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Double-layer Capacitance
Double-layer capacitance is the important characteristic of the Double layer (interfacial), electrical double layer which appears at the interface between a surface and a fluid (for example, between a conductive electrode and an adjacent liquid electrolyte). At this boundary two layers of electric charge with opposing polarity form, one at the surface of the electrode, and one in the electrolyte. These two layers, electrons on the electrode and ions in the electrolyte, are typically separated by a single layer of solvent molecules that Adhesion, adhere to the surface of the electrode and act like a dielectric in a conventional capacitor. The amount of charge stored in double-layer capacitor depends on the applied voltage. The double-layer capacitance is the physical principle behind the electrostatic double-layer type of supercapacitors. History * Development of the double layer and pseudocapacitance model see Double layer (interfacial) * Development of the electrochemical com ...
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Double Layer (interfacial)
Double layer may refer to: * Double layer (biospecific), the surface where two different phases of matter are in contact * Double layer (plasma physics), a structure in a plasma and consists of two parallel layers with opposite electrical charge * Double layer (surface science), a structure that appears on the surface of an object when it is placed into a liquid * Double layer forces, which occur between charged objects across liquids * Double layer potential In potential theory, an area of mathematics, a double layer potential is a solution of Laplace's equation corresponding to the electrostatic or magnetic potential associated to a dipole distribution on a closed surface ''S'' in three-dimensions. T ..., a solution of Laplace's equation * Double layer suturing, two layers of sutures, first in a deep level of a tissue and then at a more superficial level * DVD+R DL or Double layer, a DVD format {{disambig ...
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Solvation
Solvations describes the interaction of a solvent with dissolved molecules. Both ionized and uncharged molecules interact strongly with a solvent, and the strength and nature of this interaction influence many properties of the solute, including solubility, reactivity, and color, as well as influencing the properties of the solvent such as its viscosity and density. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. The surrounded solute particles then move away from the solid solute and out into the solution. Ions are surrounded by a concentric shell of solvent. Solvation is the process of reorganizing solvent and solute molecules into solvation complexes and involves bond formation, hydrogen bonding, and van der Waals forces. Solvation of a solute by water is called hydration. Solubility of solid compounds dep ...
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Differential Capacitance
Differential capacitance in physics, electronics, and electrochemistry is a measure of the voltage-dependent capacitance of a nonlinear capacitor, such as an electrical double layer or a semiconductor diode. It is defined as the derivative of charge with respect to potential. Description In electrochemistry differential capacitance is a parameter introduced for characterizing electrical double layers: : C = \frac where is surface charge and is electric surface potential. Capacitance is usually defined as the stored charge between two conducting surfaces separated by a dielectric divided by the voltage between the surfaces. Another definition is the rate of change of the stored charge or surface charge () divided by the rate of change of the voltage between the surfaces or the electric surface potential (). The latter is called the "differential capacitance", but usually the stored charge is directly proportional to the voltage, making the capacitances given by the two defini ...
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Electrical Breakdown
In electronics, electrical breakdown or dielectric breakdown is a process that occurs when an electrically insulating material (a dielectric), subjected to a high enough voltage, suddenly becomes a conductor and current flows through it. All insulating materials undergo breakdown when the electric field caused by an applied voltage exceeds the material's dielectric strength. The voltage at which a given insulating object becomes conductive is called its '' breakdown voltage'' and, in addition to its dielectric strength, depends on its size and shape, and the location on the object at which the voltage is applied. Under sufficient voltage, electrical breakdown can occur within solids, liquids, or gases (and theoretically even in a vacuum). However, the specific breakdown mechanisms are different for each kind of dielectric medium. Electrical breakdown may be a momentary event (as in an electrostatic discharge), or may lead to a continuous electric arc if protective devices ...
