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Disclination
In crystallography, a disclination is a line defect in which rotational symmetry is violated. In analogy with dislocations in crystals, the term, ''disinclination'', for liquid crystals first used by Frederick Charles Frank and since then has been modified to its current usage, ''disclination''. It is a defect in the orientation of director whereas a dislocation is a defect in positional order. Example in two dimensions In 2D, disclinations and dislocations are point defects instead of line defects as in 3D. They are topological defects and play a central role in melting of 2D crystals within the KTHNY theory, based on two Kosterlitz–Thouless transitions. Equally sized discs (spheres, particles, atoms) form a hexagonal crystal as dense packing in two dimensions. In such a crystal, each particle has six nearest neighbors. Local strain and twist (for example induced by thermal motion) can cause configurations where discs (or particles) have a coordination number different of ...
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Liquid Crystal
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. There are many types of LC phases, which can be distinguished by their optical properties (such as textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. LC materials may not always be in a LC state of matter (just as water may be ice or water vapor). Liquid crystals can be divided into 3 main types: * thermotropic, * lyotropic, and * metallotropic. Thermotropic and lyotropic liquid crystals consist mostly of organic molecules, although a few minerals are also known. Thermotropic LCs exhibit a phase transition into the LC phase as temperature changes. Lyotropic LCs exhibit phase transitions as a function of b ...
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Frederick Charles Frank
Sir Frederick Charles Frank, OBE, FRS (6 March 1911 – 5 April 1998) was a British theoretical physicist. He is best known for his work on crystal dislocations, including (with Thornton Read) the idea of the Frank–Read source of dislocations. He also proposed the cyclol reaction in the mid-1930s, and made many other contributions to solid-state physics, geophysics, and the theory of liquid crystals. Early life and education He was born in Durban, South Africa, although his parents returned to England soon afterwards. He was educated at Thetford Grammar School and Ipswich School and went on to study chemistry at Lincoln College, Oxford, gaining a doctorate at the university's Engineering Laboratory. Career Prior to World War II, he worked as a physicist in Berlin and as a colloid chemist in Cambridge. During World War II he joined the Chemical Defence Experimental Station at Porton Down, Wiltshire, but in 1940 was transferred to the Air Ministry's Assistant Directorate ...
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Liquid Crystal
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. There are many types of LC phases, which can be distinguished by their optical properties (such as textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. LC materials may not always be in a LC state of matter (just as water may be ice or water vapor). Liquid crystals can be divided into 3 main types: * thermotropic, * lyotropic, and * metallotropic. Thermotropic and lyotropic liquid crystals consist mostly of organic molecules, although a few minerals are also known. Thermotropic LCs exhibit a phase transition into the LC phase as temperature changes. Lyotropic LCs exhibit phase transitions as a function of b ...
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Dislocation
In materials science, a dislocation or Taylor's dislocation is a linear crystallographic defect or irregularity within a crystal structure that contains an abrupt change in the arrangement of atoms. The movement of dislocations allow atoms to slide over each other at low stress levels and is known as ''glide'' or slip. The crystalline order is restored on either side of a ''glide dislocation'' but the atoms on one side have moved by one position. The crystalline order is not fully restored with a ''partial dislocation''. A dislocation defines the boundary between ''slipped'' and ''unslipped'' regions of material and as a result, must either form a complete loop, intersect other dislocations or defects, or extend to the edges of the crystal. A dislocation can be characterised by the distance and direction of movement it causes to atoms which is defined by the Burgers vector. Plastic deformation of a material occurs by the creation and movement of many dislocations. The number an ...
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Line Defect
A crystallographic defect is an interruption of the regular patterns of arrangement of atoms or molecules in crystalline solids. The positions and orientations of particles, which are repeating at fixed distances determined by the unit cell parameters in crystals, exhibit a periodic crystal structure, but this is usually imperfect.Ehrhart, P. (1991Properties and interactions of atomic defects in metals and alloys, volume 25 of Landolt-Börnstein, New Series III, chapter 2, p. 88, Springer, Berlin Several types of defects are often characterized: point defects, line defects, planar defects, bulk defects. Topological homotopy establishes a mathematical method of characterization. Point defects Point defects are defects that occur only at or around a single lattice point. They are not extended in space in any dimension. Strict limits for how small a point defect is are generally not defined explicitly. However, these defects typically involve at most a few extra or missing atoms. La ...
