the simple release of energy by objects to the realization of abilities in people. The philosopher Aristotle incorporated this concept into his theory of potentiality and actuality, a pair of closely connected principles which he used to analyze motion, causality, ethics, and physiology in his ''Physics'', ''Metaphysics'', ''Nicomachean Ethics'', and ''De Anima'', which is about the human psyche. That which is potential can theoretically be made actual by taking the right action; for example, a boulder on the edge of a cliff has potential to fall that could be actualized by pushing it over the edge. Several languages have a potential mood, a grammatical construction that indicates that something is potential. These include Finnish, Japanese, and Sanskr ...
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Elementary Particle
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, antiquarks, and antileptons, which generally are matter particles and antimatter particles), as well as the fundamental bosons ( gauge bosons and the Higgs boson), which generally are force particles that mediate interactions among fermions. A particle containing two or more elementary particles is a composite particle. Ordinary matter is composed of atoms, once presumed to be elementary particles – ''atomos'' meaning "unable to be cut" in Greek – although the atom's existence remained controversial until about 1905, as some leading physicists regarded molecules as mathematical illusions, and matter as ultimately composed of energy. Subatomic constituents of the atom were first identified in the early 1930s; the electron and the proto ...
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