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Chemical Stability
In chemistry, chemical stability is the thermodynamic stability of a chemical system, in particular a chemical compound or a polymer. Colloquially, it may instead refer to kinetic persistence, the shelf-life of a metastable substance or system; that is, the timescale over which it begins to degrade. Thermodynamic stability occurs when a system is in its lowest energy state, or in chemical equilibrium with its environment. This may be a dynamic equilibrium in which individual atoms or molecules change form, but their overall number in a particular form is conserved. This type of chemical thermodynamic equilibrium will persist indefinitely unless the system is changed. Chemical systems might undergo changes in the phase of matter or a set of chemical reactions. State A is said to be more thermodynamically stable than state B if the Gibbs free energy of the change from A to B is positive. Versus reactivity Thermodynamic stability applies to a particular system. The reacti ...
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Charge Carrier
In solid state physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. In a conducting medium, an electric field can exert force on these free particles, causing a net motion of the particles through the medium; this is what constitutes an electric current. The electron and the proton are the elementary charge carriers, each carrying one elementary charge (''e''), of the same magnitude and opposite sign. In conductors In conducting mediums, particles serve to carry charge. In many metals, the charge carriers are electrons. One or two of the valence electrons from each atom are able to move about freely within the crystal structure of the metal. The free electrons are referred to as conduction electrons, and the cloud of free electrons is called a Fermi gas. Many metals have electron and hole bands. In ...
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Field Strength
In physics, field strength refers to a value in a vector-valued field (e.g., in volts per meter, V/m, for an electric field ''E''). For example, an electromagnetic field has both electric field strength and magnetic field strength. Field strength is a common term referring to a '' vector'' quantity. However, the word 'strength' may lead to confusion as it might be referring only to the magnitude of that vector. For both gravitational field strength and for electric field strength, The Institute of Physics glossary states "this glossary avoids that term because it might be confused with the magnitude of the ravitational or electricfield". As an application, in radio frequency telecommunications Telecommunication, often used in its plural form or abbreviated as telecom, is the transmission of information over a distance using electronic means, typically through cables, radio waves, or other communication technologies. These means of ..., the signal strength excit ...
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Aluminum Oxide
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, ALOX or alundum in various forms and applications and alumina is refined from bauxite. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire,which have an alumina content approaching 100%. Al2O3 is used as feedstock to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point. Natural occurrence Corundum is the most common naturally occurring crystalline form of aluminium oxide. Rubies and sapphires are gem-quality forms of corundum, which owe their characteristic colours to trace impurities. Rubies are given their ...
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Electrolytic Capacitors
An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble salts, acids, and bases, dissolved in a polar solvent like water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also function as electrolytes. Electrolyte sol ...
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Debye Length
In plasmas and electrolytes, the Debye length \lambda_\text (Debye radius or Debye–Hückel screening length), is a measure of a charge carrier's net electrostatic effect in a solution and how far its electrostatic effect persists. With each Debye length the charges are increasingly electrically screened and the electric potential decreases in magnitude by e. A Debye sphere is a volume whose radius is the Debye length. Debye length is an important parameter in plasma physics, electrolytes, and colloids ( DLVO theory). The Debye length for a plasma consisting of particles with density n, charge q, and temperature T is given by \lambda_\text^2 = \varepsilon_0 k_\textT/(n q^2) . The corresponding Debye screening wavenumber is given by 1/\lambda_\text . The analogous quantities at very low temperatures (T \to 0) are known as the Thomas–Fermi length and the Thomas–Fermi wavenumber, respectively. They are of interest in describing the behaviour of electrons in metals at roo ...
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Electric Field
An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) describes their capacity to exert attractive or repulsive forces on another charged object. Charged particles exert attractive forces on each other when the sign of their charges are opposite, one being positive while the other is negative, and repel each other when the signs of the charges are the same. Because these forces are exerted mutually, two charges must be present for the forces to take place. These forces are described by Coulomb's law, which says that the greater the magnitude of the charges, the greater the force, and the greater the distance between them, the weaker the force. Informally, the greater the charge of an object, the stronger its electric field. Similarly, an electric field is stronger nearer charged objects and weaker f ...
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