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Crystallography
Crystallography is the experimental science of determining the arrangement of atoms in crystalline solids. Crystallography is a fundamental subject in the fields of materials science and solid-state physics ( condensed matter physics). The word "crystallography" is derived from the Greek word κρύσταλλος (''krystallos'') "clear ice, rock-crystal", with its meaning extending to all solids with some degree of transparency, and γράφειν (''graphein'') "to write". In July 2012, the United Nations recognised the importance of the science of crystallography by proclaiming that 2014 would be the International Year of Crystallography. denote a direction vector (in real space). * Coordinates in ''angle brackets'' or ''chevrons'' such as <100> denote a ''family'' of directions which are related by symmetry operations. In the cubic crystal system for example, would mean 00 10 01/nowiki> or the negative of any of those directions. * Miller indices in ''parentheses ...
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Close-packing Of Equal Spheres
In geometry, close-packing of equal spheres is a dense arrangement of congruent spheres in an infinite, regular arrangement (or lattice). Carl Friedrich Gauss proved that the highest average density – that is, the greatest fraction of space occupied by spheres – that can be achieved by a lattice packing is :\frac \approx 0.74048. The same packing density can also be achieved by alternate stackings of the same close-packed planes of spheres, including structures that are aperiodic in the stacking direction. The Kepler conjecture states that this is the highest density that can be achieved by any arrangement of spheres, either regular or irregular. This conjecture was proven by T. C. Hales. Highest density is known only for 1, 2, 3, 8, and 24 dimensions. Many crystal structures are based on a close-packing of a single kind of atom, or a close-packing of large ions with smaller ions filling the spaces between them. The cubic and hexagonal arrangements are very close to one anoth ...
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Affine Transformation
In Euclidean geometry, an affine transformation or affinity (from the Latin, ''affinis'', "connected with") is a geometric transformation that preserves lines and parallelism, but not necessarily Euclidean distances and angles. More generally, an affine transformation is an automorphism of an affine space (Euclidean spaces are specific affine spaces), that is, a function which maps an affine space onto itself while preserving both the dimension of any affine subspaces (meaning that it sends points to points, lines to lines, planes to planes, and so on) and the ratios of the lengths of parallel line segments. Consequently, sets of parallel affine subspaces remain parallel after an affine transformation. An affine transformation does not necessarily preserve angles between lines or distances between points, though it does preserve ratios of distances between points lying on a straight line. If is the point set of an affine space, then every affine transformation on can b ...
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Isotropy
Isotropy is uniformity in all orientations; it is derived . Precise definitions depend on the subject area. Exceptions, or inequalities, are frequently indicated by the prefix ' or ', hence ''anisotropy''. ''Anisotropy'' is also used to describe situations where properties vary systematically, dependent on direction. Isotropic radiation has the same intensity regardless of the direction of measurement, and an isotropic field exerts the same action regardless of how the test particle is oriented. Mathematics Within mathematics, ''isotropy'' has a few different meanings: ; Isotropic manifolds: A manifold is isotropic if the geometry on the manifold is the same regardless of direction. A similar concept is homogeneity. ; Isotropic quadratic form: A quadratic form ''q'' is said to be isotropic if there is a non-zero vector ''v'' such that ; such a ''v'' is an isotropic vector or null vector. In complex geometry, a line through the origin in the direction of an isotropic vecto ...
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Coordination Number
In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central ion/molecule/atom is called a ligand. This number is determined somewhat differently for molecules than for crystals. For molecules and polyatomic ions the coordination number of an atom is determined by simply counting the other atoms to which it is bonded (by either single or multiple bonds). For example, r(NH3)2Cl2Br2sup>− has Cr3+ as its central cation, which has a coordination number of 6 and is described as ''hexacoordinate''. The common coordination numbers are 4, 6 and 8. Molecules, polyatomic ions and coordination complexes In chemistry, coordination number, defined originally in 1893 by Alfred Werner, is the total number of neighbors of a central atom in a molecule or ion. The concept is most commonly applied to coordinat ...
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